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MATERIAL SAFETY DATA SHEET LIQUID PREPARATION FOR : TIPP-EX® ECOLUTIONS CORRECTION FLUID

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME : Recommended uses : SUPPLIER : Name : Address :

Version : 1 Date : 7/11/2008 Supersedes : 0/0/0

BIC

LIQUID PREPARATION FOR : TIPP-EX® ECOLUTIONS CORRECTION FLUID Correction fluid SOCIETE BIC 14, Rue Jeanne d'Asnières 92611 CLICHY Cédex FRANCE + 33 01 45 19 52 00 +33 01 45 19 52 99 [email protected] ORFILA (France) : +33 01 45 42 59 59

Telephone number : Telefax number : E-mail : EMERGENCY TELEPHONE NUMBER :

2. HAZARDS IDENTIFICATION

MOST IMPORTANT HAZARDS : Adverse human health effects : Environmental effects : To our knowledge, no specific risk when handled in accordance with good occupational hygiene and safety practice. Presents no particular risk to the environment, provided the recommendations concerning disposal (see section 13) and any applicable national or local regulations are complied with Not classified as flammable by EC criteria but may present a hazard in the event of a fire According to EC regulations, this product is not classified as a "hazardous preparation".

Physical and chemical hazards : - Fire or explosion : Classification of the product :

3. COMPOSITION / INFORMATION ON INGREDIENTS

MIXTURE : Chemical nature : Hazardous constituents :

Substance name Ethanediol Titanium dioxide Ammonia solution Limestone : : : :

Aqueous solution based on polymers

Contents < 20 % < 40 % < 10 % < 20 % CAS No / EC No / Index No 107-21-1 / 203-473-3 / 603-027-00-1 13463-67-7 / 236-675-5 / ----1336-21-6 / 215-647-6 / 007-001-01-2 1317-65-3 / 215-279-6 / ----CN 34-50 Symbol(s) Xn R-Phrase(s) 22

4. FIRST AID MEASURES

Inhalation : Move the affected person away from the contaminated area and into the fresh air If the person feels unwell : Call a doctor Immediately rinse with plenty of water. In case of redness or irritation, call a doctor Rinse immediately and thoroughly with plenty of water whilst keeping the eyes wide open (at least15 minutes) If irritation persists, consult an eye specialist Consult a doctor

Skin contact : Eye contact :

Ingestion :

SOCIETE BIC

14, Rue Jeanne d'Asnières 92611 CLICHY FRANCE

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MATERIAL SAFETY DATA SHEET LIQUID PREPARATION FOR : TIPP-EX® ECOLUTIONS CORRECTION FLUID

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Not suitable extinguishing media : Specific hazards : Specific fire fighting methods :

Version : 1 Date : 7/11/2008 Supersedes : 0/0/0

BIC

Protection of fire-fighters :

Water spray Carbon dioxide (CO2) None to our knowledge. If there is a fire close by, use suitable extinguishing agents On heating or during combustion : Toxic vapors may be released Do not attempt to fight the fire without suitable protective equipment Cool down the containers/equipment exposed to heat with a water spray Contain the extinguishing fluids by bunding Complete protective clothing Self-contained breathing apparatus

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Environmental precautions : Methods for cleaning up : - Recovery : - Neutralization : Avoid contact with skin and eyes Do not breathe vapours Contain the spilled material by bunding Do not discharge into drains and rivers Recover the product by mechanical means. Absorb non-recoverable liquid with: - inert absorbent material - earth or sand Wash contaminated area with large amounts of water Dispose of contaminated materials in accordance with current regulations

- Cleaning/decontamination : - Disposal :

7. HANDLING AND STORAGE

HANDLING Technical measures : Precautions : STORAGE Technical measures : Storage conditions : - Recommended : Vapour extraction at source Avoid contact with skin and eyes. The floor of the depot should be impermeable and designed to form a water-tight basin. Store : - in a cool, well-ventilated area - the container tightly closed Mineral acids Strong oxidizing agents Original packaging

Incompatible materials : Packaging materials : - Recommended :

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures : Occupational exposure limits : - France : Ensure good ventilation of the work station Extraction to remove vapours at their source Ethylene Glycol : VME = 52 mg/m³ (20 ppm) VLE = 104 mg/m³ (40 ppm) Ammonia : VME = 7 mg/m³ (10 ppm) VLE = 14 mg/m³ (20 ppm)

SOCIETE BIC

14, Rue Jeanne d'Asnières 92611 CLICHY FRANCE

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MATERIAL SAFETY DATA SHEET LIQUID PREPARATION FOR : TIPP-EX® ECOLUTIONS CORRECTION FLUID

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Version : 1 Date : 7/11/2008 Supersedes : 0/0/0

BIC

(continued)

- European Community :

Limestone : VME = 10 mg/m³ Titanium dioxide, Ti : VME = 10 mg/m³ Ethylene Glycol : Limit value (8h) : 52 mg/m³ (20 ppm) Limit value (short term) : 104 mg/m³ (40 ppm) If the ventilation is suitable, it is not necessary to wear respiratory equipment In case of intensive use : Nitrile-rubber protective gloves Breakthrough time : refer to the recommandations of the supplier Safety spectacles Do not drink, eat or smoke in the workplace Always wash your hands after handling the product

Personal protective equipment : - Respiratory protection : - Hand protection :

- Eye protection : Hygiene measures :

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : Colour : Odour : pH : Solubility : - in water : Liquid white Characteristic 6-8 Soluble

10. STABILITY AND REACTIVITY

Stability : Hazardous reactions : - Materials to avoid : - Hazardous decomposition products : Stable under normal conditions of use - strong oxidizing agents - mineral acids On combustion or on thermal decomposition (pyrolysis) releases : Carbon oxides (CO, CO2)

11. TOXICOLOGICAL INFORMATION

Acute toxicity : Ethylene Glycol : LD 50 oral (rat) : > 2000 mg/kg LD 50 skin (Rabbit) : > 10000 mg/kg (published data) Ethylene Glycol : Weariness Nausea Vomiting Central Nervous System depressant Ethylene Glycol : May cause slight temporary irritation

Acute symptoms :

Local effects :

SOCIETE BIC

14, Rue Jeanne d'Asnières 92611 CLICHY FRANCE

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MATERIAL SAFETY DATA SHEET LIQUID PREPARATION FOR : TIPP-EX® ECOLUTIONS CORRECTION FLUID

12. ECOLOGICAL INFORMATION

DEGRADABILITY : Ethylene Glycol : 83-96 % biodegradation after 14 days (published data) Easy biodegradable Ethylene Glycol : -1.36 (log POW) (published data) Not potentially bioaccumulable

Version : 1 Date : 7/11/2008 Supersedes : 0/0/0

BIC

BIOACCUMULATION : Octanol/water partition coefficient :

ECOTOXICITY : Effects on the aquatic environment :

No information available, however this product is not considered to present any particular risk for the aquatic environment. Ethylene Glycol : EC 50 (Daphnia : Daphnia magna) / 48h : 51 mg/l LC 50 (Fish : Leuciscus idus) / 48 h : > 10000 mg/l (published data)

13. DISPOSAL CONSIDERATIONS

WASTE FROM PRODUCT : Destruction/Disposal : CONTAMINATED PACKAGING : Destruction/disposal : NOTE : Dispose of in accordance with relevant local regulations Destroy at an authorised site The user's attention is drawn to the possible existence of specific european, national or local regulations regarding disposal

14. TRANSPORT INFORMATION

INTERNATIONAL REGULATIONS : RID/ADR/IMDG/IATA : NOTE : Not restricted The above regulatory prescriptions are those valid on the date of publication of this sheet Given the possible evolution of transport regulations for hazardous materials, in case the present sheet is dating back to more than 12 months ago, it would be advisable to check their validity with your commercial agency

15. REGULATORY INFORMATION

EC LABELLING : - Symbols and indications of danger : - R phrases : - S phrases : - Additional phrases : No symbol No R phrase No S phrase The following must appear on the label : Safety data sheet available for professional user on request The regulatory information given above only indicate the principal regulations specifically applicable to the product described in the MSDS The user's attention is drawn to the possible existence of additional provisions which complete these regulations Refer to all applicable international, national and local regulations or provisions

16. OTHER INFORMATION

Restrictions on use : R phrases text of § 3 : This product must not be used for other applications that mentionned in §1. R22 : Harmful if swallowed. R34 : Causes burns. R50 : Very toxic to aquatic organisms. European Chemicals Bureau (ECB)

Bibliography references :

SOCIETE BIC

14, Rue Jeanne d'Asnières 92611 CLICHY FRANCE

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MATERIAL SAFETY DATA SHEET LIQUID PREPARATION FOR : TIPP-EX® ECOLUTIONS CORRECTION FLUID

16. OTHER INFORMATION

Safety data sheet established by :

Version : 1 Date : 7/11/2008 Supersedes : 0/0/0

BIC

(continued)

MSDS of suppliers LISAM SERVICES - TELEGIS 6 rue des Boucheries F-60400 NOYON www.reachelp.com Safety Made Easy with www.lisam.com

This sheet complements the technical sheets but does not replace them. The information given is based on our knowledge of the product, at the time of publication. It is given in good faith. Besides, the attention of the user is drawn to the possible risk incurred by using the product for any other use than that for which it was intended. In no way does this exempt the user from knowing and applying all the regulations controlling his activity. He alone will take on the responsibility for taking the precautions involved by the use of the product. The aim of all the mandatory regulations mentioned is just to help the user to fulfil his obligations regarding the use of hazardous products. This information must not be considered exhaustive. It does not exempt the user from ensuring that other obligations than those mentioned could apply, related to the storage and use of the product, this being his sole responsibility. End of document

SOCIETE BIC

14, Rue Jeanne d'Asnières 92611 CLICHY FRANCE

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