Read Microsoft Word - Deltamethrin Tech..doc text version

MATERIAL SAFETY DATA SHEET

SECTION 1 - IDENTIFICATION OF THE SUBSTANCE AND COMPANY Company Address: The National Company For Agrochemicals & Investment 473 El_horreya St., Bolkly Alexandria-Egypt Tel.: (203) 5440640/1 Product Name: Deltamethrin Technical CAS RN: 52918-63-5 CUS (Customs union and statistics number): 27685 CN-Code (Combined Nomenclature code): 2926 90 95 Chemical Name: (S)-a-cyano-3-phenoxybenzyl (1R,3R)-3-(2,2-dibromovinyl)-2,2-dimehyl cyclopropanecarboxylate Chemical family: pyrethroid SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS Component Deltamethrin Percentage 98 % Fax.: (203) 5411150

SECTION 3 - IDENTIFICATION OF HAZARDS Emergency Overview: Danger and corrosive. · causes irreversible eye damage. · may be fatal if swallowed. Potential Health Effects

EYES: DANGER; CORROSIVE. Causes irreversible eye damage. SKIN: No skin irritant. INHALATION: Harmful if inhaled. INGESTION: May be fatal if swallowed.

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SECTION 4- FIRST AID MEASURES

AFTER CONTACT WITH SKIN: Remove all contaminated clothing and shoes immediately.

Wash affected area with soap and large amount of water (approximately 15 - 20 min).

AFTER CONTACT WITH EYES: Hold eyelids open and flush with a steady, gentle stream of

water for 15 minutes. Get medical attention.

AFTER INHALATION: Remove victim to fresh air. If not breathing, give artificial respiration,

preferably mouth-to-mouth. Get medical attention.

AFTER INGESTION: Call a doctor or get medical attention. Do not induce vomiting because of

aspiration hazard. Do not give anything by mouth to an unconscious person. Avoid alcohol.

HINTS FOR THE PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric

lavage. SECTION 5 - FIRE FIGHTING MEASURES Extinguishing Media: carbon dioxide, dry chemical, foam, and water fog. Special Fire fighting procedures: If a significant quantity of this product is involved in a fire, call the fire brigade. When fighting fires involving significant quantities of this product, wear safety boots, non-flammable overalls, gloves, hat, goggles and respirator. All skin areas should be covered. Unusual Fire & Explosion Hazards: Fire decomposition products from this product may form toxic mixtures in confined spaces. Vapors from this product are heavier than air and may accumulate in sumps, pits and other low-lying spaces, forming potentially explosive mixtures. They may also flash back considerable distances. Stability: This product is unlikely to spontaneously decompose. Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death

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SECTION 6 - ACCIDENTAL RELEASE MEASURES Avoid contact with the spilled material or contaminated surfaces. Do not smoke, eat or drink during the cleanup process. Personnel involved in cleanup should wear full body protective clothing and equipment as described in Section 8 ­ PERSONAL PROTECTION. Keep people and animals away. Consider evacuation and obtain assistance from emergency services if needed. Prevent spilled material from entering drains or watercourses. Contain spill and sweep up carefully. Avoid creating dust. Collect and store in recovery drums. Clean floor with detergent and water, absorbing wash water with clay granules and transfer this to the drum. Seal and label drums for safe disposal. Deal with all spillages immediately. If contamination of drains, streams, watercourses, etc. is unavoidable, warn the local water authority. Decontaminate tools, equipment and clothing used in the cleanup. Dispose of any heavily soiled clothing, placing it in disposal drum. SECTION 7 - HANDLING AND STORAGE HANDLING: Keep out of reach of children. Very dangerous. Poisonous if absorbed by skin contact, inhaled or swallowed. Avoid contact with eyes and skin. Do not touch or rub eyes, nose or mouth with hand when handling granules. Wear protective clothing and equipment as above. Keep away from volatile chemicals and sources of ignition. Avoid creating dust. Do not inhale dust. If product on skin, immediately wash area with soap and water. After use and before eating, drinking or smoking, wash hands, arms and face thoroughly with soap and water. After each day's use, wash gloves, respirator and contaminated clothing with detergent and warm water. STORAGE: KEEP OUT OF REACH OF CHILDREN Store in the closed, original container in a dry, cool, well-ventilated area. Do not store for prolonged periods in direct sunlight. Store in a locked room or place away from children, animals, food, feedstuffs, seed and fertilizers. DO NOT store in or around the home. Store below 45°C. Avoid extreme heat. Keep dry ­ moisture can increase handling hazards.

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SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION

VENTILATION: No special ventilation requirements are normally necessary for this product.

However make sure that the work environment remains clean and that dusts and vapours are minimized.

EYE PROTECTION: Eye protection such as protective glasses or goggles is recommended when

product is being used.

SKIN PROTECTION: Prevent skin contact by wearing impervious gloves, clothes and, preferably,

apron. Make sure that all skin areas are covered. See below for suitable material types.

PROTECTIVE MATERIAL TYPES: We suggest that protective clothing be made from rubber, PVC. RESPIRATOR: Usually, no respirator is necessary when using this product.

Safety deluge showers should be provided near to where this product is being used. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES:

PHYSICAL DESCRIPTION & COLOUR: Colourless crystals. ODOR: MOLECULAR WEIGHT: MOLECULAR FORMULA: BOILING POINT: FREEZING/MELTING POINT: S.G./DENSITY VAPOUR PRESSURE: WATER SOLUBILITY:

Characteristic of mineral spirits. 505.2 C22H19Br2NO3 Not available. 100-102 oC. Bulk density 0.55 g/cm3 (25 oC) 1.24 x 10-5 mPa (25 °C, gas saturation method). In water <0.2 mg/l (25 °C).

SECTION 10 - STABILITY AND REACTIVITY

CHIMECAL STABILITY: Extremely stable on exposure to air. HAZARDOUS POLYMERIZITION: Will not occur

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SECTION 11 - TOXICOLOGICAL INFORMATION Oral: Dermal: Inhalation: LD50 for Rats: 135->5000 mg/kg. LD50 for Dogs: >300 mg/kg. LD50 for Rats and Rabbits: > 2000 mg/kg LC50 (4h) for Rats: 2.2 mg/l air.

Eye Irritation: mild eye irritant (rabbits). Skin Irritation:Non-irritating to skin (rabbits). ADI (JMPR): 0.01 mg/kg b.w. Other: Non-mutagenic and non-teratogenic (mice, rats, rabbits). Toxicity class: WHO (a.i.) II SECTION 12 - ECOLOGICAL INFORMATION This pesticide is toxic to fish and aquatic invertebrates. Do not apply directly to water, to areas where surface water is present, or to intertidal areas below the mean high water mark. Do not apply when weather conditions favor drift from treated area. Drift or runoff from treated fields may be hazardous to aquatic organisms in areas near the application site. Do not contaminate water by cleaning of equipment or disposal of equipment wash waters. This product is toxic to bees exposed to direct treatment. Do not apply it, or allow it to drift, to crops or weeds on which bees are actively foraging.

FISH TOXICITY:

96 hour LC50, Rainbow trout ­ 0.91µg/l, bluegill sunfish 1.4µg/l.

AVIAN TOXICITY:

Acute oral LD50 for mallard ducks >4640 mg/kg. Dietary LC50 (8 d) for mallard ducks >8039, quail >5620 mg/kg diet.

BEE TOXICITY: Toxic to bees.

LD50 (oral) 79 ng/bee; (contact) 51 ng/bee.

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SECTION 13 - DISPOSAL CONSIDERATIONS

WASTE: Pesticide wastes are toxic and hazardous. Dispose of in accordance with applicable

and local laws and regulations. Do not discharge or pour into soil, drainage system or bodies of water.

CONTAINER:

Triple rinse (or equivalent). Then offer for recycling or reconditioning, or

puncture and dispose of in a sanitary landfill, or incineration, or if allowed by state and local authorities, by burning (plastic containers). If burned, stay out of smoke. SECTION 14 - TRANSPORT INFORMATION DESCRIPTION: Pyrethroid pesticide, Solid, Toxic.

UN NUMBER: HAZARD CLASS: PACKING GROUP:

UN 3349 6.1 PG III SECTION 15 - REGULATORY INFORMATION

Risk Symbols: T: Toxic., N: Dangerous for the environment Risk Phrases: R23/25 Toxic by inhalation and if swallowed. R50 Very toxic to aquatic organisms. R53 May cause long-term adverse effects in the aquatic environment. SECTION 16 - OTHER INFORMATION

DISCLAIMER: The information presented herein is based on available data from reliable

sources and is correct to the best of Agrochem knowledge. Agrochem makes no warranty, express or implied, regarding the accuracy of the data or the results obtained from the use of this product. Nothing herein may be construed as recommending any practice or any product in violation of any law or regulations. The user is solely responsible for determining the suitability of any material or product for a specific purpose and for adopting any appropriate safety precautions. We disclaim all liability for injury or damage stemming from any improper use of the material or product described herein.

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