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Material Safety Data Sheet

Material Name: ALODINE 871 TOUCH-N-PREP COATIN ID: RS00223178 / IDH No. 887197

* * * Section 1 - Chemical Product and Company Identification * * *

Product Trade Name ALODINE 871 TOUCH-N-PREP COATIN

Manufacturer Information

Henkel Surface Technologies Henkel Corporation 32100 Stephenson Highway Madison Heights, MI 48071 Contact Phone: (248) 583-9300 Chemtrec Emergency # (800) 424-9300

* * * Section 2 - Composition / Information on Ingredients * * *

CAS # 7788-97-8 Proprietary Component Chromic fluoride Zirconium compound Percent 1-10 <1

Component Related Regulatory Information

This product may be regulated, have exposure limits or other information identified as the following: Chromium compounds, Fluorides, Chromium, inorganic compounds, Zirconium compounds, n.o.s..

* * * Section 3 - Hazards Identification * * *

Emergency Overview:

WARNING! EYE AND SKIN IRRITANT. This product may be harmful or fatal if it is swallowed, inhaled or in contact with the skin.

Eye Contact:

Contact can cause moderate to severe irritation and possible injury to the eyes.

Skin Contact:

Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis. Product contains chromium, which may cause an allergic skin sensitization reaction. Massive overexposures may lead to kidney failure and death.

Skin Absorption:

A component in this product may be absorbed through the skin in harmful amounts.

Ingestion:

Acute ingestion may result in mild gastrointestinal distress. This product may be harmful if it is swallowed.

Inhalation:

This product may cause irritation to the respiratory system. The repeated breathing of this material for years may cause fluorosis.

Medical Conditions Aggravated by Exposure:

Pre-existing eye, skin and respiratory disorders.

* * * Section 4 - First Aid Measures * * *

Eye Contact:

In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention.

Skin Contact:

Immediately take off all contaminated clothing. For skin contact, flush with large amounts of water. Seek immediate medical attention. If irritation persists, repeat flushing and get medical attention. Discard any shoes or clothing items that cannot be decontaminated.

Ingestion:

If the material is swallowed, get immediate medical attention or advice -- Do not induce vomiting. Give one to two glasses of water or milk. Never give anything by mouth to a victim who is unconscious or is having convulsions.

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Page 1 of 6 Issue Date: 09/21/06 Revision: 1.0101

Material Safety Data Sheet

Material Name: ALODINE 871 TOUCH-N-PREP COATIN ID: RS00223178 / IDH No. 887197

Inhalation:

If mist or vapor of this product is inhaled, remove person immediately to fresh air. Seek medical attention if symptoms develop or persist.

First Aid: Notes to Physician

Treatment of hypocalcemia associated with fluoride exposure may be corrected by intravenous calcium gluconate or calcium chloride. Treatment of hypomagnesemia may be corrected by intravenous magnesium sulfate.

* * * Section 5 - Fire Fighting Measures * * *

Flash Point: Upper Flammable Limit (UFL): Not applicable Not applicable Method Used: Lower Flammable Limit (LFL): Not applicable Not applicable Flammability Classification: Not applicable

Fire & Explosion Hazards:

This product is an aqueous mixture which will not burn.

Extinguishing Media:

Use any media suitable for the surrounding fires.

Fire-Fighting Instructions:

Firefighters should wear full protective clothing including self contained breathing apparatus.

* * * Section 6 - Accidental Release Measures * * *

Containment Procedures:

Stop the flow of material, if this is without risk. Wear appropriate protective equipment and clothing during cleanup.

Clean-Up Procedures:

Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of collected material according to regulation.

* * * Section 7 - Handling and Storage * * *

Handling Procedures:

Do not get this material in your eyes, on your skin, or on your clothing. Wash thoroughly after handling. Do not inhale vapors or mists of this product. Do not take internally. For industrial use only.

Storage Procedures:

Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Store below 110 ºF (43.3 ºC). Thaw and mix thoroughly if frozen.

* * * Section 8 - Exposure Controls / Personal Protection * * *

Exposure Guidelines:

A: General Product Information

Follow all applicable exposure limits.

B: Component Exposure Limits

Chromic fluoride (7788-97-8)

ACGIH: OSHA: 2.5 mg/m3 TWA (as F) (related to Fluorides) 2.5 mg/m3 TWA (as F) (related to Fluorides)

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Page 2 of 6 Issue Date: 09/21/06 Revision: 1.0101

Material Safety Data Sheet

Material Name: ALODINE 871 TOUCH-N-PREP COATIN

Zirconium compound (Proprietary)

ACGIH: OSHA: NIOSH: 5 mg/m3 TWA (as Zr) (related to Zirconium compounds) 10 mg/m3 STEL (as Zr) (related to Zirconium compounds) 5 mg/m3 TWA (as Zr) (related to Zirconium compounds) 10 mg/m3 STEL (as Zr) (related to Zirconium compounds, n.o.s.) 5 mg/m3 TWA (as Zr, except Zirconium tetrachloride) (related to Zirconium compounds) 10 mg/m3 STEL (as Zr, except Zirconium tetrachloride) (related to Zirconium compounds)

ID: RS00223178 / IDH No. 887197

Engineering Controls:

Ventilation should effectively remove and prevent buildup of any vapor or mist generated from the handling of this product.

PERSONAL PROTECTIVE EQUIPMENT

As prescribed in the OSHA Standard for Personal Protective Equipment (29 CFR 1910.132), employers must perform a Hazard Assessment of all workplaces to determine the need for, and selection of, proper protective equipment for each task performed.

Eyes/Face Protective Equipment:

Wear chemical goggles; face shield (if splashing is possible).

Skin Protection:

Use impervious gloves. Gloves should be tested to determine suitability for prolonged contact. Use of impervious apron and boots are recommended.

Respiratory Protection:

If ventilation is not sufficient to effectively prevent buildup of aerosols or vapors, appropriate NIOSH/MSHA respiratory protection must be provided.

Work Practices:

Eye wash fountain and emergency showers are recommended.

* * * Section 9 - Physical & Chemical Properties * * *

Physical State: Odor: Vapor Density: Specific Gravity: Viscosity: Solubility Water: Percent Volatile: Liquid Slight acidic Not determined 1.00 - 1.05 400.00 mPas Complete Not applicable Appearance: Vapor Pressure: Boiling Point: pH: VOC: Evaporation Rate: Percent Solids: Dark green Not determined >212 ºF (>100 ºC) 3.8 - 4.2 @ 72 ºF (22 ºC) Not applicable Not determined < 5.0%

* * * Section 10 - Chemical Stability & Reactivity Information * * *

Chemical Stability:

Stable under normal conditions.

Incompatibility:

This product may react with strong oxidizing agents.

Decomposition Products:

May liberate hydrogen fluoride.

Hazardous Polymerization:

Will not occur.

* * * Section 11 - Toxicological Information * * *

Acute Toxicity:

A: General Product Information

No information available for the product.

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Page 3 of 6 Issue Date: 09/21/06 Revision: 1.0101

Material Safety Data Sheet

Material Name: ALODINE 871 TOUCH-N-PREP COATIN B: Component Analysis - LD50/LC50

No LD50/LC50's are available for this product's components.

ID: RS00223178 / IDH No. 887197

Carcinogenicity:

A: General Product Information

No information available for the product.

B: Component Carcinogenicity

Chromic fluoride (7788-97-8)

ACGIH: A4 - Not Classifiable as a Human Carcinogen (related to Fluorides)

Zirconium compound (Proprietary)

ACGIH: A4 - Not Classifiable as a Human Carcinogen (related to Zirconium compounds)

Chronic Toxicity

Chronic fluoride exposure can produce fluorosis, a condition characterized by nausea, vomiting, loss of appetite, diarrhea or constipation, anemia, weakness, and joint stiffness.

Epidemiology:

No information available for the product.

Neurotoxicity:

No information available for the product.

Mutagenicity:

No information available for the product.

Teratogenicity:

No information available for the product.

Other Toxicological Information:

None available.

* * * Section 12 - Ecological Information * * *

Ecotoxicity:

A: General Product Information

No data available for this product.

B: Component Analysis - Ecotoxicity - Aquatic Toxicity

No ecotoxicity data are available for this product's components.

Environmental Fate:

No data is available concerning the environmental fate, biodegradation or bioconcentration for this product.

* * * Section 13 - Disposal Considerations * * *

US EPA Waste Numbers & Descriptions:

A: General Product Information

This product contains chromium which is a hazardous waste (D007).

B: Component Waste Numbers

No EPA Waste Numbers are applicable for this product's components.

Disposal Instructions:

Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.

* * * Section 14 - Transportation Information * * *

US DOT Information

Shipping Name: Please refer to the container label for transportation information.

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Page 4 of 6 Issue Date: 09/21/06 Revision: 1.0101

Material Safety Data Sheet

Material Name: ALODINE 871 TOUCH-N-PREP COATIN ID: RS00223178 / IDH No. 887197

* * * Section 15 - Regulatory Information * * *

US Federal Regulations

A: General Product Information

This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).

B: Component Analysis

None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), or CERCLA (40 CFR 302.4). SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No Reactive: No

State Regulations

A: General Product Information

No additional information available.

B: Component Analysis - State

The following components appear on one or more of the following state hazardous substances lists:

Component Chromic fluoride (¹related to Chromium compounds) Zirconium compound (¹related to Zirconium compounds) CAS # 7788-97-8 Proprietary CA Yes¹ Yes¹ FL No No MA No No MN No Yes¹ NJ Yes No PA Yes¹ No

Other Regulations

A: General Product Information

All components are on the U.S. EPA TSCA Inventory List.

B: Component Analysis - Inventory

Component Chromic fluoride Zirconium compound CAS # 7788-97-8 Proprietary TSCA Yes Yes DSL Yes Yes EINECS Yes Yes

C: Component Analysis - WHMIS IDL

No components are listed in the WHMIS IDL.

* * * Section 16 - Other Information * * *

NFPA Ratings: Health: 2 Fire: 0 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe HMIS Ratings: Health: 2* Fire: 0 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard

Key/Legend

EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration; NFPA = National Fire Protection Association; HMIS = Hazardous Material Identification System; CERCLA = Comprehensive Environmental Response, Compensation and Liability Act; SARA = Superfund Amendments and Reauthorization Act The information presented herein is believed to be factual as it has been derived from the works and opinions of persons believed to be qualified experts; however, nothing contained in this information is to be taken as a warranty or representation for which Henkel Surface Technologies bears legal responsibility. The user should review any recommendations in the specific context of the intended use to determine whether they are appropriate. Contact: Product Safety and Regulatory Affairs Contact Phone: (248) 583-9300

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Page 5 of 6 Issue Date: 09/21/06 Revision: 1.0101

Material Safety Data Sheet

Material Name: ALODINE 871 TOUCH-N-PREP COATIN ID: RS00223178 / IDH No. 887197

This is the end of MSDS # RS00223178 / IDH No. 887197

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Page 6 of 6 Issue Date: 09/21/06 Revision: 1.0101

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