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MATERIAL SAFETY DATA SHEET

SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

C]ariant

MANUFACTURER/SUPPLIER NAME: Clariant Corporation, AZElectronic Materials PO Box 3700, 70 Meister Avenue Somerville, NJ 08876-1258 TELEPHONE NUMBERS: Emergency-CHEMTREC: Product Information: CustomerService: AZ(R) None

(800) 424-9300 (908) 429-3593 (800) 515-4164

PRODUCT NAME: SYNONYMS: MSDS NO. REVISION DATE: DATE PRINTED: SECTION 2.

AQUATAR COATING

70S4 11/23/1999 02/01/2000 COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name& CAS WeightPercent Number Trade Secret: Fluoroalkyl ammonium salt 2-Propenoicacid homopolymer 009003-01-4 3 1.5

Hazardous?

NJTrade Secret #

Ingredient Synonyms None Polyacrylicacid

OtherInformation-

Yes Yes

67829000004-5053P NA

Tradesecret per NJ/PARTKlaws. None

Chemical Name& CAS WeightPercent Number Water 007732-18-5 >95

Hazardous?,

NJ TradeSecret #

Ingredient Synonyms None

OtherInformation:

No

NA

NJ/PA listings. RTK Not on anyother state RTK list.

SECTION 3.

HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW: Clear, colorless liquid. Noodor. Noncombustible. Water soluble. Maybe irritating organ effects with repeated or excesssive exposure. POTENTIAL HEALTH EFFECTS:

and/or toxic. Mayproducesystemic or

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Clariant Corporation, ElectronicMaterials AZ AZ(R) AQUATAR COATING70S4 REVISION DATE: 11/23/1999

RelevantRoutes Exposure: of liquid andmist contactwith skin andeyes.Inhalationof mist. Medical Conditions Aggravated: Preexisting skin andeyeconditions may aggravated. be 2-Propenoic homopolymerstypically irritating to skin, eyes, and mucous acid are membranes. dilute solution may This give similar responses exposure the liquid or aerosol. upon to Thefluoroalkyl ammonium present about is a strongskin irritant anda severe irritant. It is toxic in rats by salt, at 3%, eye the oral route. It wasnegative the Ames for mutagenicity wasfoundto be a non-sensitizer guinea in Test and in pigs. A closley related, but not identical, fluoroalkyl ammonium hasbeen salt foundto induce benign liver, testicular, and pancreatic tumors chronicrat feedingstudies.Furthertest dataindicate that the related fluoroalkyl ammonium does in salt not damage but acts througha mechanism rats whichis not relevant to human DNA, in exposure. related material The also shows toxicity by skin absorption a longhalf-life in man. and Noted effects in rats are pdmadly the liver andblood on systems.

SECTION 4.

FIRST AID MEASURES

FIRST AID PROCEDURES: Inhalation: Remove victim to fresh air. Consult physician irritation occurs. if Eye Contact: Flushthoroughly with waterfor 15 minutes.Getimmediate medicalhelp. Skin Contact: immediately remove contaminated clothing andwash affected area thoroughlywith soapandwater. Consultphysicianif exposure extensive if irritation occurs. is or Ingestion: If person conscious, is give wateror milk to dilute stomach contents. Never give anythingby mouth an unconscious to person.Donot inducevomiting. Consult physician. SECTION 5. FIRE FIGHTING MEASURES

Noncombustible.Compatible extinguishingagents.Water-based with material with low level of combustible solid content. SECTION 6. ACCIDENTAL RELEASE MEASURES

Spill or LeakProcedures: Wearing appropriate personal protectiveequipment, containspill, collect onto inert absorbent, placein a suitable and container.Rinseresidua]with water.

SECTION 7.

HANDLING AND STORAGE

Handling: Useonly with adequate ventilation andproperprotective eyewear, gloves,andclothing. Avoidcontactwith skin, eyes, and clothing. Keep containerclosed. Storage: Storein original container.Storeat appropriate temperature. label for details. Keep See fromfreezing.

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Clariant Corporation, AZ Electronic Materials AZ(R) AQUATAR COATING 70S4 REVISION DATE: 11/23/1999

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls: Where mist is present, provide local exhaustventilation or a respirator certified for mist by NIOSH. Personal Protective Equipment(PPE): Clothing suitable to prevent skin contact. Safety eyewear protect against splashes. Rubbergloves. Where to mist is present, providelocal ventilation or a respirator certified for mist by NIOSH. ExposureGuidelines: Chemical Name CAS & Number Trade Secret Ruoro : alkyl ammonium salt 2-Pmpenoic acid homopolymer 009003-01-4 Weight Percent Manufacturer's ACGIHTWA TLV* OSHA PEL* TWA TLV* 3 1.5 NIOSH REL* AIHAWEEL*

Chemical Name CAS & Number Water 007732-18-5

Weight Percent Manufacturer's ACGIHTWATLV* OSHA PEL* TWA TLV* >95

NIOSH REL*

AIHAWEEL*

"TWA = Time TLV Weighted Average Threshold Limit Value ACGIHAmerican = Conference Governmental of Industrial Hygienists OSHA = Occupational PEL SafetyandHealthAdministration Permissable Exposure Limit NIOSH = NationalInstitute of Occupational REL SafetyandHealthRecommended Limit Exposure AIHA WEELAmedcan = Indusb'ial Hygiene Association Workplace Environmental Exposure Level **SkinNotation ***Hoechst Celanese Workplace Exposure (HCC Level WEL); included a "no contact"recommendation dueto its skin absorption Is for NMP properties. Basedon the absorption and excretion characteristics of a compound similar to the fluoroalkyl ammonium in this salt product, prolongedand repeated exposureto this product by contact with liquid or mists should be avoided.

SECTION 9. PHYSICALAND CHEMICALPROPERTIES

Appearance: Odor: Physical State: pH Vapor Pressure Boiling Point: Solubility in water: Specific gravity: Evaporation rate (butyl acetate1): %Volatile: Clear, colorless liquid. Noodor. Liquid with dissolved solids. 4 Approximately the sameas water. 100 deg C. Soluble. 1.00 Approximately the sameas water. 95

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Clariant Corporation, AZ Electronic Materials AZ(R) AQUATAR COATING 70S4 REVISION DATE: 11/23/1999

SECTION 10,

STABILITY ANDREACTIVITY

Chemical Stability: Stable. Hazardous Polymerization: Will not occur. Conditions to Avoid: Avoid contact with alkaline materials. Hazardous Decomposition Products: Thermaldecompositionmaygenerate carbon dioxide, carbon monoxide,and oxides of nitrogen. Also hydrogenfluoride.

SECTION 11. TOXICOLOGICAL INFORMATION

Carcinogen: IARC:NO NTP: NO OSHA'NO Ingredient Toxicity Data: Chemical Name CAS & Number Trade Secret Ruom : alkyl ammonium salt 2-Pmpenoic acid homopolymer 009003-01-4 WeightPercent 3 1.5 oral rat LD50 100-160 mg/kg skin rbt LD50 inh rat LC50

Chemical Name CAS & Number Water 007732-18-5

WeightPercent >95

oral rat LD50

skin rbt LDS0

Inh rat LC50

TOXICITY HAZARD STATEMENTSFOR PRODUCT:

SECTION 12.

ECOLOGICAL INFORMATION

Ingredient Ecological Toxicity Data:

Chemical Name CAS & Number Trade Secret Fluore : alkyl ammonium salt 2-Propenoic acid homopolyrner 009003-01-4

Weight Percent 3 1.5

Fish LC50 >300 (96hr-Bluegill mg/L Sunfish)

Daphnla EC50 48hrEC50:2.7 16 mg/L & (2 tests). 48hr NOEC: & 2.8 0.5 mg/L tests) (2

AlgaeIC50 96 hr IC50:>300 mg/L

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Clariant Corporation, ElectronicMaterials AZ AZ(R) AQUATAR COATING70S4 REVISIONDATE: 11/23/1999

Chemical Name& CAS Number Water 007732-18-5

Weight Percent

Fish LC50

Daphnla EC50

Algae IC50

>95

Environmental hazard information statements (using EUclassification criteria): Biological Oxygen Demand (BOD)for Product: 730 mg/L(5 day) Chemical Oxygen Demand (COD)for Product: 21000 mg/L (single test)

SECTION 13.

DISPOSAL CONSIDERATIONS

Disposal: Consultlocal, state, andfederal regulations. This productdoesnot become hazardous a waste.However, to the low due biodegradability the fluoroalkyl ammonium incinerationis the preferredmethod disposal.If incinerated,operatol of salt, of mustbe advised that the product,as sold, contains2 percentorganicallybound fluorine.

SECTION 14. TRANSPORT INFORMATION

DOT/IATA ShipperEntry: Thisproduct not regulated surfaceor air transportation. is for

SECTION 15.

REGULATORY INFORMATION

TSCA Inventory Status: All components this productare listed on the TSCA of Inventory. SARA Title III section313: This productis not subject to SARA Title III Section313reporting requirements under40CFR372. OSHA Physical Hazards: None OSHA Health Hazards: EyeHazard. Irritant. Skin Hazard. Toxic. SARA (311,312) HazardClass(es): Acutehealth hazard.

SECTION 16.

OTHER INFORMATION

HMISRatings: Health= 2; Flammability 0; Reactivity = 0; PPE=G = NFPA Ratings: Health=- 2; Flammability 0; Reactivity= 0; SpecialHazard None. = = Page 5 Of 6

Clariant Corporation, ElectronicMaterials AZ AZ(R) AQUATAR COATING70S4 REVISION DATE: 11/23/1999

(R) andTM indicate trademarks Clariant AG,its business of partnersor suppliers. Theinformation herein is provided good faith, but no warranty, express implied,is made respectto suchinformation. or with

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