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MATERIALSAFETY DATA SHEET

PRODUCT

N A LC 0

NALCO2895 PLUS

Emerqency TelephoneNumber Medical (800) 462-5378 hours) (24

(800) I-M-ALERT

SECTION

01 CHEMICAL

PRODUCT

AND

COMPANY

IDENTIFICATION

..............................................................................

TRADE NAME: DESCRIPTION:

NALCO 2895 An aqueous

PLUS solution

of sulfites 0 OTHER

NFPA 704M/HMIS 0:Insignificant SECTION 02

RATING: i/i l:Slight COMPOSITION

HEALTH 0/0 FLAHIW_ABILITY 0/0 REACTIVITY 2:Moderate 3=High 4:Extreme ON INGREDIENTS

AND INFORMATION

..............................................................................

Our hazard evaluation has identified the following hazardous under OSHA's Hazard Communication Rule, Section 15 for the nature of the hazard(s). INGREDIENT(S) Sodium sulfite Potassium sulfite SECTION 03 HAZARD IDENTIFICATION CAS # 7757-83-7 10117-38-1

chemical ingredient(s) 29 CFR 1910.1200. Consult

APPROX.% 10-20 1-5

..............................................................................

EMERGENCY OVERVIEW: CAUTION: May cause eyes and clothing.

irritation to skirl and Do not take internally. residual

eyes.

Avoid

contact

with

skin,

Empty containers may contain unless properly reconditioned. PRIMARY ROUTE(S) OF EXPOSURE:

product.

Do not

reuse

container

Eye,

Skin,

Inhalation

EYE CONTACT: SKIN CONTACT: INGESTION: INHALATION:

Can cause mild, short-lasting irritation. Can cause mild, short-lasting irritation. Can be harmful. May cause irritation to the respiratory tract

and

lungs.

SYMPTOMS OF EXPOSURE: Ingestion of sulfite can cause in sensitive individuals. The resultant symptoms can breathing, flushed skin and a rash. AGGRAVATION OF EXISTING product, which has been SECTION 04 FIRST AID

an allergic reaction include difficulty in

CONDITIONS: Sulfur dioxide may be given off by this shown to cause breathing difficulties in asthmatics.

..............................................................................

INFORMATION

..............................................................................

EYES: SKIN: INGESTION: INHALATION:

Flush with water for 15 minutes. Call a physician. Flush with water for 15 minutes. Induce vomiting. Give water. Call a physician at once. Remove to fresh air. Treat symptoms. Call a physician at once.

NOTE TO PHYSICIAN: Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition.

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NALCOCHEMICAL COMPANY ONE NALCO CENTER° NAPERVILLE, ILLINOIS 60563-1198 AREA (630) 305-1000

MATERIALSAFETY DATA SHEET

PRODUCT

NALCO

NALCO2895 PLUS

Emer,qency Telephone Number Medical (800) 462-5378(24 hours)

(800) I-M-ALERT do not

CAUTION: If unconscious, having trouble breathing induce vomiting or give water. SECTION 05 FIRE FIGHTING MEASURES FLASH POINT: EXTINGUISHING None (PMCC) ASTM D-93

or in convulsions,

MEDIA: Not applicable

UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve SOx under fire conditions. SECTION 06 ACCIDENTAL RELEASE MEASURES IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONENUMBER (800) I-M-ALERTor (800) 462-5378. SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 15. Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 15. For large indoor spills, evacuate employees and ventilate area. Those responsible for control and recovery should wear the protective equipment specified in Section 8 SECTION 07 HANDLING AND STORAGE Storage : Keep container closed when not in use.

SECTION 08 EXPOSE~E CONTROLS AND PERSONAL PROTECTION RESPIRATORY PROTECTION: If it is possible to generate significant levels of vapors or mists, a NIOSH approved or equivalent respirator is recommended. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a positive pressure, self-contained breathing apparatus is recommended. VENTILATION: General ventilation is recommended. Additionally, local exhaust ventilation is recommended where vapors or mists may be released. PROTECTIVE EQUIPMENT: Use impermeable gloves and chemical splash goggles when attaching feeding equipment, doing maintenance or handling product. Examples of impermeable gloves available on the market are neoprene, nitrile, PVC, natural rubber, viton, and butyl (compatibility studies have not been performed). The availability of an eye wash fountain and safety shower is recommended.

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7 NAPERVILLE,ILLINOIS 60563-1198

NALCO CHEMICAL COMPANY ONE NALCO CENTER ° AREA(630) 305-1000

MATERIALSAFETY DATA SHEET NALCO

I

PHYSICAL AND CHEMICAL PROPERTIES

PRODUCT NALCO 2895 PLUS

Emerqenc¥ Telephone Number Medical (800) 462-5376 (24 hours) If clothing is contaminated, remove affected area. Launder contaminated clothing clothing and thoroughly before reuse. wash

(800) the

I-M-ALERT

HUMAN EXPOSURE CHARACTERIZATION: Based on Nalco's application and our recommended personal protective the potential human exposure is: MODERATE. SECTION 09

recommended equipment,

product

COLOR: ODOR: DENSITY: SOLUBILITY IN WATER: SPECIFIC GRAVITY: pH (NEAT) FLASH POINT: NOTE: SECTION These I0 physical

Clear, colorless to light Slight sulfur dioxide 9.6-10.0 Ibs/gal. Completely 1.16-1.20 @ 77 Degrees F 6.5-7.0 None (PMCC) properties are typical values

yellow

FORM:

Liquid

ASTM ASTM ASTM for this

D-1298 E-70 D-93

product.

STABLILITYAND

REACTIVITY

INCOMPATIBILITY: Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. Avoid contact with strong acids (eg. sulfuric, phosphoric, hydrochloric, chromic, sulfonic) which can generate heat, boiling and the release of toxic fumes. nitric, splattering

or

STORAGE: Evolves sulfur dioxide when open to atmosphere. The rate of sulfur dioxide evolution increases with temperature and/or transfer of product. Sulfur dioxide may react with vapors from neutralizing amines, and may produce a visible cloud of amine salt particulate. THERMAL formed. SECTION TOXICITY DECOMPOSITION PRODUCTS: In the event Do not breathe smoke or fumes. Wear ii TOXICOLOGICAL STUDIES: INFORMATION studies have on our been conducted on this product. of combustion, SOx, suitable protective H2S may be equipment.

No toxicity

HUMAN HAZARD CHARACTERIZATION: Based the potential human hazard is: LOW

hazard

characterization,

SECTION

12 ECOLOGICAL into the

INFORMATION environment, see CERCLA in Section 15.

If released

ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION: Based on our Hazard Characterization, the potential environmental hazard is: LOW. Based on Nalco's recommended product application and the product's characteristics, the potential environmental exposure is: MODERATE.

PAGE NALCO CHEMICAL COMPANY

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ONE NALCO CENTER ¯ AREA (630) 3051000

MATERIALSAFETY DATA SHEET

PRODUCT

NALCO

NALCO2895 PLUS

Emerqency Telephone Number Medical (800) 462-5378 (24 hours)

(800)

I-M-ALERT

SECTION

13 DISPOSAL

CONSIDERATIONS a

DISPOSAL: hazardous (RCRA) 40 nor is it

If this product becomes a waste, it does not meet the criteria of waste as defined under the Resource Conservation and Recovery Act CFR 261, since it does not have the characteristics of Subpart listed under Subpart D.

As a non-hazardous liquid waste, it should be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to an industrial waste landfill. A non-hazardous liquid waste can also be deep-well injected in accordance with local, state and federal regulations. SECTION 14 TRANSPORTATION INFORMATION CLASS MAY VARY BY PACKAGING, PROPERTIES, TYPICAL PROPER SHIPPING NAMES FOR THIS

PROPER SHIPPING NAME/HAZARD AND MODE OF TEANSPORTATION. PRODUCT ARE: ALL TRANSPORTATION MODES :

PRODUCT IS NOT REGULATED DURING TRANSPORTATION

SECTION The

15 REGULATORY

INFORMATION apply to this product.

following

regulations

FEDERAL

REGULATIONS:

OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredient hazardous and the reason is shown below. Sodium sulfite = Irritant Potassium sulfite - Irritant Sulfur dioxide = TWA 2 ppm, STEL 5 ppm ACGIH/TLV 5 mg/m3 I0 mg/m3 ACGIH/TLV 2 ppm, STEL 5 ppm OSHA/PEL 5 mg/m3 i0 mg/m3 OSHA/PEL

in this

product

is

Sulfur

dioxide

= TWA

CERCLA/SUPERFUND, 40 CFR 117, 302: Notification of spills of this product SARA/SUPERFUND (TITLE III)-

is not

required. ACT OF 1986

AMENDMENTS AND REAUTHORIZATION SECTIONS 502, 311, 312 AND 313:

SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 This product does not contain ingredients listed Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET

CFR 355): in Appendix

A and

B as an

REQUIREMENTS

(40

CFR 370):

PAGE NALCO CHEMICAL COMPANY

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7 NAPERVILLE, ILLINOIS 60563-1198

ONE NALCO CENTER ¯ AREA (630) 305-1000

MATERIALSAFETY DATA SHEET

PRODUCT

NALCO

NALCO 2895 Emerqency Telephone Number Medical (800)462-5378 hours) (24

PLUS

(800) I-M-ALERT

product

Our hazard evaluation has found this product to be hazardous. should be reported under the followlng EPA hazard categories: XX ----Immediate (acute) health hazard Delayed (chronic) health hazard Fire hazard Sudden release of pressure hazard Reactive hazard

The

under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals. The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals. SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients on the List TOXIC SUBSTANCES CONTROL The chemical ingredients (40 CFR 710). ACT (TSCA): in this product

of Toxic

Chemicals.

are

on the

8(b)

Inventory

List

FOOD AND DRUG ADMINISTRATION (FDA): Federal Food, Drug and Cosmetic Act: When use situations necessitate compliance with FDA regulations, product is acceptable under 21 CFR 173.310 - for use in boilers steam from treated boilers may contact food. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), Consult Section 13 for RCRA classification. 40 CFR 261 SUBPART

this where

C &

FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): None of the ingredients are specifically listed. CLEAN This STATE AIR ACT, Sec. iii (40 CFR 60), Sec. Sec. 611 (40 CFR 82, CLASS does not contain ingredients

40 CFR

401.15

product

112 (40 CFR 61, 1990 Amendments), I and II Ozone depleting substances): covered by the Clean Air Act.

REGULATIONS: 65: contain 65.

CALIFORNIA PROPOSITION This product does not California Proposition

any

chemicals

which

require

warning

under

MICHIGAN CRITICAL MATERIALS: This product does not contain Materials Register. STATE RIGHT TO KNOW LAWS: This product does not contain INTERNATIONAL This REGULATIONS: controlled

ingredients

listed

on the

Michigan

Critical

ingredients

listed

by State

Right

To Know

Laws.

is a WHMIS

product

under

The

House

of Commons

of Canada

Bill

PAGE NALCO CHEMICAL COMPANY

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ONE NALCO CENTER " AREA (630) 305-1000

MATERIALSAFETY DATA SHEET

PRODUCT

NALCO

I

CAS INFORMATION FHDT31196

NALCO2895 PLUS

Emerqency Telephone Number Medical (800) 462-5378 (24 hours)

(800)

I-M-ALERT

C-70 (Class D2B). The product contains the following substance(s), from Ingredient Disclosure List or has been evaluated based on its toxicological properties, to contain the following hazardous ingredient(s): Chemical Name # % Concentration 10-20 1-5 Range

Sodium sulfite Potassium sulfite SECTION Nalco 16 OTHER internal 17 RISK

7757-83-7 10117-38-1

number

SECTION

CHARACTERIZATION

Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and exposures of this product. Based on our recommended use of this product, we have characterized the product's general risk. This information should provide assistance for your own risk management practices. We have evaluated our product's risk as follows: * * The human risk is: LOW. risk is: LOW.

The environmental

Any use inconsistent with Nalco's recommendations may affect our risk characterization. Our sales representative will assist you to determine if your product application is consistent with our recommendations. Together we can implement an appropriate risk management process. This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information. SECTION 18 REFERENCES Limit Values for Chemical Substances and Physical Agents Exposure Indices, American Conference of Governmental Hygienists, OH. and

Threshold Biological Industrial

Hazardous Substances Data Bank, National Library of Medicine, Maryland (CD-ROM version), Micromedex, Inc., Englewood, CO.

Bethesda,

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer. Integrated Washington, Risk Information System, U.S. Environmental Protection Agency, D.C. (CD-ROM version), Micromedex, Inc., Englewood, CO.

PAGE NALCO CHEMICAL

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7 ILLINOIS 60563-1198

COMPANY ONE NALCO CENTER ¯ NAPERVILLE, AREA (630) 305-1000

MATERIALSAFETY DATA SHEET

PRODUCT

NALCO

IIII

NALCO2895 PLUS

Emerqency Telephone Number Medical (800) 462-5378(24 hours)

(800) I-M-ALERT

Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service. Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, Ohio (CD-ROM version), Micromedex, Inc., Englewood, CO. Shepard's Catalog of Teratogenic Agents (CD-ROM version), Micromedex, Inc., Englewood, CO. Suspect Chemicals Sourcebook (a guide to industrial chemicals covered under major regulatory and advisory programs), Roytech Publications (a Division of Ariel Corporation), Bethesda, MD. The Teratogen Information System, University of Washington, Seattle, Washington (CD-ROM version), Micromedex, Inc., Englewood, CO.

PREPARED BY: William S. Utley, PhD., DABT, Manager, Product Safety DATE CHANGED: '0572"0/~998 ~ DATE PRINTED: 03/28/1999

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NALCO CHEMICAL COMPANYONE NALCO CENTER ° NAPERVILLE, AREA(630) 305-1000

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