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DAP-PL-3856.99

CERTIFICATE

TÜV Rheinland Immissionsschutz und Energiesysteme GmbH

Manufacturer:

Horiba Europe GmbH, Leichlingen

Measuring System: PG 250 Components: Test Report: CO, NO, NO2, SO2, CO2, O2 936/809014 TÜV Rheinland vom 20.01.2001

The measurement system fulfils the requirements of QAL 1 according to EN 14181 and EN ISO 14956.

Köln, 2008-10-08

Dr. rer. nat. Peter Wilbring

Dipl.-Chem. Martin Kerpa

www.umwelt-tuv.de / www.eco-tuv.com [email protected] Tel. +49 - 221 - 806 - 2275

TÜV Rheinland Immissionsschutz und Energiesysteme GmbH Am Grauen Stein 51105 Köln The company is accredited to DIN EN ISO/IEC 17025.

attached: 6 page(s)

EN ISO 14956 and prEN 15267-3 calculation for QAL 1 in EN 14181

Manufacturer data Manufacturer Measurement System Name Serial Number Measuring Principle TÜV Data Approval Report Date Editor Measurement Component Evaluation of the cross sensitivity (CS) to 21 Vol.-% Oxygen to 30 Vol.-% Humidity to 15 Vol.-% Carbon dioxide to 50 mg/m³ Methane to 100 mg/m³ Dinitrogen monoxide to 300 mg/m³ Nitrogen monoxide to 30 mg/m³ Nitrogen dioxide to 20 mg/m³ Ammonia to 1000 mg/m³ Sulphur dioxide to 200 mg/m³ Hydrogen chloride Sum of positive cross sensitivities Sum of negative cross sensitivities Calculation of the combined standard uncertainty Test Value Lack of fit Biggest interference (positiv or negativ) Span shift in the field test Zero shift in the field test Sensitivity to sample volume flow Sensitivity to ambient temperature Dependence on supply voltage Repeatability at span Field reproducibility Uncertainty of the test gas at the reference point Combined standard uncertainty (uC) Total expanded uncertainty Relative total expanded uncertainty Requirement

Horiba Europa gas measurement system PG250 5763470107, 5763470108 non dispersive IR

936/809014 20.01.2001 27.06.2005 Fr. Hamacher CO CS 0,00 0,00 -1,38 0,00 0,00 0,00 1,00 0,00 0,50 0,00 125

X max, j mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³

mg/m³

2,00 mg/m³ -1,38 mg/m³

u ( X max, j ) = X 3

u(X max,j ) 2

X

uL uI ud,s ud,z uv ut usv us uD utg uc (uc * k)

max, j

-0,50 2,00 -2,50 2,25 0,00 -4,50 0,00 0,00 0,94 2,50

mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³

-0,29 1,15 -1,44 1,30 0,00 -2,60 0,00 0,00 0,54 1,44

2

mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³

0,083 1,333 2,083 1,688 0,000 6,750 0,000 0,000 0,293 2,083 3,783 7,415 9,9 10,0

u c = (u max, j ) Uc = uc * 1,96 Uc in % of the limit 75 mg/m³ Uc in % of the limit 75 mg/m³

Result: Requirements keep to QAL 1 of EN 14181

EN ISO 14956 and prEN 15267-3 calculation for QAL 1 in EN 14181

Manufacturer data Manufacturer Measurement System Name Serial Number Measuring Principle TÜV Data Approval Report Date Editor Measurement Component Evaluation of the cross sensitivity (CS) to 21 Vol.-% Oxygen to 30 Vol.-% Humidity to 300 mg/m³ Carbon monoxide to 15 Vol.-% Carbon dioxide to 50 mg/m³ Methane to 100 mg/m³ Dinitrogen monoxide to 30 mg/m³ Nitrogen dioxide to 20 mg/m³ Ammonia to 200 mg/m³ Sulphur dioxide to 50 mg/m³ Hydrogen chloride Sum of positive cross sensitivities Sum of negative cross sensitivities Calculation of the combined standard uncertainty Test Value Lack of fit Biggest interference (positiv or negativ) Span shift in the field test Zero shift in the field test Sensitivity to sample volume flow Sensitivity to ambient temperature Dependence on supply voltage Repeatability at span Field reproducibility Uncertainty of the test gas at the reference point Combined standard uncertainty (uC) Total expanded uncertainty Relative total expanded uncertainty Requirement

Horiba Europa gas measurement system PG250 5763470107 und 5763470108 chemiluminescence

936 / 809014 27.06.2005 Fr. Hamacher NO CS 0,00 0,00 0,39 0,00 0,00 0,00 0,00 0,00 0,52 0,78 130

X max, j mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³

mg/m³

1,69 mg/m³ 0,00 mg/m³

u ( X max, j ) = X 3

u(X max,j ) 2

X

uL uI ud,s ud,z uv ut usv us uD utg uc (uc * k)

max, j

-0,52 1,69 -2,47 2,60 0,00 -4,42 0,00 0,00 1,21 2,60

mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³

-0,30 0,98 -1,43 1,50 0,00 -2,55 0,00 0,00 0,70 1,50

2

mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³

0,090 0,952 2,034 2,253 0,000 6,512 0,000 0,000 0,485 2,253 3,818 7,484 5,8 20,0

u c = (u max, j ) Uc = uc * 1,96 Uc in % of the limit 130 mg/m³ Uc in % of the limit 130 mg/m³

Result: Requirements keep to QAL 1 of EN 14181

EN ISO 14956 and prEN 15267-3 calculation for QAL 1 in EN 14181

Manufacturer data Manufacturer Measurement System Name Serial Number Measuring Principle TÜV Data Approval Report Date Editor Measurement Component Evaluation of the cross sensitivity (CS) to 21 Vol.-% Oxygen to 30 Vol.-% Humidity to 300 mg/m³ Carbon monoxide to 15 Vol.-% Carbon dioxide to 50 mg/m³ Methane to 100 mg/m³ Dinitrogen monoxide to 300 mg/m³ Nitrogen monoxide to 20 mg/m³ Ammonia to 1000 mg/m³ Sulphur dioxide to 200 mg/m³ Hydrogen chloride Sum of positive cross sensitivities Sum of negative cross sensitivities Calculation of the combined standard uncertainty Test Value Lack of fit Biggest interference (positiv or negativ) Span shift in the field test Zero shift in the field test Sensitivity to sample volume flow Sensitivity to ambient temperature Dependence on supply voltage Repeatability at span Field reproducibility Uncertainty of the test gas at the reference point Combined standard uncertainty (uC) Total expanded uncertainty Relative total expanded uncertainty Requirement

Horiba Europa gas measurement system PG250 5763470107 und 5763470108 chemiluminescence

936 / 809014 27.06.2005 Fr. Hamacher NO2 CS 0,00 0,00 0,00 0,00 0,00 0,80 0,00 0,00 0,00 0,80 200

X max, j mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³

mg/m³

1,60 mg/m³ 0,00 mg/m³

u ( X max, j ) = X 3

u(X max,j ) 2

X

uL uI ud,s ud,z uv ut usv us uD utg uc (uc * k)

max, j

3,20 1,60 -3,80 4,00 0,00 -5,80 0,00 0,00 1,86 4,00

mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³

1,85 0,92 -2,19 2,31 0,00 -3,35 0,00 0,00 1,07 2,31

2

mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³

3,413 0,853 4,813 5,333 0,000 11,213 0,000 0,000 1,147 5,333 5,666 11,106 5,6 20,0

u c = (u max, j ) Uc = uc * 1,96 Uc in % of the limit 200 mg/m³ Uc in % of the limit 200 mg/m³

Result: Requirements keep to QAL 1 of EN 14181

EN ISO 14956 and prEN 15267-3 calculation for QAL 1 in EN 14181

Manufacturer data Manufacturer Measurement System Name Serial Number Measuring Principle TÜV Data Approval Report Date Editor Measurement Component Evaluation of the cross sensitivity (CS) to 21 Vol.-% Oxygen to 30 Vol.-% Humidity to 300 mg/m³ Carbon monoxide to 15 Vol.-% Carbon dioxide to 50 mg/m³ Methane to 100 mg/m³ Dinitrogen monoxide to 300 mg/m³ Nitrogen monoxide to 30 mg/m³ Nitrogen dioxide to 20 mg/m³ Ammonia to 200 mg/m³ Hydrogen chloride Sum of positive cross sensitivities Sum of negative cross sensitivities Calculation of the combined standard uncertainty Test Value Lack of fit Biggest interference (positiv or negativ) Span shift in the field test Zero shift in the field test Sensitivity to sample volume flow Sensitivity to ambient temperature Dependence on supply voltage Repeatability at span Field reproducibility Uncertainty of the test gas at the reference point Combined standard uncertainty (uC) Total expanded uncertainty Relative total expanded uncertainty Requirement

Horiba Europa gas measurement system PG250 5763470107 und 5763470108 non dispersive IR

936/809014 27.06.2005 Fr. Hamacher SO2 CS 0,00 0,00 1,50 2,00 3,50 0,00 2,00 1,50 0,00 0,00 500

X max, j mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³

mg/m³

10,50 mg/m³ 0,00 mg/m³

u ( X max, j ) = X 3

u(X max,j ) 2

X

uL uI ud,s ud,z uv ut usv us uD utg uc (uc * k)

max, j

4,00 10,50 -9,50 10,00 0,00 -20,50 0,00 0,00 5,43 10,00

mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³

2,31 6,06 -5,48 5,77 0,00 -11,84 0,00 0,00 3,13 5,77

2

mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³

5,333 36,750 30,083 33,333 0,000 140,083 0,000 0,000 9,820 33,333 16,992 33,305 16,7 20,0

u c = (u max, j ) Uc = uc * 1,96 Uc in % of the limit 200 mg/m³ Uc in % of the limit 200 mg/m³

Result: Requirements keep to QAL 1 of EN 14181

EN ISO 14956 and prEN 15267-3 calculation for QAL 1 in EN 14181

Manufacturer data Manufacturer Measurement System Name Serial Number Measuring Principle TÜV Data Approval Report Date Editor Measurement Component Evaluation of the cross sensitivity (CS) to 21 Vol.-% Oxygen to 30 Vol.-% Humidity to 300 mg/m³ Carbon monoxide to 50 mg/m³ Methane to 100 mg/m³ Dinitrogen monoxide to 300 mg/m³ Nitrogen monoxide to 30 mg/m³ Nitrogen dioxide to 20 mg/m³ Ammonia to 1000 mg/m³ Sulphur dioxide to 200 mg/m³ Hydrogen chloride Sum of positive cross sensitivities Sum of negative cross sensitivities Calculation of the combined standard uncertainty Test Value Lack of fit Biggest interference (positiv or negativ) Span shift in the field test Zero shift in the field test Sensitivity to sample volume flow Sensitivity to ambient temperature Dependence on supply voltage Repeatability at span Field reproducibility Uncertainty of the test gas at the reference point Combined standard uncertainty (uC) Total expanded uncertainty Relative total expanded uncertainty Requirement

Horiba Europa Gasmessgerät PG250 5763470107 und 5763470108 pyroelektrischer Sensor

936 / 809014 20.01.2001 27.06.2005 Fr. Hamacher CO2 CS 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 20

X max, j Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-%

Vol.-%

0,00 Vol.-% 0,00 Vol.-%

u ( X max, j ) = X 3

u(X max,j ) 2

X

uL uI ud,s ud,z uv ut usv us uD utg uc (uc * k)

max, j

-0,12 0,00 0,34 0,16 0,00 0,34 0,00 0,00 0,27 0,40

Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-%

-0,07 0,00 0,20 0,09 0,00 0,20 0,00 0,00 0,16 0,23

2

Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-%

0,005 0,000 0,039 0,009 0,000 0,039 0,000 0,000 0,024 0,053 0,410 0,803 4 10,0

u c = (u max, j ) Uc = uc * 1,96 Uc in % of the upper range value 20 Vol.-% Uc in % of the upper range value 20 Vol.-%

Result: Requirements keep to QAL 1 of EN 14181

EN ISO 14956 and prEN 15267-3 calculation for QAL 1 in EN 14181

Manufacturer data Manufacturer Measurement System Name Serial Number Measuring Principle TÜV Data Approval Report Date Editor Measurement Component Evaluation of the cross sensitivity (CS) to 30 Vol.-% Humidity to 300 mg/m³ Carbon monoxide to 15 Vol.-% Carbon dioxide to 50 mg/m³ Methane to 100 mg/m³ Dinitrogen monoxide to 300 mg/m³ Nitrogen monoxide to 30 mg/m³ Nitrogen dioxide to 20 mg/m³ Ammonia to 1000 mg/m³ Sulphur dioxide to 200 mg/m³ Hydrogen chloride Sum of positive cross sensitivities Sum of negative cross sensitivities Calculation of the combined standard uncertainty Test Value Lack of fit Biggest interference (positiv or negativ) Span shift in the field test Zero shift in the field test Sensitivity to sample volume flow Sensitivity to ambient temperature Dependence on supply voltage Repeatability at span Field reproducibility Uncertainty of the test gas at the reference point Combined standard uncertainty (uC) Total expanded uncertainty Relative total expanded uncertainty Requirement

Horiba Europa Gasmessgerät PG250 5763470107 und 5763470108 galvanische Zelle

936 / 809014 27.06.2005 Fr. Landgraf O2 CS 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 25

X max, j Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-%

Vol.-%

0,00 Vol.-% 0,00 Vol.-%

u ( X max, j ) = X 3

u(X max,j ) 2

X

uL uI ud,s ud,z uv ut usv us uD utg uc (uc * k)

max, j

0,00 0,00 0,05 -0,05 0,00 0,08 0,00 0,00 0,15 0,38

Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-%

0,00 0,00 0,03 -0,03 0,00 0,04 0,00 0,00 0,09 0,22

2

Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-%

0,000 0,000 0,001 0,001 0,000 0,002 0,000 0,000 0,008 0,047 0,241 0,472 1,9 6,0

u c = (u max, j ) Uc = uc * 1,96 Uc in % of the upper range value 25 Vol.-% Uc in % of the upper range value 25 Vol.-%

Result: Requirements keep to QAL 1 of EN 14181

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