Read 2008_IndustrialLubricants_Newsroom_Brochures_MetalWorkingProductRange.pdf text version

Clariant International Ltd. Functional Chemicals Division Marketing Metal Working 4132 Muttenz Switzerland Phone +41 61 46 978 11 Fax +41 61 46 975 512 Clariant Produkte (Deutschland) GmbH Functional Chemicals Division Research & Development Metal Working 65926 Frankfurt am Main Germany Phone +49 69 305 66 07 Fax +49 69 303 299 Internet http://www.clariant.com

fuenfwerken.com | EBR 5276 | 09.2008

Functional Chemicals Division

Products for Metal Working Fluids Product Information Update Summer 2008

Product Information

Update Spring 2008

Products for Metal Working Fluids

12 Glossary

Package Abbreviations

MEA DEA TEA EO PO APEO TBN m.p. m.r. HLB Monoethanolamine Diethanolamine Triethanolamine Ethylene oxide Propylene oxide Alkylphenol ethoxylate Total base number melting point melting range Hydrophilic-lipophilic-balance A package is a stable pre-formulation of different emulsifiers, corrosion inhibitors and EP / AW additives if needed. In combination with suitable mineral oils, packages can be easily applied by enduser to formulate concentrates and / or emulsions using a co-emulsifier for adjustment.

Content

> Product names in alphabetical order Introduction Products at a glance 1 1.1 1.1.1 1.1.2 1.1.3 1.1.4 1.2 2 2.1 2.1.1 2.1.2 2.1.3 2.1.4 2.2 3 3.1 3.2 Anionic emulsifiers / Corrosion inhibitors for soluble oils and semisynthetics Alkenyl succinic acid derivatives Alkenyl succinic acid anhydrides Alkenyl succinic acid halfamides, imidocaproic acids, halfesters Alkenyl succinic acid derivative packages Packages / Others Ether carboxylates Nonionic emulsifiers Nonionics Nonylphenol oxethylates Tristyrylphenol oxethylates Fatty alcohol oxethylates Fatty acid oxethylates Fatty acid esters Fatty acid alkanol amides Fatty acid diethanolamides Fatty acid alkanolamides / DEA free > Page 04

> 06 > 08 ­ 21

Storage time

The standard storage time for the products listed in this brochure is in general two years. If special storage conditions are necessary it is mentioned in the column "Remarks".

> > > > > > >

23 24 24 24 26 26 28

DEA-content

This remark refers to the column "DEA-content". The DEA content is given, when DEA is used as a neutralizing or reaction agent. If nothing mentioned there, the product contains no DEA at all or other neutralizing agents (e.g. MEA, TEA, alkali) are used.

APEO-content

In general all products mentioned in the brochure are free of alkylphenol ethoxylates. Exceptions are marked in the column "Remarks" with a notice: "APEO-containing".

> 31 > 32 > 32 > 32 > 32 ­ 35 > 36 > 36 > > > 39 40 40

Lime soap dispersing power, K-value

The lime soap dispersing power of some products is listed as K-value (according to the withdrawn DIN-method 53 903). The K-value is a degree for the amount of Ca-oleate which is dispersed by 1g of resp. emulsifier. The higher the K-value, the higher the lime soap dispersing power.

>

79

> Page 4 4.1 4.2 5 6 6.1 6.2 6.3 Water soluble corrosion inhibitors and lubricants Water soluble corrosion inhibitors Water soluble lubricants Oil soluble corrosion inhibitors Lubricants and EP-Additives Esters Phosphoric acid esters Polyalkylene / Polyethylene glycols see chapter 11 Brochures / Other ranges Cleaners Fatty alcohol oxalkylates Corrosion inhibitors / Specialities Solvents see chapter 11 Brochures / Other ranges Defoamers Biocides Others Dewatering fluids Amines 11 11.1 11.2 11.3 11.4 11.5 12 Brochures / Other ranges Raw Materials for the Chemo-Technical Industry Fatty Amines and Derivatives Glymes / glycol diethers Polyalkylene / Polyethylene glycols Hordaphos (phosphoric acid esters) Glossary

> Page > > > > > > > 78 78 78 78 78 78 79

> 43 > 44 ­ 47 > 46 > 49­ 51

> 53 > 54 > 56 ­ 59 > > > > > > 78 61 62 64 64 78

7 7.1 7.2 7.3

8 9 10 10.1 10.2

> 67 ­ 69 > 71 ­ 73 > > > 75 76 76

This information is based on our present state of knowledge and is intended to provide general notes on our products and their uses. It should not therefore be construed as guaranteeing specific properties of the products described on their suitability for a particular application. Any existing industrial property rights must be observed. The quality of our products is guaranteed under our General Conditions of Sale. > 03

Product names in alphabetical order

A Aicrobat N Antimussol 3472 N Antimussol 4459 liq. Antimussol 4752 liq. Antimussol FN Antimussol TIP Antimussol ZJ Appretan Defoamer 5084 liq. Appretan Defoamer 5342 liq. Arkomon SO Arkopal N 040 Arkopal N 060 Arkopal N 090 D Dodicor 2565 Dodicor 2725 NF Dodigen 95 Dispersogen SP 040 E Emulsogen 3971 Emulsogen 3980 Emulsogen 4616 Emulsogen 4617 Emulsogen 5126 MW Emulsogen 5690 Emulsogen A Emulsogen A 060 Emulsogen CIO 050 Emulsogen CNH 030 Emulsogen CNO 080 Emulsogen COA 070 Emulsogen COL 020 Emulsogen COL 050 Emulsogen COL 080 Emulsogen COL 100 Emulsogen CTS 100

> Page E > 74 > 68 > 68 > 68 > 68 > 68 > 68 > 68 > 68 > 52 > 32 > 32 > 32 > > > > > > > > > > > > > > > > > > > > > 64 64 64 56 26 26 28 28 24 24 36 36 28 28 28 28 28 28 28 28 28 G

Emulsogen CTS 160 Emulsogen EL 360 Emulsogen ELO 200 Emulsogen ENF Emulsogen LP Emulsogen M Emulsogen MS 12 Emulsogen MT 050 Emulsogen OG Emulsogen P Emulsogen T Emulsogen TS 100 Emulsogen TS 160 Genagen IS 140 Genagen O 100 Genamin 3920 Genamin 8 R 100 D Genamin CH 020 Genamin NO 050 Genamin SH 100 D P Genapol B Genapol BA 040 Genapol EP 0244 Genapol EP 2424 Genapol EP 2464 Genapol EP 2544 Genapol EP 2552 Genapol EP 2564 Genapol EP 2584 Genapol O 020 Genapol O 050 Genapol PN 30 Genapol PS Genapol RX 065

> Page > 28 > 36 > 36 > 76 > 34 > 34 > 34 > 40 > 36 > 34 > 26 > 32 > 32 > > > > > > > > > > > > > > > > > > > > > 36 36 76 76 76 76 76 46 62 62 62 62 62 62 62 62 32 32 46 46 34

H Hicor BAT Hicor C Hordaphos 124 Hordaphos 125 Hordaphos 145 Hordaphos 222 Hordaphos DEOD Hordaphos MDAH Hordaphos MDB Hordaphos MDGB Hordaphos MDHX Hordaphos MDIT Hordaphos MDO Hostacor 1102 Hostacor 2732 Hostacor 3928 Hostacor 3981 Hostacor 4053 Hostacor 4053 SEO Hostacor 4154 Hostacor 4221 Hostacor 4222 Hostacor 4323 Hostacor 4359 Hostacor B Hostacor BI Hostacor BIT Hostacor DT Hostacor IS Hostacor IT Hostacor L Hostacor MT Hostacor MTF Hostacor PSO 300 Hostacor V 4188 Hostagliss A

> Page H > 40 > 40 > 56 > 56 > 56 > 56 > 56 > 56 > 56 > 58 N > 58 > 58 > 58 > 46 > 44 > 24 > 24 > 44 > 44 S > 26 > 24 > 26 > 24 > 26 > 44 > 46 > 46 > 40 > 44 > 44 > 24 > 40 > 40 > 50 > 40 > 54

Hostagliss DHSZ Hostagliss FN Hostagliss H Hostagliss L4 Hostagliss PA 135 Hostagliss PA 165 Hostaphat OPS 100 Hostaphat OPS 80 P Hostaphat TBEP Nipacide BIT 20 Nipacide CI Nipacide FC Nipacide HTP/2 Nipacide IPBC 20 Nipacide IPBC 30 Nipacide MBM Nipaclean 3 Sodium Omadine 40%

> Page > 54 > 54 > 54 > 54 > 54 > 54 > 64 > 64 > 58 > > > > > > > > > 72 72 72 72 72 72 72 72 72

>

> 2

05

Introduction

Nonylphenol / Nonylphenol ethoxylate Directive 2003/53/EC In general all products mentioned in the brochure are free of alkylphenols and alkylphenol ethoxylates (esp. nonylphenols and nonylphenol ethoxylates). Exceptions are marked in the column "Remark" with notice: "APEO-containing" and are use restricted according to Directive 2003/53/EC effective from 17 January 2005. See also: http://eur-lex.europa.eu/pri/en/oj/dat/2003/l_178/l_17820030717en00240027.pdf

Clariant is one of the world's leading manufacturers of surfactants and auxiliaries.

Clariant is a global leader in the field of speciality chemicals. The Functional Chemicals Division serves a wide range of industries e.g. Personal Care, Coating and Construction, Detergents and Oil, Gas and the Mining industry. For Metal Working Clariant supplies: < corrosion inhibitors < emulsifiers < lubricants < cleaners < defoamers < dewatering fluids < biocides < ep / aw- additives

The base materials for these surfactants and raw materials are from both renewable and petrochemical sources. What is common to all products is their high quality standard, which is achieved through intensive research and development, modern production methods with constant quality monitoring and customer-oriented applications technology, and this standard is continuously improved. Over and above the product range, we offer assistance to find specific solutions to solve problems, either through advice or through related development work in the laboratory. Biocides For EEC (Europe): Based on our information (status April 2008) all mentioned biocides are in compliance with the BPD 98/8/EC and amendments/corrections. This information is based on the current situation and Clariant reserves the right to modify the support if the data requirements change or the market position alters. See also: http://ecb.jrc.it/biocides/ For Germany: Biozide sicher verwenden. Vor Gebrauch stets Kennzeichnung und Produktinformation lesen.

REACH According to Regulation (EC) No. 1907/2006 (REACH), the manufacture or import of chemical substances in volumes exceeding 1 ton per year must be registered at the European Chemicals Agency (ECHA) in Helsinki. REACH registration is related to substances and not products, e.g. preparations/formulations of substances. Production, import and marketing of a REACH-substance will be restricted to those uses evaluated in its registration dossier. The REACH process starts with preregistration (1st June 2008 until 1st December 2008), which assures the availability of preregistered substances to the registration date. The date of registration depends on the production volume of the substance and lies between 2010 and 2018. We confirm that we will pre-register all substances manufactured by Clariant Division FUN in the EU or imported in the EU, which are relevant for the products listed in this brochure. However, no promise can be given that Clariant will offer all listed products over the 11 year phase of the REACH implementation. If REACH registration requires unacceptable costs, Clariant will contact its customers to find an appropriate solution.

New Products

< Antimussol 3472 N < Appretan Defoamer 5084 liq. < Appretan Defoamer 5342 liq. < Emulsogen 5690 < Genamin NO 050

> Page

> > > > > 68 68 68 24 76 < Genagen IS 140 < Genapol BA 040 < Genapol RX 065 < Hordaphos DEOD < Hostaphat TBEP

> Page

> > > > > 36 62 34 56 56 < Hostagliss L4 < Nipaclean 3 < Nipacide BK < Nipacide HPT/2 < Sodium Omadine 40%

> Page

> > > > > 54 72 72 72 72

Changed products (from Update Winter 2004/2005)

<Aicamide N deleted <Aicamide 2067 deleted <Aicamide 2131/B deleted <Aicrobat N deleted and replaced by Nipacide BK <Antimussol 3472 deleted and replaced by Antimussol 3472 N < Antimussol 4846 deleted and replaced by Appretan Defoamer 5342 <Emulsogen 5171 deleted <Emulsogen AL deleted <Emulsogen COL 090 deleted, recommended alternative Emulsogen COL 080 or COL 100 < Emulsogen E deleted and replaced by Emulsogen ENF < Emulsogen MR deleted < Emulsogen PN extra deleted < Emulsogen PSP 123 deleted < Emulsogen SFO deleted < Emulsogen SBL deleted < Emulsogen TS 050 deleted < Genamin 4048 deleted < Genamin 5577 deleted < Genamin 18 R 100 D deleted < Genamin SH 100 D FLA modified and renamed Genamin SH 100 D P (Pellets) < Genapol 2822 renamed to Genapol EP 0244 < Genapol 2808 renamed to Genapol EP 2564 < Genapol 2809 renamed to Genapol EP 2584 < Genapol 3938 renamed Genapol EP 2464 < Genapol 3970 renamed to Genapol EP 2424 < Genapol EP 2454 deleted < Genapol OA 020 deleted < Genapol GX 030 deleted < Genapol X 020 deleted < Genopurl ASA deleted < Highsorb GD deleted < Highsorb GF deleted < Hostacor V 5233 deleted < Hostacor 5428 deleted < Hostacor GLA 1 deleted < Hostacor IPT deleted < Hostacor IC deleted < Hostagliss 1090 deleted < Hostagliss D deleted < Hostagliss DHV deleted < Hordaphos 123 deleted < Hordaphos 185 renamed to Dispersogen SP 040 < Hordaphos AW 100 deleted < Hordaphos EP 300 deleted < Hostamer AM deleted < Nipacide HTP/3 replaced by Nipicide HTP/2 < Nipacide SP replaced by Sodium Omadine 40% < Nipaclean 2 replaced by Nipaclean 3

Antimussol®, Appretan Defoamer®, Arkomon®, Arkopal®, Dispersogen®, Dodicor®, Dodigen®, Emulsogen®, Genagen®, Genamin®, Genapol®, Genopur®, Hordaphos®, Hostacor®, Hostagliss®, Hostaphat® and Nipacide® are registered trademarks in numerous countries and licensed to Clariant. Detergent Regulation EC 648/2004 and EC 907/2006 According to the Detergent Regulation Surfactants used in detergents (cleaners etc.) have to show an ultimate biodegradation above given minimum limits according to EC648/2004. The determination methods, minimum ultimate biodegradation limits and test report quality requirements are provided by the regulation. Producers state the compliance with the EU Detergent Regulation with phrases in the EU safety data sheet (EU-SDS) Chapter 12 or 15. Products with a compliance phrase in the EU-SDS show in the column remarks the abbreviation: "DR +". See also: http://eur-lex.europa.eu/LexUriServ/site/en/oj/2004/l_104/l_10420040408en00010035.pdf

>

07

Products at a glance

Function Emulsifier Corrosion inhibitor Lubricant

DEA-free

Boron-free

Applications Neat cutting oils Cutting Fluids milky semisynthetic synthetic Corrosion Metal protection oils cleaners Dewatering fluids

> Page

1

1.1

Anionic emulsifiers / Corrosion inhibitors for soluble oils and semisynthetics Alkenyl succinic acid derivatives

1.1.1 Alkenyl succinic acid anhydrides Hostacor L Emulsogen 5126 MW Emulsogen 5690 1.1.2 Alkenyl succinic acid halfamides, imidocaproic acids, halfesters Hostacor 3928 Hostacor 3981 Hostacor 4221 Hostacor 4323 1.1.3 Alkenyl succinic acid derivative packages Hostacor 4222 Emulsogen 3971 Emulsogen 3980 Hostacor 4154 Hostacor 4359 1.1.4 Packages / Others Emulsogen T

> > >

24 24 24

> > > >

24 24 24 24

> > > > > >

26 26 26 26 26

26

most suitable

> 08

suitable

> 09

Products at a glance

Function Emulsifier Corrosion inhibitor Lubricant

DEA-free

Boron-free

Applications Neat cutting oils Cutting Fluids milky semisynthetic synthetic Corrosion Metal protection oils cleaners Dewatering fluids

> Page

1

1.2

Anionic emulsifiers / Corrosion inhibitors for soluble oils and semisynthetics Ether carboxylates Emulsogen CIO 050 Emulsogen CNH 030 Emulsogen CNO 080 Emulsogen COA 070 Emulsogen COL 020 Emulsogen COL 050 Emulsogen COL 080 Emulsogen COL 100 Emulsogen CTS 100 Emulsogen CTS 160 Emulsogen 4616 Emulsogen 4617

> > > > > > > > > > > >

28 28 28 28 28 28 28 28 28 28 28 28

2

2.1

Nonionic emulsifiers Nonionics

2.1.1 Nonylphenol oxethylates Arkopal N 040 Arkopal N 060 Arkopal N 090 2.1.2 Tristyrylphenol oxethylates Emulsogen TS 100 Emulsogen TS 160 2.1.3 Fatty alcohol oxethylates Genapol O 020 Genapol O 050

> > > > > > >

32 32 32

32 32

32 32

>

10

most suitable

suitable

>

11

Products at a glance

Function Emulsifier Corrosion inhibitor Lubricant

DEA-free

Boron-free

Applications Neat cutting oils Cutting Fluids milky semisynthetic synthetic Corrosion Metal protection oils cleaners Dewatering fluids

> Page

2

2.1

Nonionic emulsifiers Nonionics

2.1.3 Fatty alcohol oxethylates Emulsogen M Emulsogen LP Emulsogen MS 12 Emulsogen P Genapol RX 065 2.1.4 Fatty acid oxethylates Emulsogen A Emulsogen A 060 Genagen IS 140 Genagen O 100 Emulsogen EL 360 Emulsogen ELO 200

> > > > >

34 34 34 34 34

> > > > > >

36 36 36 36 36 36

2.2

Fatty acid esters Emulsogen OG

>

36

3

3.1

Fatty acid alkanolamides Fatty acid diethanolamides Hostacor DT Hicor BAT Hicor C

> > > > > > >

40 40 40

3.2

Fatty acid alkanolamides / DEA free Hostacor V 4188 Hostacor MT Hostacor MTF Emulsogen MT 050 40 40 40 40

>

12

most suitable

suitable

>

13

Products at a glance

Function Emulsifier Corrosion inhibitor Lubricant

DEA-free

Boron-free

Applications Neat cutting oils Cutting Fluids milky semisynthetic synthetic Corrosion Metal protection oils cleaners Dewatering fluids

> Page

4

4.1

Water soluble corrosion inhibitors and lubricants Water soluble corrosion inhibitors Hostacor B Hostacor 4053 Hostacor 4053 SEO Hostacor IS Hostacor 2732 Hostacor IT Hostacor BI Hostacor BIT Hostacor 1102

> > > > > > > > >

44 44 44 44 44 44 46 46 46

4.2

Water soluble lubricants Genapol B Genapol PN 30 Genapol PS

> > >

46 46 46

5

Oil soluble corrosion inhibitors

Arkomon SO Hostacor PSO 300

> >

50 50

most suitable

> 14

suitable

> 15

Products at a glance

Function Emulsifier Corrosion inhibitor Lubricant

DEA-free

Boron-free

Applications Neat cutting oils Cutting Fluids milky semisynthetic synthetic Corrosion Metal protection oils cleaners Dewatering fluids

> Page

6

6.1

Lubricants and EP-Additives Esters Hostagliss FN Hostagliss H Hostagliss L4 Hostagliss A Hostagliss DHSZ Hostagliss PA 135 Hostagliss PA 165

> > > > > > > > > > > > > > > > > > > >

54 54 54 54 54 54 54

6.2

Phosphoric acid esters Dispersogen SP 040 Hordaphos 124 Hordaphos 125 Hordaphos 145 Hordaphos 222 Hordaphos DEOD Hordaphos MDAH Hordaphos MDB Hordaphos MDGB Hordaphos MDHX Hordaphos MDIT Hordaphos MDO Hostaphat TBEP 56 56 56 56 56 56 56 56 58 58 58 58 58

6.3

Polyalkylene glycols / Polyethylene glycols see chapter 11 Brochures / Other ranges

>

78

most suitable

> 16

suitable

> 17

Products at a glance

Function Emulsifier Corrosion inhibitor Lubricant

DEA-free

Boron-free

Applications Neat cutting oils Cutting Fluids milky semisynthetic synthetic Corrosion Metal protection oils cleaners Dewatering fluids

> Page

7

7.1

Cleaners Fatty alcohol oxalkylates Genapol EP 0244 Genapol EP 2424 Genapol EP 2464 Genapol EP 2552 Genapol EP 2544 Genapol EP 2564 Genapol EP 2584 Genapol BA 040

> > > > > > > >

62 62 62 62 62 62 62 62

7.2

Corrosion inhibitors / Specialities Dodigen 95 Dodicor 2565 Dodicor 2725 NF Hostaphat OPS 100 Hostaphat OPS 80 P

> > > > > >

64 64 64 64 64 78

7.3

Solvents see chapter 11 Brochures / Other Ranges Defoamers

8

Antimussol 3470 liq. Antimussol 3472 N Antimussol 4459 liq. Antimussol 4752 liq. Antimussol FN Antimussol TIP Antimussol ZJ Appretan Defoamer 5084 liq. Appretan Defoamer 5342 liq.

> > > > > > > > >

68 68 68 68 68 68 68 68 68

most suitable

> 18

suitable

> 19

Products at a glance

Function Emulsifier Corrosion inhibitor Lubricant

DEA-free

Boron-free

Applications Neat cutting oils Cutting Fluids milky semisynthetic synthetic Corrosion Metal protection oils cleaners Dewatering fluids

> Page

9

Biocides

Nipacide BK Nipacide BIT 20 Nipacide CI Nipacide FC Nipacide HTP/2 Nipacide IPBC 20/IPBC 30 Nipacide MBM Nipaclean 3 Sodium Omadine 40%

> > > > > > > > >

72 72 72 72 72 72 72 72 72

10

10.1

Others Dewatering fluids Emulsogen ENF Genamin 8 R 100 D

> >

76 76

10.2

Amines Genamin SH 100 D P Genamin 3920 Genamin NO 050 Genamin CH 020

> > > >

76 76 76 76

most suitable

> 20

suitable

> 21

1 Anionic emulsifiers / Corrosion inhibitors for soluble oils and semisynthetics

> Page 1.1 Alkenyl succinic acid derivatives > > > > > 24 24 24 24 24 1.1.4 Packages / Others Emulsogen T 1.2 Ether carboxylates Emulsogen CIO 050 Emulsogen CNH 030 Emulsogen CNO 080 Emulsogen COA 070 Emulsogen COL 020 Emulsogen COL 050 Emulsogen COL 080 Emulsogen COL 100 Emulsogen CTS 100 Emulsogen CTS 160 Emulsogen 4616 Emulsogen 4617

1.1.1 Alkenyl succinic acid anhydrides Hostacor L Emulsogen 5126 MW Emulsogen 5690 1.1.2 Alkenyl succinic acid halfamides, imidocaproic acids, halfesters Hostacor 3928 Hostacor 3981 Hostacor 4221 Hostacor 4323 1.1.3 Alkenyl succinic acid derivatives packages Hostacor 4222 Emulsogen 3971 Emulsogen 3980 Hostacor 4154 Hostacor 4359

> Page > > > > > > > > > > > > > > > 26 26 28 28 28 28 28 28 28 28 28 28 28 28 28

> > > > >

24 24 24 24 24

> > > > > >

26 26 26 26 26 26

>

23

Emulsifier

Corrosion inhibitor

1.1

Alkenyl succinic acid derivatives

1.1.1 Alkenyl succinic acid anhydrides Hostacor L

Alkenyl succinic acid anhydride / nonionic, anionic as salt brown, clear to turbid, viscous liquid ­ ­ Hostacor L, Emulsogen 5126 MW and Emulsogen 5690 are soluble in mineral oils and insoluble in water. They have to be converted to the corresponding alkali and / or amine / alkanolamine salts by hydrolysis when used in water based metal working fluids. In this form they are stabilizing emulsions and are used as hydrotropes (coupling agents). Contrary to Emulsogen 5126 and Emulsogen 5690, Hostacor L has pronounced wetting properties but is not stable against water hardness. Hostacor L shows good corrosion protection as alkali and / or alkanolamine salt. Hostacor L may become turbid after prolonged storage. The product gets clear again after homogenizing at 70°C.

Emulsogen 5126 MW

Lubricant

1

Anionic emulsifiers / Corrosion inhibitors for soluble oils and semisynthetics

Chemical description / Ionicity

Function

Appearance

DEAcontent (%)

pH (1%) in water

Applications / Properties General aspects Special remarks

Alkenyl succinic acid anhydride / nonionic, anionic as salt Alkenyl succinic acid anhydride / nonionic, anionic as salt

pale brown, viscous liquid brown, viscous liquid

­

­

Emulsogen 5126 MW is solubilized in mineral oil due to its high viscosity (high molecular weight). Emulsogen 5690 is solubilised in a synthetic ester due to its high viscosity (high molecular weight)

Emulsogen 5690 1.1.2 Alkenyl succinic acid halfamides, imidocaproic acids, halfesters Hostacor 3928

­

­

Na / TEA mix salt of an alkenyl succinic acid half amide / anionic

dark brown, clear, viscous liquid

­

8.2 ­ 9.2

Hostacor 3928 is used as emulsifier with corrosion protecting properties for milky / transparent metalworking fluids. The product is clearly soluble in water, dispersible in mineral oils and compatible with non / anionic products. Mineral oil based formulations show no gelation tendency, form spontaneously emulsions and are stable in hard water. Hostacor 3981 and 4221 are used as emulsifiers with corrosion protecting properties for milky / transparent metalworking fluids. The free acids must be neutralized to the alkali and / or alkanolamine salts. Mineral oil based formulations show no gelation tendency, form spontaneously emulsions and are stable in hard water. Both products are compatible with other non / anionic additives. Hostacor 4221 is suitable for formulations with low pH values (approx. 8). Hostacor 4323 is used as emulsifier with corrosion protecting properties for milky amine and nitrogen free metalworking fluids. The product is insoluble in water and soluble in mineral oil. Mineral oil based formulations show no gelation tendency, form spontaneously emulsions and are stable in hard water. The product is compatible with other non / anionic additives.

Storage stability is max. 1 year. Storage temperature should be below 30°C.

Hostacor 3981

Alkenyl succinic imido carboxylic acid / anionic as salt

dark brown, clear, viscous liquid brownish, clear, viscous liquid

­

­

Hostacor 3981 is insoluble in water and slightly turbid dispersible in mineral oil. Product should be stored in a cool place. Hostacor 4221 is insoluble in water and clearly soluble in mineral oil.

Hostacor 4221

Alkenyl succinic imido carboxylic acid / anionic as salt

­

­

Hostacor 4323

Alkenyl succinic acid half ester / anionic as salt

light brown, clear, viscous liquid

­

­

During the neutralization, for instance with 50% aqueous KOH, temperatures above 60°C and a local excess of alkali should be avoided. Storage temperature should be below 30°C.

>

24

>

25

Emulsifier

Corrosion inhibitor

1.1

Alkenyl succinic acid derivatives

1.1.3 Alkenyl succinic acid derivative packages Hostacor 4222

Package based on Na / TEA mix salt of a complex amino carboxylic acid / anionic Package based on Na / TEA mix salt of a complex amino carboxylic acid / anionic Combination of alkenyl succinic acid half amide with nonionics and alkanol amides / anionic, nonionic Corrosion inhibitor package containing boric acid / anionic, nonionic brownish, clear, oily liquid dark brown, clear, oily liquid dark brown, clear, viscous liquid dark brown, clear, viscous liquid ­ 8.5 ­ 9.5 Hostacor 4222 and Emulsogen 3971 are emulsifier packages with good corrosion protecting properties for milky, opaque and transparent metal working fluids. Both products are soluble in water and dispersible in mineral oil. Mineral oil based formulations show no gelation tendency, form spontaneously emulsions and are stable in hard water. Hostacor 4222 and Emulsogen 3971 are very easy and versatile to use for any kind of formulation.

Emulsogen 3971

Lubricant

1

Anionic emulsifiers / Corrosion inhibitors for soluble oils and semisynthetics

Chemical description / Ionicity

Function

Appearance

DEAcontent (%)

pH (1%) in water

Applications / Properties General aspects Special remarks

­

7.5 ­ 9.0

Emulsogen 3980

approx. 10

9.4 ­ 9.8

Product should be stored in a cool place.

Hostacor 4154

­

9 ­ 10

Hostacor 4154 and Hostacor 4359 are corrosion inhibitors and emulsifiers for water miscible metal working fluids. They are largely unaffected by water hardness and are used for milky, opaque and transparent emulsions. Genapol O 020 can be used as co-emulsifier.

Storage stability is max. 6 month in closed containers at temperatures below 30°C. Due to the high boron content the storage of Hostacor 4154 needs certain precautions. Impurities, especially boric acid crystals may lead to irreversible solidification of the product. Storage stability is max. 1 year. Storage temperature max.30° C.

Hostacor 4359

Corrosion inhibitor package containing boric acid / anionic, nonionic

dark brown, clear, viscous liquid

­

9 ­ 10

1.1.4 Packages / Others Emulsogen T

Combination of polyglycol ether and an anionic emulsifier / anionic, nonionic yellow, clear liquid ­ 6­7 Emusogen T is an emulsifier for triglycerides. Cloudiness in the concentrate can be eliminated by adding small amounts of oleic acid.

> 26

>

27

Emulsifier

1.2

Ether carboxylates Emulsogen CIO 050

Ether carboxylic acid (5 EO), nonionic / anionic (as salt) Ether carboxylic acid (3 EO), nonionic / anionic (as salt) Ether carboxylic acid (8 EO), nonionic / anionic (as salt) Ether carboxylic acid (7 EO), nonionic / anionic (as salt) Ether carboxylic acid (2 EO), nonionic / anionic (as salt) Ether carboxylic acid (5 EO), nonionic / anionic (as salt) Ether carboxylic acid (8 EO), nonionic / anionic (as salt) Ether carboxylic acid (10 EO), nonionic / anionic (as salt) Ether carboxylic acid (10 EO), nonionic / anionic (as salt) Ether carboxylic acid (16 EO), nonionic / anionic (as salt) Ether carboxylic acid blend, nonionic / anionic (as salt) Ether carboxylic acid blend, nonionic / anionic (as salt) yellowish, clear liquid ­ 2.0 ­ 3.5 Ether carboxylic acids are based on fatty alcohol oxethylates and exhibit the benefits of anionic and nonionic emulsifiers, especially when they are converted to their salt form, eg. after neutralisation with alkanolamines. Therefore, the Emulsogen C-types are versatile formulating agents, providing high emulsion stability over the complete pH-range, tolerating high content of electrolytes and are stable against water hardness. In general they are easily biodegradable, show low toxicity and excellent skin compatibility. Depending on their structure (type of fatty alcohol, degree of oxethylation), foaming properties, corrosion protection, lime soap dispersing power may differentiate widely from product to product. An overview about these properties is given in the three columns on the right side of this page. As a result of the manufacturing process the products contain max. 1% sodium chloride-typically less. Emulsogen CNO 080 and COL 100 are avialable as low chlorid versions with a sodium chloride content at max. 0,1%. 95 ­ 115 Low Medium Low (<4) Low (<4) Low (<4) High (25) Low (8) Medium (12.5) High (25) Excellent (>25) High (20) High (20) Low (<4) High (25)

Lubricant

Anionic emulsifiers / Corrosion inhibitors for soluble oils and semisynthetics

Corrosion inhibitor

1

Chemical description / Ionicity

Function

Appearance

DEAcontent (%)

pH (1%) in water

Applications / Function

Acid Value mg KOH/g

Foaming tendency

Corrosion inhibiting properties

Lime soap dispersing power 1

Emulsogen CNH 030

colourless, clear liquid colourless, clear liquid

yellowish, clear liquid yellowish, clear liquid yellowish, clear liquid yellowish, dull amber gel yellowish, clear liquid yellowish, clear liquid yellowish, clear liquid yellowish, clear liquid yellowish, clear liquid

­

2.0 ­ 4.0

140 ­ 155

Low

Medium

Emulsogen CNO 080 / 080 LC

­

1.5 ­ 3.0

90 ­ 105

Low

Low

Emulsogen COA 070

­

2.0 ­ 4.0

70 ­ 85

Medium ­ Low Medium ­ Low Medium

Low

Emulsogen COL 020

­

2.0 ­ 4.0

65 ­ 95

High

Emulsogen COL 050

­

2.0 ­ 4.0

75 ­ 85

High

Emulsogen COL 080

­

1.5 ­ 3.0

68 ­ 78

Medium ­ High Medium ­ High High

Low

Emulsogen COL 100 / 100 LC

­

2.5 ­ 3.5

64 ­ 78

Low

Emulsogen CTS 100

­

2.0 ­ 4.0

42 ­ 52

Medium

Emulsogen CTS 160

­

2.0 ­ 4.0

39 ­ 49

High

Low

Emulsogen 4616

­

2.0 ­ 3.5

100 ­ 125

Low

Medium

Emulsogen 4617

­

2.0 ­ 4.0

83 ­ 90

Low

Low

1)

Definition of K-value see glossary

>

28

>

29

2 Nonionic emulsifiers

> Page 2.1 Nonionics > > > > > > > > > > > > > > > > > > > > > > > 32 32 32 32 32 32 32 32 32 32 32 34 34 34 34 34 36 36 36 36 36 36 36

2.1.1 Nonylphenol oxethylates Arkopal N 040 Arkopal N 060 Arkopal N 090 2.1.2 Tristyrylphenol oxethylates Emulsogen TS 100 Emulsogen TS 160 2.1.3 Fatty alcohol oxethylates Genapol O 020 Genapol O 050 Emulsogen M Emulsogen LP Emulsogen MS 12 Emulsogen P Genapol RX 065 2.1.4 Fatty acid oxethylates Emulsogen A Emulsogen A 060 Genagen IS 140 Genagen O 100 Emulsogen EL 360 Emulsogen ELO 200

> Page 2.2. Fatty acid esters Emulsogen OG > > 36 36

Nonylphenol / Nonylphenol ethoxylate Directive 2003/53/EC

In general all products mentioned in the brochure are free of alkylphenols and alkylphenol ethoxylates (esp. nonylphenols and nonylphenol ethoxylates). Exceptions are marked in the column "Remark" with notice: "APEO-containing" and their use is restricted according to Directive 2003/53/EC effective from 17 January 2005.

See also: http://eur-lex.europa.eu/pri/en/oj/dat/2003/l_178/l_17820030717en00240027.pdf

>

31

Emulsifier

Corrosion inhibitor

2.1

Nonionics

2.1.1 Nonylphenol oxethylates Arkopal N 040

Nonylphenol polyglycol ether (4 EO) yellowish liquid ­ ­ 9 Emulsifiers for mineral oil containing metal working fluids based on naphthenic mineral oils and metal cleaners. Products contain APEO and are not allowed to be used in EC effective from 17 January 2005. Raw material for dewatering fluids.

Arkopal N 060

Lubricant

2

Nonionic emulsifier

Chemical description / Ionicity

Function

Appearance

DEAcontent (%)

pH (1%) in water

HLB value

Applications / Properties General aspects Special remarks

Nonylphenol polyglycol ether (6 EO)

yellowish liquid

­

­

11

For alternatives to nonylphenol oxethylates / APEO see chapter below and the brochure cited in chapter 12.1.

Arkopal N 090

Nonylphenol polyglycol ether (9 EO)

yellowish liquid

­

6­8

12 ­ 13

2.1.2 Tristyrylphenol oxethylates Emulsogen TS 100

Tristyrylphenol polyglycol ether (10 EO) yellowish, clear liquid yellowish, clear liquid ­ approx. 7 10 ­ 11 Emulsifier for mineral oil containing metal working fluids (esp. based on naphthenic mineral oils). Excellent emulsifiers with good wetting properties and outstanding lime soap dispersing power (k = 20).

Emulsogen TS 160

Tristyrylphenol polyglycol ether (16 EO)

­

approx. 7

­

2.1.3 Fatty alcohol oxethylates Genapol O 020

Polyglycol ether (2 EO) based on oleyl/cetyl alcohol turbid, yellowish liquid ­ approx. 7 5 Genapol O 020 is clearly soluble in naphthenic and slightly turbid soluble in paraffinic mineral oils. Genapol O 020 is a hydrotrope and a useful coemulsifier for anionic products. Genapol O 020 stabilizes and clarifies oil concentrates and also improves the dispersity and stability of emulsions. Genapol O 020 is preferably used in combination with emulsifiers like Hostacor 3928, Hostacor 3981 or Hostacor 4221. Genapol O-050 is dispersible in mineral oils and shows excellent emulsification properties for most mineral oils. Stable emulsions are obtained in soft and hard water. In metal working fluids good compatibility to anionic formulation components is given. It has a good stability against electrolytes and excellent lime soap dispersing properties (K value 17 ­ 20). When stored at ambient temperatures the products may become hazy or deposits are formed. Before use, Genapol O 020 and Genapol O 050 has to be homogenized at 50°C.

Genapol O 050

Polyglycol ether (5 EO) based on oleyl/cetyl alcohol

turbid, yellowish liquid

­

approx. 7

9

>

32

>

33

Emulsifier

Corrosion inhibitor

2.1

Nonionics

2.1.3 Fatty alcohol oxethylates Emulsogen M

Polyglycol ether (5 EO) based on oleyl / cetyl alcohol clear, yellow liquid ­ approx. 7 9 Emulsogen M / LP are excellent, low foaming emulsifiers for mineral oils and are showing an excellent compatibility to anionic components of metal working fluids. As expressed by their excellent lime soap dispersing power (K-value of 17 ­ 20) they are providing stable emulsions in soft and hard water and stabilizing the emulsion against increasing amounts of electrolytes. Emulsogen M / LP are clearly soluble in most kinds of mineral oils and are easy to formulate. In solution of mineral oils they have a positive impact to lubrication. Emulsogen MS 12 is dispersible in mineral oils and shows excellent emulsification properties for most mineral oils. Stable emulsions are obtained in soft and hard water. In metal working fluids good compatibility to anionic formulation components. It has a good stability against electolytes and excellent lime soap dispersing power (K-value 17 ­ 20). Special emulsifiers for the preparation of liquid emulsions from paraffin waxes melting between 38 and 56°C. A homogenizer is not required. Genapol RX 065 is a water-free, mineral oil soluble, emulsifier with excellent lime soap dispersing power. It is especially suited for rolling fluids. Emulsogen M and Emulsogen LP are stable and homogeneous at room temperature. The pour point for Emulsogen M / LP is between 0 and 5°C.

Emulsogen LP

Polyglycol ether (5.5 EO) based on oleyl / cetyl alcohol

Lubricant

2

Nonionic emulsifiers

Chemical description / Ionicity

Function

Appearance

DEAcontent (%)

pH (1%) in water

HLB value

Applications / Properties General aspects Special remarks

clear, yellow liquid

­

approx. 7

10

Emulsogen MS 12

Polyglycol ether (7 EO) based on oleyl / cetyl alcohol

turbid, yellowish liquid

­

approx. 7

11

When stored at ambient temperatures the product may become hazy or deposits are formed. Before use, Emulsogen MS 12 has to be warmed up to 50°C and homogenized.

Emulsogen P

Polyglycol ether (6,5 EO) based on saturated fatty alcohol

yellow paste

­

approx. 7

­

Emulsogen P is used for preparation of stable, easily dilutable, oil-in-water emulsions with a solid content of up to 30%. Genapol RX 065 becomes turbid with sedimentaion at room temperature and must homogenised at 30°C ­ 40°C before use.

Genapol RX 065

Polyglycol ether based on synthetic fatty alcohol

clear liquid

­

approx. 10 12 ­ 13

>

34

>

35

Emulsifier

Corrosion inhibitor

2.1

Nonionics

2.1.4 Fatty acid oxethylates Emulsogen A

Fatty acid polyglycol ester (5,5 EO) based on oleic acid pale brown, clear liquid ­ approx. 7 ­ Emulsogen A is an emulsifier for many mineral oils. It is clearly soluble in most kinds of mineral oils. The emulsion forms spontaneously when the oil / emulsifier mixture is stirred into water. Emulsifiers for mineral oils. The emulsion forms spontaneously when the oil / emulsifier mixture is stirred into water. Emulsogen A 060 is turbid soluble in mineral oils and dispersible in water.

Emulsogen A 060

Lubricant

2

Nonionic emulsifiers

Chemical description / Ionicity

Function

Appearance

DEAcontent (%)

pH (1%) in water

HLB value

Applications / Properties General aspects Special remarks

Fatty acid polyglycol ester (6 EO) based on oleic acid

pale brown, clear liquid

­

approx. 7

­

Genagen O 100

Fatty acid polyglycol ester (10 EO) based on oleic acid

yellow, clear to turbid liquid

­

approx. 7

­

Genagen O 100 is clearly soluble in paraffinic mineral oils. Clear solutions in naphthenic mineral oils are obtained at concentrations below 25% only. Genagen O 100 is opaque dispersible in water. Emulsifiers for cleaner formulations. Genagen IS 140 is a waxy solid at room temperature.

Genagen IS 140

Fatty acid polyglycid ester (14EO) based isostearic acid

yellowish turbid, pasty to liquid

­

approx. 7

­

Emulsogen EL 360

Polyglycol ester (36 EO) based on castor oil

turbid, liquid or pasty

­

approx. 7

­

Emulsifiers for triglycerides, oils of vegetable origin, vegetable and synthetic ester oils to form spontaneously milky emulsions.

Cloudiness of the concentrate can be adjusted by adding small amounts of oleic acid.

Emulsogen ELO 200

Modified castor oil oxethylate

yellow brownish clear liquid

­

approx. 7

­

2.2

Fatty acid esters Emulsogen OG

Oleic acid polyglycerol ester yellow liquid ­ approx. 7 ­ Coemulsifier in metal working fluids based on paraffinic mineral oils. Concentrate and emulsion stability are improved by addition of 2­3%. Emulsifier for high viscous water-in-oil emulsions based on mineral oils, petroleum, fatty acid esters etc.

>

36

>

37

3 Fatty acid alkanol amides

> Page 3.1 Fatty acid diethanolamides Hostacor DT Hicor BAT Hicor C > > > > 40 40 40 40

3.2

Fatty acid alkanolamides / DEA free Hostacor V 4188 Hostacor MT Hostacor MTF Emulsogen MT 050

> > > > >

40 40 40 40 40

>

39

Emulsifier

Corrosion inhibitor

3.1

Fatty acid diethanolamides Hostacor DT

Tall oil fatty acid diethanolamide brown, clear, oily liquid approx. 30 approx. 10 Hostacor DT, and the Hicor types are clear soluble in most mineral oils and are dispersible in water. They are used as corrosion inhibitors for water miscible metalworking fluids or neat oil applications respectively corrosion prevention oils. Corrosion protection of used emulsion can be generally adjusted by these products. By varying the concentration of Hostacor DT it is possible to adjust the corrosion inhibiting effect of the emulsion to the special requirements of the user. Hostacor DT is useful as corrosion inhibitor in rust prevention oils.

Hicor BAT

Lubricant

3

Fatty acid alkanol amides

Chemical description / Ionicity

Function

Appearance

DEAcontent (%)

pH (1%) in water

Applications / Properties General aspects Special remarks

Fatty acid diethanolamide based on rapeseed oil

yellow, clear liquid

0.5 ­ 0.6

8.9 ­ 9.5

Hicor BAT is a corrosion inhibitor with an extremely low content of free DEA and free acid. As a consequence formation of lime soaps is reduced when mixed with water of high hardness. During storage, the temperature should not drop below 20°C, to avoid gelification and turbidity. Hicor C is a corrosion inhibitor with a low content of free DEA and free acid. As a consequence formation of lime soaps is reduced when mixed with water of high hardness. During storage, the temperature should not drop below 20°C, to avoid gelification and turbidity.

Hicor C

Fatty acid diethanolamide based on rapeseed oil

yellow, clear liquid

5­7

3.2

Fatty acid alkanolamides / DEA free Hostacor V 4188

Tall oil fatty acid monoisopropanolamide, formulated brown, clear, oily liquid approx. 9 Hostacor V 4188, Hostacor MT and Hostacor MTF are clear soluble in most mineral oils and are dispersible in water. They are used as corrosion inhibitors for water miscible metal working fluids or neat oil applications respectively corrosion prevention oils. Corrosion protection of used emulsion can be generally adjusted by these products. Hostacor V 4188 is useful as corrosion inhibitor in rust prevention oils.

Hostacor MT

Tall oil fatty acid monoethanol amide, ethoxylated

clear, brown liquid

­

approx. 9.5

Hostacor MT is a corrosion inhibitor with a low content of free acid and is very effective as an emulsion stabilizer. By mixing MT with e.g. tall oil fatty acid and alkanolamines, pH-values between 9.5 ­ 10.5 can be adjusted. HLB value: approx. 7.6 Hostacor MTF is based on Hostacor MT and contains additionally fatty acid alkanolamine salts. It is a DEA free alternative for products like Hostacor DT (page 42).

Hostacor MTF

Tall oil fatty acid monoethanol amide, ethoxylated, formulated

clear, brown liquid

­

approx. 10.5

Emulsogen MT 050

Tall oil fatty acid monoethanol amide, ethoxylated

clear, brown liquid

­

9.5 ­ 10

Emulsogen MT 050 is a nonionic emulsifier based on a fatty acid alkanol amide with low content of acid and amine. Generally it is used for water miscible metal working fluids providing an additional corrosion inhibition effect.

Emulsogen MT 050 is highly compatible with anionic, cationic and nonionic surfactants. It is showing very low foam tendency and is providing an outstanding lime soap dispersing power (k > 20).

>

40

>

41

4 Water soluble corrosion inhibitors and lubricants

> Page 4.1 Water soluble corrosion inhibitors Hostacor B Hostacor 4053 Hostacor 4053 SEO Hostacor IS Hostacor 2732 Hostacor IT Hostacor BI Hostacor BIT Hostacor 1102 > > > > > > > > > > 44 44 44 44 44 44 44 46 46 46

> Page 4.2 Water soluble lubricants Genapol B Genapol PN 30 Genapol PS > > > > 46 46 46 46

>

43

Emulsifier

Corrosion inhibitor

4.1

Water soluble corrosion inhibitors Hostacor B

Alkanolamine containing formulation with boric acid yellowish, clear, viscous liquid 78% approx. 2.7 9 ­ 10 Hostacor B, Hostacor 4053 and Hostcor 4053 SEO are suitable raw materials for the production of mineral oil free metal working fluids. They are water miscible in any ratio, hardwater stable and extremely low foaming. In combination with suitable emulsifiers (Emulsogen and Hostacor grades) they can be used as corrosion inhibitors for emulsifiable metal working fluids

Hostacor 4053

Lubricant

4

Water soluble corrosion inhibitors and lubricants

Chemical description / Ionicity

Function

Appearance

DEAcontent (%)

Boroncontent (%)

pH (1%) in water

Applications / Properties General aspects Special remarks

Alkanolamine containing formulation with boric acid

yellowish, clear, viscous liquid

­

approx. 3.0

9 ­ 10

The temperature should not drop below 0°C, to avoid gelification and turbidity

Hostacor 4053 SEO

Alkanolamine containing formulation with boric acid

yellowish, clear, viscous liquid

­

approx. 7.0

9 ­ 10

Hostacor 4053 SEO must be stored at 60°C to avoid crystallisation

Hostacor IS

Isononanoylamidocaproic acid/anionic as salt

Crystalline substance, m. r. approx. 50 °C

­

­

­

Hostacor 2732

Isononanoylamidocaproic acid partially neutralized with cyclohexylamine/ anionic as salt

Yellow, clear viscous liquid

­

­

­

Hostacor IS and Hostacor 2732 are insoluble in water. Water soluble salts of Hostacor IS and Hostacor 2732 are obtained by neutralization with alkanolamines and hydroxides. They are used alone or in combination with other water soluble corrosion inhibitors or lubricants for cutting or grinding fluids and in aqueous hydraulic fluids. Hostacor IS and Hostacor 2732 are also suitable for the formulation of aluminium working fluids. pH value should be adjusted to approx. 8 to avoid staining which is often observed at high pH values. Hostacor IT is clearly soluble in water, stable against water hardness and low foaming. It is used alone or in combination with other water soluble corrosion inhibitors or lubricants for cutting or grinding fluids, in aqueous hydraulic systems and in cleaners. For better lubricity Genapol B/PN30/ PS are suitable. Hostacor IT is also suitable for the formulation of aluminium working fluids.

Hostacor IS is a raw material for manufacturing water soluble corrosion inhibitors. Product must be liquefied before use. DR+ Hostacor 2732 is a liquefied version of Hostacor IS which is easily pourable at room temperature. DR+

Hostacor IT

TEA salt of Isononanoylamidocaproic acid/anionic

Yellow, clear viscous liquid

­

­

approx. 8.0

Hostacor IT is a ready to use product. It is darkening during storage to red brown colour. This does not affect the application properties. DR+

>

44

>

45

Emulsifier

Corrosion inhibitor

4.1

Water soluble corrosion inhibitors Hostacor BI

Formulation based on alkanolamine, boric acid and corrosion inhibitor/ anionic Formulation based on alkanolamine, boric acid and corrosion inhibitor/ anionic Mixture of alkanolamines, boric acid and polycarboxylic acid salt/anionic Yellow, clear viscous liquid approx. 58% approx. 2.1 9 ­ 10 Hostacor BI, Hostacor BIT and Hostacor 1102 are used as corrosion inhibitors alone or in combination with other water soluble corrosion inhibitors, glycols and EO/PO block- or copolymers for mineral oil free cutting and grinding fluids. Hostacor BI, BIT and 1102 are water miscible, stable against water hardness and low foaming.

Hostacor BIT

Lubricant

4

Water soluble corrosion inhibitors and lubricants

Chemical description / Ionicity

Function

Appearance

DEAcontent (%)

Boroncontent (%)

pH (1%) in water

Applications / Properties General aspects Special remarks

Yellow, clear viscous liquid

­

approx. 2.5

9 ­ 10

Hostacor 1102

Slightly yellow, clear viscous liquid

approx. 56%

approx. 2.5

9.5

4.2

Water soluble lubricants Genapol B

EO / PO blockpolymer based on ethylenediamine EO / PO blockpolymer based on ethylenediamine EO / PO random copolymer brown, viscous liquid yellow, viscous liquid yellowish, highly viscous liquid ­ ­ approx. 11 10 ­ 11 Genapol B / PN 30 / PS are low foaming lubricants for synthetic metal working fluids. They are stable against water hardness. In combination with corrosion inhibitors like Hostacor IT or Hostacor BIT, clear water soluble metalworking fluids with good lubricating and corrosion protecting properties are obtained. Water solubility increases from Genapol PN 30, Genapol B to Genapol PS. Depending on the amounts of boric acid esters, corrosion inhibitors and solubilizing agents, the Genapol ­ type of adequate solubility has to be selected to obtain stable and clear concentrates resp. synthetic metal working fluids. Genapol PN 30 and Genapol B do not contain free ethylene diamine.

Genapol PN 30

­

­

Genapol PS

­

­

5­7

> 46

> 47

5 Oil soluble corrosion inhibitors

> Page Arkomon SO Hostacor PSO 300 > > 50 50

>

49

Emulsifier

Corrosion inhibitor

Arkomon SO

Lubricant

5

Oil soluble corrosion inhibitors

Chemical description / Ionicity

Function

Appearance

DEAcontent (%)

­

Boroncontent (%)

­

pH (1%) in water

Applications / Properties General aspects Special remarks

Oleic acid sarcoside

yellow to brown, clear liquid

­

Arkomon SO is soluble in most kind of mineral oils. The strong foaming tendency of Arkomon SOsalts in aqueous emulsions should be taken in Arkomon SO is used as corrosion inhibitor for oil consideration. based metal working fluids and corrosion protection oils. In neutralized form, e. g. as sodium salt it can be used as corrosion inhibitor in water miscible metal working fluids.

Hostacor PSO 300

Calcium petroleum sulphonate, overbased [TBN 300]

dark, viscous liquid

­

­

­

In rust prevention oils Hostacor PSO 300 provides long term rust protection to workpieces also under unfavourable conditions such as storage under open air. Hostacor PSO 300 is an oil soluble lubricity and EP / AW additive with excellent corrosion protection properties. As EP / AW additive it is used in neat cutting oils, honing oils or deep drawing oils alone or in combination with other EP-additives.

Addition of acids to Hostacor PSO 300 containing formulations must be avoided.

>

50

>

51

6 Lubricants and EP-Additives

> Page 6.1 Esters Hostagliss FN Hostagliss H Hostagliss L4 Hostagliss A Hostagliss DHSZ Hostagliss PA 135 Hostagliss PA 165 > > > > > > > > 54 54 54 54 54 54 54 54 6.2 Phosphoric acid esters Dispersogen SP 040 Hordaphos 124 Hordaphos 125 Hordaphos 145 Hordaphos 222 Hordaphos DEOD Hordaphos MDAH Hordaphos MDB Hordaphos MDGB Hordaphos MDHX Hordaphos MDIT Hordaphos MDO Hostaphat TBEP

> Page > > > > > > > > > > > > > > 56 56 56 56 56 56 56 56 56 58 58 58 58 58

6.3

Polyalkylene glycols / Polyethylene glycols see chapter 11 Brochures / Other ranges > 78

>

53

Emulsifier

Corrosion inhibitor

Lubricant

6

6.1

Lubricants and EP-Additives Esters Hostagliss FN

Chemical description / Ionicity

Function

Appearance

DEAcontent (%)

Acid number (mg KOH / g)

Applications / Properties General aspects Viscosity (mm2/s) at 40°C at 100°C

13 ­ 17 min. 150

Viscosity Index

Polyester based on special fatty acids.

brown, clear liquid

­

max. 5

Hostagliss H

Nitrogen containing complex polyester based on fatty acids, dicarboxylic acids and polyvalent alcohols. Acid group containing complex ester based on fatty acids.

brown, clear viscous liquid

­

5.5 ­ 8.5

Hostagliss FN and Hostagliss H are excellent lubricity and AW additives and can be easily incorporated into water miscible metalworking fluids. In particular they show an outstanding performance in formulations for aluminium cutting fluids. Synergistic effects are obtained when 1 : 1 mixtures of Hostagliss FN / Hostagliss H are applied.

75 ­ 110

3000 ­ 5000

250 ­ 500

approx. 180

Hostagliss L4

clear viscous liquid

­

50.5 ­ 55.5

Hostagliss A

Acid group containing complex ester based on fatty acids, dicarboxylic acids and polyvalent alcohols. Acid group containing complex ester based on fatty acids, dicarboxylic acids and polyvalent alcohols. Copolymer of -olefin and maleic acid di butyl ester.

brown, clear viscous liquid

­

42 ­ 52

approx.400 Hostagliss L4, Hostagliss A and Hostagliss DHSZ are complex esters with a high residual acid number and can be easily incorporated into concentrates for water based emulsions despite their high viscosities. They contribute to emulsion stability 900 ­ 1100 and corrosion protection when neutralized with alkanolamines.

approx. 45

approx. 169

80 ­ 120

approx. 180

Hostagliss DHSZ

brown, clear viscous liquid

­

29 ­ 35

2000 ­ 2700

180 ­ 220

approx. 210

Hostagliss PA 135

clear liquid

­

max. 2

Hostagliss PA 165

Copolymer of -olefin and maleic acid di butyl ester.

clear liquid

­

max. 2

Hostagliss PA 135 and Hostagliss PA 165 are fully saturated, liquid polymeric esters. The hydrolytic stability is good so they can be applied in water based metalworking fluids as well as lubricant in various neat oil applications.

270 ­ 330

31 ­ 37

min. 120

730 ­ 800

65 ­ 75

min. 120

>

54

>

55

Emulsifier

Corrosion inhibitor

6.2

Phosphoric acid esters Dispersogen SP 040

Phosphoric acid mono / di ester based on alkylphenol ethoxylate clear colourless to yellowish liquid brownish viscous liquid approx. 3.9 approx. 110 approx. 2.5 Dispersogen SP 040 is used in neutralized form as emulsifier. Product should be stored at ambient temperature. Max. storage time is 1 year.

Hordaphos 124

Phosphoric acid mono / di ester based on fatty alcohol polyglycol ether.

Lubricant

6

Acid number (mg KOH / g)

Lubricants and EP-Additives

Chemical description / Ionicity

Function

Appearance

pH (1% in water / Isopropanol 1:3)

P-content (%)

Applications / Properties General aspects Special remarks

approx. 4.4

approx. 130

approx. 2.8

Hordaphos 124 is suitable for low foaming formulations and as a solubilizing agent.

Max. storage time is 1 year.

Hordaphos 125

Phosphoric acid mono / di ester based on fatty alcohol polyglycol ether.

yellowish to brownish viscous liquid clear yellowish to brownish liquid

approx. 5.4

approx. 180

approx. 2.5

Hordaphos 125 is used in neutralized form for water miscible metal working fluids.

Max. storage time is 1 year.

Hordaphos 145

Phosphoric acid mono / di ester based on fatty alcohol polyglycol ether

approx. 5.0

approx. 160

approx. 3.0

Hordaphos 145 can be used as emulsifier or as detergent in low viscous mineral oils when neutralized with suitable amines and / or alkanolamines. The EP activity of Hordaphos 145 is influenced by the amines chosen for neutralisation. It is recommended to use Hordaphos 145 in mixtures with esters, e.g. TMP-oleate. Hordaphos 222 is used in neutralized form for water micible metal working fluids.

Product should be stored at ambient temperature. Max. storage time is 1 year.

Hordaphos 222

Phosphoric acid mono / di ester based on alkyphenol ethoxylate

clear colourless to yellowish liquid clear colourless to yellowish liquid colourless to yellowish liquid

4.3 ­ 5.3

approx. 140

approx. 2.4

Product should be stored at ambient temperature. Max. storage time is 1 year.

Hordaphos DEOD

Phosphoric acid mono / di ester based on decanol, ethanol and octanol

approx. 12.0

approx. 220

approx. 2.5

In combination with Aluminium salts (Locron types) and suitable surfactants Hordaphos DEOD is a thickener for mineral oils Hordaphos MDAH is suitable additive for low viscous mineral oils so it can be used in oil based grinding fluids. Hordaphos MDAH has very strong phosphatizing properties. Hordaphos MDB is used for synthetic and semi synthetic metal working fluids after neutralization.

Product should be stored at ambient temperature. Max. storage time is 1 year

Hordaphos MDAH

Phosphoric acid mono / di (2-ethylhexyl) ester

approx. 11.5

approx. 308

approx. 2.3

Product should be stored at ambient temperature. Max. storage time is 1 year.

Hordaphos MDB

Phosphoric acid mono / di alkyl ester based on short chain alcohol

clear acolourless to yellowish liquid

approx. 17.2

approx. 470

approx. 2. 2

Max. storage time is 1 year.

>

56

>

57

Emulsifier

Corrosion inhibitor

6.2

Phosphoric acid esters Hordaphos MDGB

Phosphoric acid mono / di glykol alkyl ester clear colourless to yellowish liquid clear colourless to yellowish liquid approx. 19.5 approx. 548 approx. 1.7 Hordaphos MDGB is suitable for water miscible cutting fluids. Due to its low decomposition temperature it is a highly active EP-additive. Hordaphos MDHX is mainly used as AW-additive in amine neutralized form. Max. storage time is 1 year.

Lubricant

6

Acid number (mg KOH / g)

Lubricants and EP-Additives

Chemical description / Ionicity

Function

Appearance

pH (1% in water / Isopropanol 1:3)

P-content (%)

Applications / Properties General aspects Special remarks

Hordaphos MDHX

Phosphoric acid mono / di glykol alkyl ester

approx. 13.1

approx. 375

approx. 2.3

Max. storage time is 1 year.

Hordaphos MDIT

Phosphoric acid mono / di alkyl ester

clear colourless to yellowish liquid clear colourless to yellowish liquid

approx. 8.5

approx. 230

approx. 2.5

Hordaphos MDIT is used in neutralized form as emulsifier. Due to the very low surface tension it can be used in dewatering fluids. Hordaphos MDO is used in neutralized form as emulsifier. Due to its very low surface tension it can be used in dewatering fluids.

Product should be stored at ambient temperature. Max. storage time is 1 year.

Hordaphos MDO

Phosphoric acid mono / di alkyl ester

approx. 11.5

approx. 330

approx. 2.7

Max. storage time is 1 year.

Hostaphat TBEP

Phosphoric acid trialkylester

clear colourless to turbid yellowish liquid

< 0,5

Anti-Wear additive / lubricant for environmentally sensitive applications

For short chain phosphoric acid esters suitable for surface treatment and metal cleaners see brochures listed in chapter 11.5

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7 Cleaners

> Page 7.1 Fatty alcohol oxalkylates Genapol EP 0244 Genapol EP 2424 Genapol EP 2464 Genapol EP 2552 Genapol EP 2544 Genapol EP 2564 Genapol EP 2584 Genapol BA 040 > > > > > > > > > 62 62 62 62 62 62 62 62 62

7.2

Corrosion inhibitors / Specialities Dodigen 95 Dodicor 2565 Dodicor 2725 NF Hostaphat OPS 100 Hostaphat OPS 80 P

> > > > > >

64 64 64 64 64 64

> Page 7.3 Solvents see chapter 11.3 Brochures / Other ranges > 78

Detergent Regulation EC 648/2004 and EC 907/2006 According to the Detergent Regulation Surfactants used in detergents (cleaners etc.) have to show an ultimate biodegradation above given minimum limits according to EC648/2004. The determination methods, minimum ultimate biodegradation limits and test report quality requirements are provided by the regulation. Producers state the compliance with the EU Detergent Regulation with phrases in the EU safety data sheet (EU-SDS) Chapter 12 or 15. Products with a compliance phrase in the EU-SDS show in the column remarks the abbreviation: "DR +". See also: http://eur-lex.europa.eu/LexUriServ/site/en/oj/2004/l_104/l_10420040408en00010035.pdf

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61

Emulsifier

Corrosion inhibitor

7.1

Fatty alcohol oxalkylates Genapol EP 0244

C10 / C12 Ziegler alcohol EO ­ PO adduct C12 / C14 fatty alcohol turbid ­ 6­8 These products are all soluble in water, stable against water hardness and stable against aqueous acids and bases. They are mostly used as low foaming cleaning agents mainly for mild alkaline or neutral spray cleaners. These Genapol types show excellent compatibility with anionic corrosion inhibitors e.g. Hostacor IT. The temperature should not drop below 20°C to avoid gelification and turbidity during storage. If the products become opaque, thick or frozen it can be thawed slowly at room temperature and used after homogenization. All products are DR+.

Genapol EP 2424

Lubricant

7

Cleaners

Chemical description / Ionicity

Function

Appearance

DEAcontent (%)

pH (1%) in water

Applications / Properties General aspects Special remarks

clear, liquid

­

6­8

Genapol EP 2464

C12 / C14 oxo alcohol EO ­ PO adduct

turbid, liquid

­

6­8

Genapol EP 2552

C12 / C15 oxo alcohol EO ­ PO adduct

clear, liquid

­

6­8

Genapol EP 2544

C12 / C15 oxo alcohol EO ­ PO adduct

clear, liquid

­

6­8

Genapol EP 2564

C12 / C15 oxo alcohol EO ­ PO adduct

turbid

­

6­8

Genapol EP 2584

C12 / C15 oxo alcohol EO ­ PO adduct

turbid

­

6­8

Genapol BA 040

Benzyl alcohol-ethoxylate

clear liquid

­

6­8

Genapol BA 040 is an excellent solubilizer of low volatility for cleaner formulations. It does not show pronounced surfactant properties itself. Genapol BA 040 can also be used in emulsifiable metal working concentrates to improve spontaneity of emulsion formation. DR+

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Emulsifier

Corrosion inhibitor

7.2

Corrosion inhibitors / Specialities Dodigen 95

Mixture of an alkyl aryl ammonium rhodanide and oxalkylated amine in water / cationic. brownish, liquid ­ 8 ­ 10 Dodigen 95 is soluble in mineral / organic acids and forms stable emulsions with water. Dodigen 95 is an inhibitor for oxo acids such as sulphuric acid, phosphoric acid, sulphamic acid and organic acids such as acetic, formic and citric acid. Dodicor 2565 is soluble in water and acids. It is a special inhibitor for zinc, but protects also steel against the attack of mineral acids. All products are showing a pour point below ­ 20°C. Nevertheless, storage temperature should not drop below 20°C to avoid gelification and turbidity. If products become opaque, thick or frozen they can be thawed slowly at room temperature and used after homogenization.

Dodicor 2565

Lubricant

7

Cleaners

Chemical description / Ionicity

Function

Appearance

DEAcontent (%)

pH (1%) in water

Applications / Properties General aspects Special remarks

Solution of a quaternary chinolinium compound in water / cationic.

brownish, liquid

­

3.5 ­ 5

Dodicor 2725 NF

Mixture of quaternary chinolinium compound, alkinol and nonionic surfactant in glycol / cationic.

amber liquid

­

3­4

Dodicor 2725 NF is soluble in water and also in diluted and concentrated hydrochloric acid. It is used to inhibit the attack of hydrochloric / hydrofluoric acid solutions on low carbon steels. Dodicor 2725 NF also shows a good protection to steel against sulfamic and sulfuric acid and even to aluminium, if the acid concentrations and treating temperatures are moderate. Hostaphat OPS 100 is used in its neutralized form as inhibitor in aluminium cutting fluids and aluminium cleaner formulations. The surface quality (staining) of certain Al alloys can be improved significantly. Hostaphat OPS 100 shows also corrosion protection for ferrous metals. The product has to be warmed up above 60°C to get liquid . Suitable neutralisation agents are alkali hydroxides and amines. DR+

Hostaphat OPS 100

Alkane phosphonic acid

white wax

­

­

Hostaphat OPS 80 P

Alkane phosphonic acid in a mixture of water / alcohol

clear, amber to brownish liquid

­

­

The product is stable and do not show Solubilized version of Hostaphat OPS 100 to provide better handling. Used solvent offers a flash solidification or precipitation at storage temperatures down to + 15°C. point > 100°C DR+

7.3

Solvents Clariant offers a broad range of Glymes for cleaning applications, especially as replacement for toxicologically and environmentally problematic solvents (chlorinated solvents, NMP). See chapter 11.3

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Emulsifier

0

0.0

tab_head_2 > Page

tab_text tab_text

0.0.0 tab_head_3 tab_products Antimussol 3470 liq. Antimussol 3472 N Antimussol 4459 liq. Antimussol 4752 liq. Antimussol FN Antimussol TIP Antimussol ZJ Appretan Defoamer 5084 liq. Appretan Defoamer 5342 liq.

Lubricant

tab_head_1

Corrosion inhibitor

Chemical description-/Ionicity

Function

Appearance

8 Defoamers

> > > > > > > > >

68 68 68 68 68 68 68 68 68

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67

Silicone free

Antimussol 3470 liq.

Si-free

8

Defoamers

Chemical description / Ionicity

Appearance

Silicone content

Ionicity

Dilutability in water

Flash point

Applications / Properties General aspects Special remarks

Si

Mixture of nitrogen containing, surface yellow liquid active substances.

nonionic

yes

>100°C

Antimussol 3470 liq. and Antimussol 3472 N are combined defoamers and foam suppressants, they can be used in nonionic and anionic / nonionic metal working fluids. They are suitable for oil containing, water miscible metal working fluids. For the use in concentrates.

The products may precipitate at temperatures below 10°C, after heating to 40°C and homogenisation they becomes clear and can be used again without loss of performance. Storage stability is max. 1 year.

Antimussol 3472 N

Mixture of nitrogen containing, surface yellow liquid active substances. Mixture of nitrogen and silicon containing substances. milky dispersion

cationic

yes

>100°C

Antimussol 4459 liq.

cationic

yes

98°C

Antimussol 4459 liq. is a combined defoamer and foam suppressant, it can be used in anionic and anionic / nonionic metal working fluids. It's suitable for oil containing, water miscible metal working fluids. Antimussol 4752 liq. is an universal defoamer for a wide range of metal working fluids.

Sensitive to frost. After freezing the product is not longer usable. Storage stability is max. 6 months.

Antimussol 4752 liq.

Aqueous dispersion of fat derivatives with a low polysiloxane content.

milky dispersion

nonionic

yes

>100°C

Risk of separation after prolonged exposure to temperatures above 40°C. Sensitive to frost. After freezing the product is not longer usable. Storage stability is max. 6 months. The product becomes turbid at temperatures below 5°C, after heating to 40°C and homogenisation it becomes clear and can be used again without loss of performance. Storage stability is max. 1 year. Antimussol TIP keeps liquid below ­ 25°C. If it becomes turbid, thick or frozen under exposure of cold, thaw slowly at room temperature and homogenize carefully. Storage stability is max. 2 years. Antimussol ZJ keeps liquid down to ­ 25°C. If it becomes turbid, thick or frozen under exposure of cold, thaw slowly at room temperature and homogenize carefully. Storage stability is max. 2 years. Storage stability is max. 1 year

Antimussol FN

Mixture of sparingly water soluble foam suppressing organic substances.

viscous liquid

nonionic

no

>100°C

Antimussol FN is a defoamer for a wide range of metal working fluids. It is suitable for oil containing, water miscible metal working fluids. For the use in concentrates. Product contains fatty acid amide based on sec.-amine. Antimussol TIP is a defoamer for all classes of surfactants. It is suitable for a wide range of metal working fluids and can be applied in concentrates.

Antimussol TIP

Solution of phosphoric acid ester in alcohol

yellowish, clear liquid

nonionic

no

27°C

Antimussol ZJ

Fatty acid amide

yellow liquid

nonionic

no

>100°C

Antimussol ZJ is a raw material for defoamer formulations and is suitable for a wide range of metal working fluids. It can be applied in concentrates.

Appretan Defoamer 5084 liq.

Mixture of nitrogen containing substances with polyoxyalkylates

turbid dispersion

nonionic

yes

> 100 °C Appretan defoamer 5084 liq. is a combination of defoamer and a de-airing agent with good wetting abilities. It is suitable for a wide range of metal working fluids. For the use in Concentrates > 150 °C Appretan defoamer 5342 liq. is a universal for a defoarmer wide range of metal working fluids

Appretan Defoamer 5342 liq.

Water dispersible mixture of organic compounds, aromatic free

turbid dispersion

nonionic

nonionic

Risk of separation after prolonged exposure to temperatures above 40°C of after intensive shearing. Stzorage stability is max 1 year

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9 Biocides

> Page Nipacide BK Nipacide BIT 20 Nipacide CI Nipacide FC Nipacide HTP/2 Nipacide IPBC 20 / IPBC 30 Nipacide MBM Nipaclean 3 Sodium Omadine 40% > > > > > > > > > 72 72 72 72 72 72 72 72 72

Biocides

For EEC (Europe): Based on our information (status April 2008) all mentioned biocides are in compliance with the BPD 98/8/EC and amendments/corrections. This information is based on the current situation and Clariant reserves the right to modify the support if the data requirements change or the market position alters. See also: http://ecb.jrc.it/biocides/ For Germany: Biozide sicher verwenden. Vor Gebrauch stets Kennzeichnung und Produktinformation lesen.

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9

Biocides

Chemical description / Ionicity

Appearance

Formaldehydedonor

pH (1%) in water

Applications / Properties General aspects Special remarks

Nipacide BK

Tris(2-hydroxyethyl)-hexahydro-1,3,5- triazine

clear liquid

yes

10 ­ 11

Nipacide BK is a water soluble, wide spectrum biocide, which can be used for disinfection and preservation of metalworking fluids.

Storage time 1 year. Max. storage temperature 40°C.

Nipacide BIT 20

20% alkaline solution of benzisothiazoline

clear, yellow viscous liquid

no

8­9

Nipacide BIT 20 is used in formulations and tankside addition. It is very effective at high pHs and offers thermal stability.

Nipacide CI

Chlorinated and non chlorinated isothiazolinones

yellow liquid

no

approx. 7,5

Nipacide CI is widely used for the post treatment of metal working emulsions in large central systems.

Nipacide FC

1,2-ethandiylbis(oxy)bismethanol

clear liquid

yes

approx. 7

Nipacide FC is used in formulations and tankside dosing.It gives long term protection of emulsions against bacteria and fungi.

Nipacide HTP/2

Tris(2-hydroxyethyl)-hexahydro-1,3,5-triazine and Sodiumpyridinethiol-1-oxide.

colourless liquid

yes

approx. 11

Npacide HTP/2 is used in formulations and tankside dosing. It is a combination of bactericide and fungicide where additional fungicidal activity is required. Nipacide IPBC grades are used in formulations and tankside addition. Active levels 20% and 30%.

Nipacide IPBC 20 / IPBC 30

3-Iodo-2-propinyl-butylcarbamate

colourless to yellow liquid

no

approx. 7

Nipacide MBM

N,N-methylene bismorpholine

clear liquid

yes

approx. 10

Nipacide MBM is used in formulations and tankside dosing. It is an exceptionally good bactericide with enhanced fungicidal qualities.

Nipaclean 3

Blend of biocides, cleaners and surfactants

clear yellow liquid

yes

approx. 12

Exceptional with synthetics and semi synthetics. Used as a tankside treatment to remove contaminants, slimes and oil residues when emulsion is changed. It ensures that the system is in good microbial condition to accept new emulsion. Nipacide SP is used as fungicide in formulations and tankside addition

Sodium Omadine 40%

Sodium pyridinethiol-1 oxide

amber liquid

no

8,5 ­ 10

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10 Others

> Page 10.1 Dewatering fluids Emulsogen ENF Genamin 8 R 100 D 10.2 Amines Genamin SH 100 D P Genamin 3920 Genamin NO 050 Genamin CH 020 > > > > > > > > 76 76 76 76 76 76 76 76

>

75

Emulsifier

Corrosion inhibitor

10.1

Dewatering fluids Emulsogen ENF

Corrosion inhibitor in combination with fatty alkohol polyglycol ether yellowish to brown, clear viscous liquid ­ approx. 7 Emulsogen ENF is clearly soluble in most organic solvents. They are wetting agents with corrosion inhibiting properties for dewatering fluids. Emulsogen ENF cause the rapid separation of the water from the metal surface and prevent corrosion of the dewatered metal parts. Raw material for corrosion inhibitors in dewatering fluids. After neutralization with suitable fatty acids like caprylic acid, Genamin 8 R 100 D is used in combination with wetting agents as hydrophobic and corrosion inhibiting component in dewatering fluids. Emulsogen ENF is the nonylphenol ethoxylate free replacement of Emulsogen E (deleted product)

Genamin 8 R 100 D

Lubricant

10

Others

Chemical description / Ionicity

Function

Appearance

DEAcontent (%)

pH (1%) in water

Applications / Properties General aspects Special remarks

Octylamine, dist.

colourless liquid

­

­

10.2

Amines Genamin SH 100 D P

Tallow fatty alkyl amine white flakes ­ ­ Genamin SH 100 D P is soluble in mineral oils. It is used as corrosion inhibitor. Genamin SH 100 D P is a useful component for oil-based formulations e.g. for the neutralisation of acidic EP-additives to generate oil soluble salts. Genamin 3920, Genamin NO 050 and Genamin CH 020 are used as neutralizing agents. For emulsifiable (3920, NO 050, CH 020) and synthetic (CH 020, NO 050) metal working fluids. In many cases spontaneity of emulsion formation is improved. Genamin CH 020 causes almost no cobalt leaching. Max. storage time 1 year

Genamin 3920

Caprylamine oxethylate

clear, colourless to slight yellow liquid clear yellow to brown liquid clear, colourless to slight yellow liquid

­

­

Genamin NO 050

Caprylamine ethoxylate

­

­

Genamin CH 020

Cyclohexylamine oxethylate

­

­

Clariant offers also a variety of fatty amines and amine derivatives like fatty amine ethoxylates ­ see brochure listed in chapter 11.2.

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77

11 Brochures / Other ranges

11.1 Raw Materials for the Chemo-Technical Industry < Fatty Amines and Derivatives < Amine Oxides and Betaines < Solubilizers < Anionic Surfactants < Nonionic Surfactants < Low Foamers and Defoamers < Emulsifiers 11.2 Fatty Amines and Derivatives < Fatty Amines and Derivatives < Amine Oxides, Betaines and Quaternary Ammonium Compounds < Amine Ethoxylates 11.3 Glymes ­ Glycol diethers < Ethylene glycol dimethyl ethers < Polyethylene glycol dimethyl ethers < Polyethylene glycol dibutyl ethers < Polyethylene glycol monoallyl ethers < Polyethylene glycol allylmethyl ethers < Polyalkylene glycol monoallyl ethers < Polyalkylene glycol diallyl ethers 11.4 Polyalkylene / Polyethylene glycols < Polyethylene glycols (PEG) < Polyglycole PR < Polyglycole M < Polyglycole P41 < Polyglycole B11 < Polyglycole B01 and T01 < Polyglycole D21 < special products 11.5 Hordaphos (phosphoric acid esters) < General brochure < Additives for Cleaners < Additives for Industrial Cleaning < Additives for Surface Finishing

Information

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