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FLAME RETARDANTS

79.90

Br

15

35

Brominated Flame Retardants Phosphorus Flame Retardants Magnesium Flame Retardants Nitrogen Flame Retardants

P 30.97 Mg

24.31 12

14.01

N

7

ICL INDUSTRIAL PRODUCTS

Caring For Your Future Today

Manufacturing products to enhance safety and human well-being, ICL Industrial Products (ICL­IP), the industrial chemicals sector of Israel Chemicals Limited (ICL), is the world's largest producer of elemental bromine, and a leader in the production and marketing of bromine and bromine compounds, supplying over 33% of global demand. ICL-IP also has a leading position in the manufacturing of phosphorus based compounds for fire safety.

Resources and Quality

The Dead Sea has the world's highest concentration of bromine and supply is virtually unlimited. These rich natural resources combined with the most sophisticated workforce, enable ICL­IP to produce bromine, bromine based chemicals and minerals of the highest quality and in the most efficient way. Cutting-edge technology tamed by talented, knowledgeable and dedicated teams of individuals has inspired ICL-IP to integrate the complementary chemistry of phosphorus. It has resulted in diverse eco-friendly uses in industries such as flame retardants, plasticizers, hydraulic fluids, organic intermediates, water treatment and pharmaceutical chemicals, stabilizers, curing activators, viscosity enhancers, refractory materials, etc.

Unique Customer Service

ICL­IP offers its customers the advantage of geographic proximity to major markets, internationally based subsidiaries coordinating the supply of finished products to the customer's doorstep, experienced technical backup, and a workforce fully committed to quality and protection of the environment.

Global Production and Marketing Facilities

ICL­IP operates the world's largest elemental bromine production plant at the Dead Sea. The company's bromine compounds plants in Israel and the Netherlands, as well as Sinobrom, a JV in China, offer customer oriented manufacturing facilities based on their long standing technological expertise. ICL-IP is the industry leader in the manufacture, distribution and service of phosphorus based flame retardants, plasticizers, lubricants and hydraulic fluids, with production plants in the US, Germany and China in 2009. The company's worldwide marketing subsidiaries are: ICL-IP Europe B.V., The Netherlands; ICL-IP Israel Sales Office; ICL-IP America Inc., USA; ICL-IP Japan Ltd., Japan; ICL Asia Ltd., Hong-Kong, ICL China, PR China and ICL Brasil, Brazil.

Safety, Ecology and Quality Assurance

Strict adherence to international regulations on safety and environmental issues are core policies at ICLIP. ICL-IP's major plants have been granted ISO 14001 and OHSAS 18001 accreditations for Environmental and Safety Management Systems. ICL-IP utilizes Total Quality Management, Lean and Six Sigma methodologies across its plants worldwide to ensure consistent quality and to achieve improvements in its processes. ICL-IP supports the goals of the new EU regulation Registration, Evaluation, Authorization and Restriction of Chemicals (REACH Regulation, EC 1907/2006) which came into force on June 1st 2007. This regulation ensures the protection of human health and the environment, while minimizing animal testing and maintaining the competitiveness of the European chemical industry. ICL-IP will fully comply with the requirements of REACH, and all other regulatory systems world-wide, for all its existing and new flame retardants. ICL-IP is very active in the initiation and development of a programme to reduce waste production and environmental emissions through a code of good practice known as the Voluntary Emission Control Action Programme ­ VECAP.

Dear customer!

This brochure is designed as a working tool for your needs in flame retardancy. We, at the Flame Retardant Business Unit (FR BU) of ICL­IP, offer the plastics industry the most effective Flame Retardants that help in enhancing consumer safety, while being committed to environmental concerns. We invite you to make use of this brochure, benefit from our wide range of Flame Retardant solutions and contact us for current activities and future developments.

Response to needs of Markets and Industries

The FR BU takes an in-depth view of the plastic industry's supply chain, so that its products and solutions are directly responsive to each market segment's special needs and challenges. We are continuously studying and monitoring the requirements and trends of these market segments, including their supporting industries. This enables us to offer a valuable contribution to our customers, in meeting their current needs and future requirements.

Flame Retardants for most Applications

Using the vast natural resource of Bromine and Minerals in the Dead Sea, ICL-IP produces a series of high quality Flame Retardant products, applicable to a wide range of plastics, polymers and polymer alloys. ICL-IP also offers the world's most comprehensive range of phosphorus-based flame retardants, fire resistant plasticizers and hydraulic fluids for high demanding applications. Bromine and Phosphorus based Flame Retardants are considered as the two most efficient FR families and in fact, they constitute approximately 55% (in value) of the total FR usage. ICL­IP's portfolio also includes few additional Non-Halogen and Non-Phosphorus based FRs such as high purity grades of Magnesium Hydroxide and Melamine Cyanurate.

PolyquelTMTMTM,

and

series

As a part of the FR BU's focus on market needs, we have initiated a unique approach of developing tailor made solutions: · PolyquelTM is a new fully active and dust-free polymeric flame retardant series, as a step forward to comply with the industry's most stringent environmental guidelines such as European REACH and US TSCA legislations. · SaFRon® series for high demanding thermoplastic and polyurethane foam applications. · TexFRon® series for high quality textile back coating applications.

Polymeric Flame Retardants for Sustainability

Polymeric flame retardants are sustainable products in the view of many national and international human health and environmental regulations. They have long been recognized as the safest and most "elegant" way to flame retard high molecular weight man made materials. Non leaching With their low solubility in water, polymeric flame retardants, once they are incorporated into the end-product plastic matrix, become integrated with the plastic and leaching is not expected to occur. Non bio-accumulative Their high molecular weight makes them unlikely to penetrate through the cell membranes of living tissue. Non-blooming Furthermore, they do not migrate to the surface of the plastic during aging, thus eliminating any potential blooming in the finished product. ICL-IP is promoting several ranges of brominated polymeric flame retardants for most applications: · FR-1025: brominated polyacrylate · F-2000series: brominated epoxy polymers with a wide range of molecular weight · F-3000series: end-capped brominated epoxy polymers with various molecular weight · FR-803P: brominated polystyrene

SELECTION TABLE

Unsaturated Polyesters Chip / Particle Boards Rubbers / Elastomers Nylon = Polyamide Latex / Adhesives Phenolic Resins Textiles / Fibers Polypropylene

PVC / Flexible

Polyethylene

Epoxy Resins

Flexible PUF

PC / PC ABS

APPLICATIONS

EPS / XPS HIPS

BROMINATED FLAME RETARDANTS

FR-11 FR-245 FR-370 FR-513 FR-522 FR-613 FR-720 FR-803P FR-1025M FR-1025 FR-1206 FR-1210 FR-1524

BROMINATED EPOXY FLAME RETARDANTS

F-2001 F-2200 F-2016, F-2300 F-2100, F-2100L, F-2300H, F-2400, F-2400H F-3014, F-3020, F-3516 F-3100

TAILOR MADE FR SOLUTIONS

PolyquelTM 240, PolyquelTM 241 5371 5531 6605 7700 P series, 9020, 9025

FR Intermediates

Rigid PUF

PBT / PET

Alloys

ABS

PVC / Flexible

Polyethylene

Epoxy Resins

Flexible PUF

PC / PC ABS

HIPS / PPO

FYROLTM SERIES

Fyrol FR-2 Fyrol HF-4 Fyrol 6 Fyrol FR-7 Fyrol 38 Fyrol A300TB Fyrol PCF Fyrol PMP Fyrol PNX Fyrol PNX-LE

FYROLFLEXTM

Fyrolflex BDP Fyrolflex RDP Fyrolflex Sol-DP

PHOSFLEXTM

Phosflex 4 Phosflex 31L/41L Phosflex 71B Phosflex 362 Phosflex 390 Phosflex 418 Phosflex T-BEP

LINDOLTM

Lindol Lindol XP Plus

MAGNESIUM & NITROGEN FLAME RETARDANTS

FR-20 FR-6120 FOR MORE INFORMATION VISIT OUR WEBSITE: WWW.ICLFR.COM

Rigid PUF

EPS / XPS

PBT / PET

PHOSPHORUS FLAME RETARDANTS

Cellulosic Plastic Composite

Unsaturated Polyesters

Chip / Particle Boards

Rubbers / Elastomers

Nylon = Polyamide

Latex / Adhesives

Phenolic Resins

Textiles / Fibers

Polypropylene

Alloys

ABS

PRODUCTS & PROPERTIES

BROMINATED FLAME RETARDANTS

M.W. SPECIFIC GRAVITY BROMINE CONTENT MELTING RANGE/POINT TGA %WT. LOSS @ TEMP.

FR-11

Ammonium bromide APPLICATIONS: Chipboard, Wood Paper, Textile

NH4Br

97.9

2.43

81%

M.P. 452°C

CAS No. 12124-97-9

FR-245

Br O Br Br N Br O N N O

Br Br Br Br

Tris(tribromophenoxy) triazine APPLICATIONS: HIPS, ABS ADVANTAGES: combination of good flow and impact, UV and thermal stability, non-blooming

1067

2.44

67%

M.P. 230°C

2% @ 360°C 5% @ 385°C 10% @ 400°C

CAS No. 25713-60-4

Br

FR-370

Tris(tribromoneopentyl) phosphate APPLICATIONS: PP, HIPS, ABS, XPS, Alloys, Adhesives ADVANTAGES: UV and light stability, non-blooming

1018.5

CH2Br O=P­ OCH2­C­CH2Br CH2Br

|

3

2.30

|

70% (3% P)

M.P. 181°C

1% @ 282°C 5% @ 309°C 10% @ 319°C

CAS No. 19186-97-1 324.9 2.30 73% M.P. 65°C 2% @ 135°C 5% @ 152°C 10% @ 166°C

FR-513

Tribromoneopentyl alcohol APPLICATIONS: PU rigid and flexible foams, FR intermediate ADVANTAGES: meets high FR standards, high thermal stability, non-leaching

CH2Br HO­CH2­C­CH2­Br CH2Br

| |

CAS No. 36483-57-5 261.9 2.23 60% M.P. 109.5°C 2% @ 200°C 5% @ 225°C 10% @ 245°C

FR-522

Dibromoneopentyl glycol APPLICATIONS: UPE, PU rigid foams ADVANTAGES: high level of flame retardancy, light stability, transparency

CH2Br HO­CH2­C­CH2­OH CH2Br

| |

CAS No. 3296-90-0

OH

FR-613

Tribromophenol APPLICATION: FR Intermediate ADVANTAGE: end capping of brominated epoxies

330.8

Br

2.55

72%

Br

M.P. 93°C

5% @ 120°C 10% @ 132°C

Br

CAS No. 118-79-6

FR-720

Tetrabromobisphenol A bis(2,3 dibromopropyl ether) APPLICATIONS: PP, HIPS, ABS ADVANTAGES: good FR efficiency and thermal stability

Br

CH3 C

| |

Br OCH2CHCH2Br | Br Br

943.2

2.30

68%

M.R. 113-117°C

BrCH2CHCH2O | Br Br

CH3

1% @ 291°C 5% @ 306°C 10% @ 313°C

CAS No. 21850-44-2

FR-803P (polymer)

Brominated polystyrene APPLICATIONS: Nylon, PBT, PET ADVANTAGES: good CTI, thermal stability, non-blooming

­CH­CH2­

600000

n

2.1

x=2.7

\ Brx

66% min.

S.R. 265-324°C

2% @ 340°C 5% @ 358°C 10% @ 374°C

CAS No. 88497-56-7

BROMINATED AND BROMINATED EPOXY FLAME RETARDANTS

M.W. SPECIFIC GRAVITY BROMINE CONTENT MELTING RANGE/POINT TGA %WT. LOSS @ TEMP.

FR-1025M

Brominated acrylate monomer APPLICATIONS: Latex, Rubbers ADVANTAGES: reactive monomer, thermal stability, improves compatibility in polymer matrix

H2C=CH C=O Br\ O--CH2-- Br/

\

556.5

/

2.50

71%

| |

Br --Br

M.P. 117°C

2% @ 295°C 5% @ 319°C 10% @ 327°C

Br

CAS No. 59447-55-1

FR-1025 (polymer)

Brominated polyacrylate APPLICATIONS: PBT, Nylon, Alloys ADVANTAGES: excellent thermal aging, CTI, good impact, compatibility with fiber reinforcement and recycling

--CH2--CH--n C=O Br\ O--CH2-- Br/

\

oligomer

/

2.50

71%

| |

M.R. 190-220°C

Br --Br

2% @ 320°C 5% @ 330°C 10% @ 335°C

Br

CAS No. 59447-57-3

Br\ Br/ / Br Br

\

FR-1206

Hexabromocyclododecane APPLICATIONS: EPS, XPS ADVANTAGES: high purity, low loading and good FR efficiency

/

641.7

Br

2.18

73%

M.R. 175-185°C

\

2% @ 243°C 5% @ 247°C 10% @ 249°C

Br

CAS No. 3194-55-6

FR-1210

Decabromodiphenyl oxide APPLICATIONS: HIPS, PE, PP, ABS, PBT, UPE, Epoxy, Nylon 6, Textiles ADVANTAGES: FR efficiency, exceptional thermal stability and multi-purpose.

Br\ Br-- Br/

/

Br Br\ --O--

/

Br --Br

959.2

3.45

83%

M.P. 305°C

1% @ 322°C 5% @ 362°C 10% @ 385°C

\

Br Br/

\

Br

CAS No. 1163-19-5 543.7 2.17 58.5% M.P. 181°C 2% @ 262°C 5% @ 284°C 10% @ 301°C

FR-1524

Tetrabromobisphenol-A APPLICATIONS: Epoxy, Polycarbonate Resins, ABS ADVANTAGES: high reactivity, low color, high clarity, good FR efficiency good solubility

Br\ HO-- Br/

CH3 --C -- CH3

| |

/

Br --OH

\

Br

CAS No. 79-94-7

F-2000 SERIES - Brominated Epoxy - Low molecular weight

F-2001

APPLICATIONS: Unsaturated polyester and vinyl ester resins ADVANTAGES: UV stability, solubilty in styrene

Br\ --O-- Br/ CH3 --C -- CH3

| |

/

Br

OH

|

n

1000

1.80

49-51%

--O\ /CH\ CH2-- -- \Br CH2

M.R. 60-70°C

1% @ 280°C 5% @ 320°C 10% @ 340°C

CAS No. 68928-70-1

F-2200 HM (Proprietary)

APPLICATIONS: XPS, HIPS, Polyolefins ADVANTAGES: Thermal stabilizer, corrosion resistant, processing aid

Br\ --O-- Br/

CH3 --C -- CH3

| |

/

Br

OH

|

700

1.80

48%

\

--O\ /CH\ Br CH2 CH2-- n --

M.R. 108-118°C

1% @ 289°C 5% @ 326°C 10% @ 343°C

CAS No. 3072-84-2

FOR MORE INFORMATION VISIT OUR WEBSITE: WWW.ICLFR.COM

PRODUCTS & PROPERTIES

BROMINATED EPOXY FLAME RETARDANTS

M.W. SPECIFIC GRAVITY BROMINE CONTENT SOFTENING RANGE/TG TGA %WT. LOSS @ TEMP.

F-2000 SERIES - Brominated Epoxy polymer

Br\ --O-- Br/ CH3 --C -- CH3

| |

/

Br

OH

|

n

--O\ /CH\ CH2-- -- \Br CH2

CAS No. 68928-70-1

F-2016 (polymer)

APPLICATION: ABS ADVANTAGES: good processability, high thermal and UV stability, non-blooming

1600

1.80

50%

S.R. 105-121°C

2% @ 318°C 5% @ 340°C 10% @ 358°C

F-2100L (polymer)

APPLICATIONS: PBT, PC/ABS ADVANTAGES: high thermal and UV stability, non-blooming, non corrosive, excellent processability

10000

1.80

52%

170-190°C

1% @ 332°C 5% @ 338°C 10% @ 353°C

F-2100 (polymer)

APPLICATIONS: PBT, PC/ABS ADVANTAGES: high thermal and UV stability, non-blooming, non-corrosive, excellent processability

20000

1.80

52%

S.R. 180-205°C

1% @ 332°C 5% @ 339°C 10% @ 353°C

F-2300H (polymer)

APPLICATIONS: PBT, PET, Alloys (PC/ABS) ADVANTAGES: good mechanical, physical and flow properties, high thermal and UV stability

21500

1.80

52%

Tg 130-150°C

2% @ 337°C 5% @ 344°C 10% @ 349°C

F-2400 (polymer)

APPLICATIONS: PBT, PET, Nylon, TPU, Alloys, ABS ADVANTAGES: high thermal and UV stability, non-blooming, excellent processability

50000

1.80

53%

Tg 145-155°C

2% @ 339°C 5% @ 347°C 10% @ 353°C

F-3000 SERIES - End capped Brominated Epoxy

OH Br

|

/

CH / \ CH2CH2 Br / \ | O\ /O Br

\

|

OH Br

|

\/

CH / \ CH2CH2 Br / \ | O\ /O Br

n

\

|

Br

Br

/

C / \ H3C CH3

Br

/

Br

\

F-3014

APPLICATIONS: HIPS, ABS ADVANTAGES: good processability, nonblooming, high thermal and UV stability, good HDT impact strength, low metal adhesion

1400

1.90

60%

S.R. 87-105°C

2% @ 338°C 5% @ 354°C 10% @ 356°C

CAS No. 158725-44-1 2000 1.90 56% S.R. 105-120°C 2% @ 348°C 5% @ 360°C 10% @ 366°C

F-3020 (polymer)

APPLICATIONS: HIPS, ABS ADVANTAGES: good processability, nonblooming, hight thermal and UV stability, good HDT impact strength, low metal adhesion

CAS No. 135229-48-0 1600 1.90 54% S.R. 107-117°C 2% @ 326°C 5% @ 355°C 10% @ 365°C

F-3516

APPLICATIONS: HIPS, ABS ADVANTAGES: high thermal and UV stability, excellent flow properties, non-blooming low metal adhesion

CAS No. 158725-44-1 15000 1.90 53% S.R. 180-220°C 2% @ 338°C 5% @ 340°C 10% @ 354°C

F-3100 (polymer)

APPLICATIONS: PBT, Nylon, Alloys, ABS ADVANTAGES: processing - aid, excellent flow properties, non-blooming low metal adhesion and good thermal and UV stability

CAS No. 135229-48-0

PHOSPHORUS FLAME RETARDANTS

SPECIFIC GRAVITY PHOSPHORUS CONTENT CHLORINE CONTENT VISCOSITY mPa.s - 25°C TGA %WT. LOSS @ TEMP.

FYROLTM SERIES

Fyrol FR-2

Tris (1,3-dichloroisopropyl) phosphate APPLICATIONS: Flexible PU foam, epoxy resin and phenolics, unsaturated polyesters ADVANTAGES: Excellent processing, good thermal and hydrolytic stability, low fogging 1.52

O CH2Cl || / P­O­CH \ CH2Cl

7.1%

49.0%

1800

2% @ 205°C 5% @ 225°C 10% @ 240°C

3

CAS No. 13674-87-8 1.18 Proprietary stabilized flame retardant 8.5% 70 2% @ 215°C 5% @ 235°C 10% @ 250°C

Fyrol HF-4

Proprietary halogen-free flame retardant APPLICATIONS: Flexible PU foam ADVANTAGES: Excellent processing, low viscosity, low scorch.

Fyrol 6

Diethyl N,N bis (2-hydroxyethyl) aminomethylphosphonate APPLICATIONS: Reactive non halogen FR for rigid PU foam and urethane elastomers ADVANTAGES: Excellent for spray, pour-inplace systems and slab foams

O

|| |

C2H4­OH

/ \

1.16

12.0%

200

C2H5­O­P­CH2­N O C 2H 5

|

5% @ 170°C 10% @ 195°C

C2H4­OH

CAS No. 2781-11-5 1.31 Proprietary chlorinated phosphate ester blend Prop. Prop. 290 2% @ 210°C 5% @ 230°C 10% @ 240°C

Fyrol FR-7

Proprietary chlorinated phosphate ester blend APPLICATIONS: Flexible PU foam ADVANTAGES: Good compression set and IFD, low scorch

Fyrol 38

Modified tris(1,3-dichloro-2-propyl) phosphate APPLICATIONS: Flexible PU foam ADVANTAGE: Low scorch version of Fyrol FR-2 CAS No. 13674-87-8

1.52

7.1%

49.0%

1800

2% @ 205°C 5% @ 225°C 10% @ 240°C

Fyrol A300TB

Proprietary chloralkyl phosphate blend APPLICATIONS: Flexible PU foam for automotive applications ADVANTAGES: Easy processing, meeting the fogging requirement of the automotive industry

1.48 Proprietary chloroalkyl phosphate ester blend

7.1%

47

1050

2% @ 195°C 5% @ 215°C 10% @ 235°C

Fyrol PCF

Tris (1-chloroisopropyl) phosphate. APPLICATIONS: Isocyanurate and rigid PU foams, flexible PU foam (BS5852), unsaturated polyesters and phenolics ADVANTAGES: Excellent thermal and hydrolytic stability, low viscosity

O CH2Cl || / P­O­CH \ CH3

1.29

9.5%

32.5%

65

2% @ 145°C 5% @ 165°C 10% @ 180°C

3

CAS No. 13674-84-5 1.30

O (HO)n

\ /

Fyrol PMP

Poly-(m-phenylene methylphosphonate) APPLICATIONS: Curing agent for epoxy resin ADVANTAGES: High glass transition, excellent thermal stability

17.5%

O­P­O | \ CH3

||

O

/

O­P­O | \ CH3

p

||

/

(OH)m

m,n=

2200 @120°C

2% @ 340°C 5% @ 385°C 10% @ 425°C

0 or 1

CAS No. 63747-58-0

FOR MORE INFORMATION VISIT OUR WEBSITE: WWW.ICLFR.COM

PRODUCTS & PROPERTIES

PHOSPHORUS FLAME RETARDANTS

SPECIFIC GRAVITY PHOSPHORUS CONTENT CHLORINE CONTENT VISCOSITY mPa.s - 25°C MELTING RANGE TGA %WT. LOSS @ TEMP.

FYROLTM SERIES

Fyrol PNX

Oligomeric ethyl ethylene phosphate APPLICATIONS: Flexible PU foam, paper treatment ADVANTAGES: very high efficiency, low VOC/ FOG

O

|| |

O

|| |

n

1.31

19%

2250

C2H5­O­P­O­(CH2)2­O­P­O­C2H O C 2H 5

|

O C 2H 5

|

2% @ 185°C 5% @ 215°C 10% @ 235°C

CAS No. 184538-58-7

Fyrol PNX-LE

Modified oligomeric ethyl ethylene phosphate APPLICATIONS: Flexible PU foam, ADVANTAGE: Low scorch version of Fyrol PNX, low fogging/VOC for automotive CAS No. 184538-58-7

1.31

19%

2250

2% @ 185°C 5% @ 215°C 10% @ 235°C

FYROLFLEXTM SERIES

Fyrolflex BDP

Bisphenol A bis(diphenyl phosphate) APPLICATIONS: Polycarbonate and its alloys, polyphenylene ether blends, styrenics ADVANTAGES: High thermal stability, good hydrolytic stability

O ­O­P­O­ O

| | ||

CH3 ­C­ CH3

| |

O ­O­P­O­

n |

1.27

8.9%

515 @55°C

||

O

|

2% @ 275°C 5% @ 330°C 10% @ 395°C

CAS No. 5945-33-5

Fyrolflex RDP

Resorcinol bis(diphenyl phosphate) APPLICATIONS: Polycarbonate and its alloys, polyphenylene ether blends, styrenics, phenolic laminates ADVANTAGES: High efficiency, high thermal stability

O ­O­P­O\ O

| | ||

O

/

1.31

10.7%

105 @ 55°C

O­P­O­

n |

||

O

|

2% @ 290°C 5% @ 325°C 10% @ 360°C

CAS No. 125997-21-9 1.30 Proprietary aromatic phosphate, solid powder 10.5% M.R. 105-108°C 2% @ 300°C 5% @ 335°C 10% @ 350°C

Fyrolflex Sol-DP

Proprietary aromatic phosphate APPLICATIONS: Polycarbonate and its alloys, polyphenylene ether blends, UL94/V-2 ABS, processing aid for engineering resins ADVANTAGES: Easy to handle solid freeflowing powder, high efficiency and good hydrolytic stability

PHOSFLEXTM SERIES

Phosflex 4

Tributyl phosphate APPLICATIONS: De-airing additive, extraction agent in metal and phosphoric acid production, high-boiling solvent for inks and paints. ADVANTAGE: Low viscosity

O

||

0.98

3

11.7%

5

P­O­C4H9

2% @ 115°C 5% @ 135°C 10% @ 150°C

CAS No. 126-73-8

O ­O­P­O­

n

Phosflex 31L/41L

Isopropylated triphenyl phosphate mixture APPLICATIONS: PVC film and sheeting compounds, PVC plastisols. ADVANTAGES: High thermal stability, good solvating properties

1.18

CH3 \ / CH / H 3C 3-n

8.3%

60

||

2% @ 210°C 5% @ 230°C 10% @ 245°C

CAS No. 68937-41-7

PHOSPHORUS FLAME RETARDANTS

SPECIFIC GRAVITY PHOSPHORUS CONTENT CHLORINE CONTENT VISCOSITY mPas - 25°C TGA %WT. LOSS @ TEMP.

Phosflex 71B

t-Butylated triphenyl phosphate mixture APPLICATIONS: Plasticizer for PVC and PVC foams, polyvinyl acetate emulsion, FR for modified HIPS, functional fluid ADVANTAGE: High thermal stability

O ­O­P­O­

n

1.18

CH3 \ / C H 3C

/ \

8.5%

70

||

2% @ 215°C 5% @ 235°C 10% @ 250°C

CH3

CAS No. 56803-37-3 and 65652-41-7 and 78-33-1

O

||

2

3-n

Phosflex 362

2-ethylhexyl diphenyl phosphate APPLICATIONS: Plasticizer for PVC (plastisols, textile coatings), and vinyl/nitrile rubber foamed alloys, cellulosic polymers, PMMA, PS ADVANTAGES: Good performance at low temperature, low smoke, FDA approved in coatings for food packaging.

C 2H 5

|

1.09

8.5%

18

­O­P­O­CH2­CH­(CH2)3­CH3

2% @ 180°C 5% @ 200°C 10% @ 210°C

CAS No. 1241-94-7

O ­O­P­O­C10H21

2

Phosflex 390

Isodecyl diphenyl phosphate APPLICATIONS: Plasticizer for PVC sheeting, foamed vinyl/nitrile rubber alloys, wire insulation, coatings for apparel and upholstery, polyvinyl acetate adhesives ADVANTAGES: Good performance at low temperature, low smoke

1.07

7.9%

26

||

2% @ 205°C 5% @ 220°C 10% @ 235°C

CAS No. 29761-21-5 1.04 7.2% 24 5% @ 215°C 10% @ 235°C

Phosflex 418

Linear alkyl diphenyl phosphate APPLICATIONS: Plasticizer for PVC sheeting and wire insulation ADVANTAGES: Excellent plasticizing efficiency at low temperature, low smoke and low volatility

CAS No. 27460-02-2 and 142474-86-0 1.02

3

Phosflex T-BEP

Tris(butoxyethyl) phosphate APPLICATIONS: Emulsions of floor finishes, leveling agent in latex paints, processing aid for acrylonitrile rubber, antiblock agent for cast polyurethanes ADVANTAGE: Low viscosity

O

||

7.8%

12

P­O­(CH2)2­O­C4H9

2% @ 170°C 5% @ 200°C 10% @ 225°C

CAS No. 78-51-3

LINDOLTM SERIES

Lindol & Lindol XP Plus

Tri(m,p-cresyl) phosphate mixture APPLICATIONS: Plasticizer for PVC, synthetic rubber, cellulosic films, FR for phenolic laminates ADVANTAGE: High efficiency

O

||

1.17

\ CH3

8.4%

65

P­O­

2% @ 220°C 5% @ 235°C 10% @ 250°C

3

CAS No. 1330-78-5

PHOS-CHEKTM SERIES

Phos-ChekTM product line are efficient intumescent Flame Retardants for application in paints, coatings, polyolefins, polyurethanes and

thermosets. Selected ICL-IP Subsidiaries have distribution agreements with ICL - Performance Products LP, the producer of Phos-ChekTM. For more information, visit the website: www.phoschek.com or contact one of the following addresses: [email protected], [email protected]

FOR MORE INFORMATION VISIT OUR WEBSITE: WWW.ICLFR.COM

PRODUCTS & PROPERTIES

MINERAL AND NITROGEN FLAME RETARDANTS

M.W. SPECIFIC GRAVITY AVG. PARTICLE SIZE BULK DENSITY g/m3 TGA %WT. LOSS @ TEMP.

MAGNESIUM AND NITROGEN BASED FLAME RETARDANTS

Magnesium Hydroxide GRADES: S5 (BET 5 m2/g) uncoated or coated S7 (BET 7 m2/g) uncoated or coated S10 (BET 10 m2/g) uncoated or coated APPLICATIONS: Wire and Cables, Electrical connectors, TPO for roofing, Foils and sheets, LD and HDPE, PP, Nylon, Soft PVC ADVANTAGES: excellent smoke suppressant, acid scavenger, thermal stability

FR-20

Mg(OH)2

58.3

2.36 1.8-2.2 µm 1.5-1.8 µm 1.1-1.4 µm

0.5-0.7

2% @ 370°C 5% @ 385°C 10% @ 402°C

CAS No. 1309-42-8 255.2

NH2 N H2N N N HN NH2 O N H O NH O

FR-6120 Powder (Granules as an option)

1.70

Melamine Cyanurate APPLICATIONS: Nylon, PBT, TPU ADVANTAGES: CTI, good FR efficiency

2.5 µm (0.5-1.5 mm)

0.3 - 0.4 (0.6)

1% @ 300°C 5% @ 340°C 10% @ 360°C

CAS No. 37640-57-6

POLYQUELTMTM,

AND

SERIES TAILOR-MADE SOLUTIONS

PolyquelTM series, fully active and dust-free polymeric FR systems, is a step forward to more Eco-reliable and Sustainable Fire Safety. and Series is a milestone offering continuously innovative solutions to the identified needs of customers. These The range of tailor-made solutions address specific targets related to fire safety, easier handling, low corrosion, high flow, light and UV stability and/or antimony trioxide free products. The FR BU's solutions are opening up new fields of application. and : The following table shows some of our new commercial PolyquelTM,

Strengths:

POLYQUELTMTM,

POLYQUELTM 145 POLYQUELTM 240 & 241 5371

AND

SERIES

D D P U D P U P

U A E

5531 Antidrip Series 6605 7700 9020 P Series 9025

E

E

E

E

A U T

A U T

E E

E T E T P

P

Cellulosic Plastic Composite

Unsaturated Polyesters

Chip / Particle Boards

Rubbers / Elastomers

Nylon = Polyamide

Latex / Adhesives

Phenolic Resins

Textiles / Fibers

Polypropylene

PVC / Flexible

Polyethylene

Epoxy Resins

Flexible PUF

PC / PC ABS

U - UV stability A - Antimony oxide free E - FR efficiency D - Dust-free T - Thermal stability P - Polymer & Non-blooming

HIPS / PPO EPS / XPS ABS

Rigid PUF

PBT / PET

Alloys

APPLICATIONS

THERMOPLASTICS AND STYRENIC ALLOYS HIPS V-1/V-0

FR-1210* PROPERTIES THERMAL STABILITY MELT FLOW FR EFFICIENCY IMPACT UV / LIGHT STABILITY HEAT DISTORTION TEMP. NON-BLOOMING COST EFFICIENCY RECYCLING DUST-FREE FR-245 F-3000 PolyquelTM 240 PolyquelTM 241

HIPS V-2

FR-720 PROPERTIES THERMAL STABILITY MELT FLOW FR EFFICIENCY IMPACT UV / LIGHT STABILITY HEAT DISTORTION TEMP. NON-BLOOMING COST EFFICIENCY

* Not RoHS compliant and restricted applications in the US.

FR-1210*

FR-245

FR-370

FOR MORE INFORMATION VISIT OUR WEBSITE: WWW.ICLFR.COM

APPLICATIONS

THERMOPLASTICS AND STYRENIC ALLOYS ABS V-1/V-0

FR-1524 PROPERTIES THERMAL STABILITY MELT FLOW FR EFFICIENCY IMPACT UV / LIGHT STABILITY HEAT DISTORTION TEMP. NON-BLOOMING COST EFFICIENCY RECYCLING DUST-FREE FR-245 F-2000

Low MW

F-2000

High MW

F-3000

PolyquelTM 240

PolyquelTM 241

PC/ABS and HIPS/PPO alloys V-1/V-0

Fyrolflex RDP PROPERTIES PHOSPHORUS (P)/BROMINE (Br) BASED THERMAL STABILITY MELT FLOW FR EFFICIENCY IMPACT UV / LIGHT STABILITY HYDROLYTIC STABILITY HEAT DISTORTION TEMP. NON-PLATE-OUT COST EFFICIENCY LIQUID/SOLID HANDLING P P P P Br Fyrolflex BDP Fyrolflex Sol-DP Phosflex 71B

5531

Liquid

Liquid

Solid

Liquid

Solid

good very good excellent

THERMOPLASTICS AND STYRENIC ALLOYS PP

FR-370 PROPERTIES THERMAL STABILITY PROCESSABILITY FR EFFICIENCY IMPACT UV / LIGHT STABILITY NON-BLOOMING COST EFFICIENCY RATING V-2 FR-720 FR-1210 FR-1025 FR-20

5371

V-0/V-2

V-0/V-2

V-0 V-0 V-0

PE

FR-720 PROPERTIES THERMAL STABILITY MELT FLOW FR EFFICIENCY IMPACT UV / LIGHT STABILITY NON-BLOOMING COST EFFICIENCY DUST-FREE FR-1210 FR-1025 FR-20 PolyquelTM 145

FOR MORE INFORMATION VISIT OUR WEBSITE: WWW.ICLFR.COM

APPLICATIONS

ENGINEERING PLASTICS POLYAMIDE

Non reinforced PA 6 and 6,6 V-O

FR-803P PROPERTIES THERMAL STABILITY MELT FLOW FR EFFICIENCY IMPACT COMPARATIVE TRACKING INDEX THERMAL AGING RECYCLING UV / LIGHT STABILITY HEAT DISTORTION TEMP. NON-BLOOMING COST EFFICIENCY

FR-1025

FR-1210*

F-2400

FR-6120

FR-20

* only for Polyamide 6 / Not RoHS compliant and restricted applications in the US.

POLYAMIDE

Glass reinforced PA 6 and 6,6 V-0

FR-803P PROPERTIES THERMAL STABILITY MELT FLOW FR EFFICIENCY IMPACT COMPARATIVE TRACKING INDEX THERMAL AGING RECYCLING UV / LIGHT STABILITY HEAT DISTORTION TEMP. NON-BLOOMING COST EFFICIENCY

FR-1025

FR-1210*

F-2400

F-3100

good very good excellent

* only for Polyamide 6 / Not RoHS compliant and restricted applications in the US.

ENGINEERING PLASTICS PBT V-0

FR-1025 PROPERTIES THERMAL STABILITY MELT FLOW FR EFFICIENCY IMPACT COMPARATIVE TRACKING INDEX THERMAL AGING RECYCLING UV / LIGHT STABILITY HEAT DISTORTION TEMP. NON-BLOOMING COST EFFICIENCY F-3100 F-2000

series

FR-803P

FR-1210*

5531

to

PVC & TEXTILE ADHESIVES COATING (TAC) FLEXIBLE PVC

Phosflex 31L/41L PROPERTIES FR EFFICIENCY PLASTICIZING PERFORMANCE LOW TEMPERATURE FLEXIBILITY LOW SMOKE LOW VOLATILITY/SURFACE MIGRATION LOW SMELL CHEMICAL RESISTANCE (OIL FATS) FOOD APPROVAL COST EFFICIENCY Phosflex 71B Phosflex 362 Phosflex 390 Lindol

**

* Not RoHS compliant and restricted applications in the US. ** FDA Contact in coatings for confectionary applications

FOR MORE INFORMATION VISIT OUR WEBSITE: WWW.ICLFR.COM

APPLICATIONS

PVC & TEXTILE ADHESIVES COATING (TAC) TAC

BACK COATING

PROPERTIES PHOSPHORUS (P)/BROMINE (Br) BASED FR EFFICIENCY TRANSPARENCY LOW MELTING TEMPERATURE WATER BASED DISPERSION SOLID (S)/LIQUID (L) LOW FOGGING COST EFFICIENCY

* Restricted applications in the US

FR-1210*

9020 Br/P

9025 Br

Fyrolflex

BDP/RDP

Fyrol

FR-2

Br

P

P+Cl

L

S

L

L

L

COATING/PADDING

liquid FR systems

9020

9025

P

P+

SELECTION MATRIX COTTON POLYESTER POLYESTER/COTTON PROPERTIES FR EFFICIENCY TRANSPARENCY WASH DURABILITY SOFT HAND LOW FOGGING LOW MELTING TEMPERATURE POLYMERIC WATER BASED DISPERSION COST EFFICIENCY + + + + + + + + + +

ADHESIVES AND FIBERS

FR-720, with a unique combination of 68% of aromatic and aliphatic bromine on the same molecule, is a FR of choice for hotmelt adhesives applications.

FR-370, has unique combination of both high aliphatic bromine (70%) and phosphorus (3%) on the same molecule that

contributes to fire retardant efficiency with excellent UV and light stability. It is recommended for adhesives applications and for production of inherently flame retarded PP multifilament for textile applications

good very good excellent

PLASTIC FOAMS FLEXIBLE PUF

Fyrol FR-2 PROPERTIES LOW VISCOSITY FR EFFICIENCY LOW SCORCH LOW FOGGING COMPRESSION SET REACTIVE COST EFFICIENCY

* Also supplied in heated isocontainer

Fyrol HF-4

Fyrol FR-7

Fyrol 38

Fyrol A300TB

Fyrol PCF

Fyrol PNX

7700

FR-513*

Solid*

RIGID PUF

Fyrol 6 PROPERTIES LOW VISCOSITY FR EFFICIENCY SYSTEM STABILITY REACTIVE COST EFFICIENCY

* Also supplied in heated isocontainer

Fyrol PCF

6605

FR-513*

Solid*

EPS / XPS

Expanded and extruded polystyrene foams for building, construction and packaging industries are available in many forms: Sheets (thermal insulation), Profiles (decorative), Molded shapes (packaging). ICL-IP offers several flame retardants to match market needs in the various applications:

FR-1206 ILM

·Highpurity ·Lowermeltingrange ·Processing-aidduringextrusionofprofileorsheet

FR-1206 IHM

·Designedprimarilyforflame-retardedEPS ·Highpurity ·Readilysolubleinstyrenemonomer ·Enablesgoodcontroloftheparticlesizedistributionofthebeads

FR-370 and

·ProprietaryFRsystems ·Highthermalstabilityenableshighprocessingtemperatures ·Increasesproductivity ·Processing-aideffect

5371:

FOR MORE INFORMATION VISIT OUR WEBSITE: WWW.ICLFR.COM

ICL - INDUSTRIAL PRODUCTS

Head Office ICL-IP Ltd. Makleff House, 12 Kroitzer St., P.O.B. 180 Beer Sheva 84101, Israel Tel: +972 8 629 7608 Fax: +972 8 629 7846 E-mail: [email protected] Europe ICL-IP Europe B.V. Fosfaatweg 48, 1013 BM Amsterdam The Netherlands, or P.O. Box 465 1000 AL Amsterdam, The Netherlands Tel: +31 20 800 5800 Fax: +31 20 800 5805 E-mail: [email protected] North America and Mexico ICL-IP America Inc. 622 Emerson Road, Suite 500 St. Louis, Missouri 63141, USA Tel: +1 877 661 4272 Fax: +1 314 983 7610 E-mail: [email protected] South America ICL Brasil Ltda. Av. Major Sylvio de Magalhaes Padilha, 5200 Ed. Dallas Cj.22, 05693-000 Sao Paulo SP, Brazil Tel: +55 11 2155 4539 Fax: +55 11 2155 4507 E-mail: [email protected] Asia Pacific China ICL CHINA Room 908 Times Square Office Tower No 93 Middle Huai Hai Road Shanghai 200021, China Tel: +86 21 5386 3322 Fax: +86 21 5386 3336 E-mail: [email protected] Japan ICL-IP Japan Ltd. Izumi Shinkawa Building, 7th floor, 5-18, 1-chome Shinkawa, Chuo-ku, Tokyo 104-0033, Japan Tel: +81 3 3552 1611 Fax: +81 3 3552 1616 E-mail: [email protected] Other Asia Pacific ICL Asia Ltd. Room 2301, 23/F, Allied Kajima Building, 138 Gloucester Road, Wanchai, Hong Kong Tel: +852 2827 7761 Fax: +852 2824 1502 E-mail: [email protected] Other parts of the World ICL-IP Israel Sales Office Makleff House, 12 Kroitzer St., P.O.B. 180 Beer Sheva 84101, Israel Tel: +972 8 629 7633 Fax: +972 8 629 7819 E-mail: [email protected]

Visit our Website: www.iclfr.com Additional links: www.icl-ip.com · www.phoschek.com · www.bsef.com

GLOBAL PRESENCE

Although the information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed to be correct as of the date hereof, ICL INDUSTRIAL PRODUCTS. makes no representations as to the completeness, accuracy, quality or suitability of any information for any purpose. The use of the Information supplied herein shall be subject to and conditioned on that the persons receiving it and making use of it will make their own determination as to its safety and suitability for their purposes and applicable laws and other statutory demands prior to acquisitions, importations, exportations, transportations, implementations or uses of any kind. In no event will ICL INDUSTRIAL PRODUCTS. be responsible for damages of any nature whatsoever resulting, directly or indirectly, from the use or reliance upon Information. N O R E P R E S E N TAT I O N S O R W A R R A N T I E S , E I T H E R E X P R E S S E D O R I M P L I E D O F M E R C H A N TA B I L I T Y, F I T N E S S F O R A PA R T I C U L A R P U R P O S E O R O F A N Y O T H E R N AT U R E , A R E M A D E H E R E U N D E R W I T H R E S P E C T T O I N F O R M AT I O N O R T H E P R O D U C T T O W H I C H T H E I N F O R M AT I O N R E F E R S .

8/2010

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