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MATERIAL SAFETY DATA SHEET
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1. Product and Company Identification
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Product Name UPC CODES
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Airwick® Air Freshener, All Scents (Aerosol) Refer to Section 16 Mixture Air freshener Reckitt Benckiser Morris Corporate Center IV 399 Interpace Parkway P.O. Box 225 Parsippany, NJ 07054-0225 In Case of Emergency: 1-800-228-4722 Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: 1-800-424-9300 Outside North America: 1-703-527-3887 Health 4 3 2 1 0 Flammability Physical Hazard
Personal Protection
CAS #
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Product use
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Manufacturer
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LEGEND HMIS/NFPA Severe Serious Moderate Slight Minimal
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0 3 0 A
1 0 0
2. Hazards Identification
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Emergency overview
CAUTION EYE IRRITANT. Prolonged or frequent skin contact may cause an allergic reaction. CONTENTS UNDER PRESSURE. DO NOT spray towards face. Avoid contact with eyes and skin. Containers may explode when heated. Do not puncture or incinerate container. DO NOT expose to heat or store at temperatures above 120°F (49°C) as the container may burst. KEEP OUT OF REACH OF CHILDREN.
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Potential short term health effects Routes of exposure
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Eye, Skin contact, Inhalation. None expected during normal conditions of use. May cause eye irritation upon direct contact with the eyes. None expected during normal conditions of use. None expected during normal conditions of use. However intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Health injuries are not known or expected under normal use. Skin. Eyes. The finished product is not expected to have chronic health effects. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.
Eyes
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Skin
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Inhalation
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Ingestion
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Target organs
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Chronic effects
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Signs and symptoms
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3. Composition / Information on Ingredients
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Ingredient(s) Propane Butane Proprietary fragrance
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CAS # 74-98-6 106-97-8 Mixture
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Percent 2.5 - 10 10 - 20 0.1 - 1.5
02-Mar-2010

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4. First Aid Measures
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First aid procedures Eye contact
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Skin contact
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If in eyes, immediately flush eyes with plenty of water, remove any contact lenses and continue to flush eyes for at least 15 minutes with water. If irritation persists get medical attention. If on skin, wash with soap and water. If Irritation develops,get medical attention. Move to fresh air in case of accidental inhalation of vapours. Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. Contains: Propellants, petroleum solvent and fragrance oils. Do not puncture or incinerate container. Keep away from sources of ignition. No smoking. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children.
Inhalation
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Ingestion
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Notes to physician
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General advice
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5. Fire Fighting Measures
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Flammable properties
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Aerosol flame extension less than 18 inches (45 cm). Carbon dioxide. Dry chemical. Foam.
Extinguishing media Suitable extinguishing media
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Unsuitable extinguishing media Not available Protection of firefighters Specific hazards arising from the chemical
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Contents under pressure. Pressurized container may explode when exposed to heat or flame. Cool containers with flooding quantities of water until well after fire is out. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Oxides of carbon. Not available Not available
Protective equipment for firefighters
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Hazardous combustion products
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Explosion data Sensitivity to mechanical impact
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Sensitivity to static discharge
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6. Accidental Release Measures
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Personal precautions
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Methods for containment
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Methods for cleaning up
Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Before attempting clean up, refer to hazard data given above. Remove sources of ignition. Although the chance of a significant spill or leak is unlikely in aerosol containers, in the event of such an occurrence, absorb spilled material with a non-flammable absorbent such as sand or vermiculite. Small amounts: Wipe up with absorbent material (e.g. cloth, fleece).
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7. Handling and Storage
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Handling
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Storage
Use this product with adequate ventilation. Use good industrial hygiene practices in handling this material. When using do not eat or drink. Keep out of reach of children. DO NOT expose to heat or store at temperatures above 120°F (49°C) as the container may burst. Do not puncture or incinerate container. Keep away from heat, open flames or other sources of ignition. NOTE TO PARENTS: Intentional misuse by deliberately concentrating and inhaling aerosol products may be harmful or fatal. Help stop inhalation abuse; for information visit www.inhalant.org.
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Issue date
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8. Exposure Controls / Personal Protection
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Exposure limits Ingredient(s) Butane Exposure Limits ACGIH-TLV TWA: 1000 ppm OSHA-PEL Not established Propane ACGIH-TLV TWA: 1000 ppm OSHA-PEL TWA: 1000 ppm ACGIH-TLV Not established OSHA-PEL Not established
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Proprietary fragrance
Engineering controls
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General ventilation normally adequate.
Personal protective equipment Eye / face protection
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No special requirements under normal use conditions. Emergency responders should wear full eye and face protection. No special requirements under normal use conditions. Hand protection Emergency responders should wear impermeable gloves. No special requirements under normal use conditions. Skin and body protection Emergency responders should wear impermeable clothing and footwear when responding to a situation where contact with the liquid is possible. Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Respiratory protection Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid inhalation of vapours generated by this product during a spill or other clean-up operations. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands before breaks and immediately after handling the product.
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9. Physical and Chemical Properties
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Appearance
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Aerosol. Clear Misty spray Characteristic Not available Gas 9.2 Not available Not available Not available Not available Not available Not available Not available Not available Not available Not available Not available
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Color
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Form
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Odor
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Odor threshold
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Physical state
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pH
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Freezing point
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Pour point
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Boiling point
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Flash point
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Evaporation rate
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Flammability limits in air, lower, % by volume
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Flammability limits in air, upper, % by volume
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Vapor pressure
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Vapor density
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Specific gravity
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Octanol/water coefficient
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Auto-ignition temperature
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Not available
10. Stability and Reactivity
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Chemical stability
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Stable under recommended storage conditions. Aerosol containers are unstable at temperatures above 49°C (120.2°F). Do not mix with other chemicals. Oxidizers. Acids. Caustics.
Conditions to avoid
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Incompatible materials
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Hazardous decomposition products May include and are not limited to: Oxides of carbon. Hazardous polymerization does not occur. Possibility of hazardous reactions
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11. Toxicological Information
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Component analysis - LC50 Ingredient(s) Butane Propane Proprietary fragrance
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LC50 Not available Not available Not available LD50 Not available Not available Not available None expected during normal conditions of use. May cause eye irritation upon direct contact with the eyes. None expected during normal conditions of use. None expected during normal conditions of use. However intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Health injuries are not known or expected under normal use. The finished product is not expected to have chronic health effects. The finished product is not expected to have chronic health effects. The finished product is not expected to have chronic health effects. The finished product is not expected to have chronic health effects. The finished product is not expected to have chronic health effects. The finished product is not expected to have chronic health effects. Not available
Component analysis - Oral LD50 Ingredient(s) Butane Propane Proprietary fragrance
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Effects of acute exposure Eye
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Skin
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Inhalation
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Ingestion
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Sensitization
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Chronic effects
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Carcinogenicity
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Mutagenicity
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Reproductive effects
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Teratogenicity
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Synergistic Materials
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12. Ecological Information
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Ecotoxicity
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Not available Not available Not available Not available Not available Not available Not available Not available
Environmental effects
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Aquatic toxicity
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Persistence / degradability
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Bioaccumulation / accumulation
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Partition coefficient
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Mobility in environmental media
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Chemical fate information
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13. Disposal Considerations
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Waste codes
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Not available Dispose in accordance with all applicable regulations.
Disposal instructions
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Issue date
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Waste from residues / unused products
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Not available Not available
Contaminated packaging
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14. Transport Information
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U.S. Department of Transportation (DOT) UN 1950, Aerosols, Class 2.1 Re-classed as Consumer Commodity ORM-D
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Transportation of Dangerous Goods (TDG - Canada) Not regulated under TDG - Consumer Commodity / Limited Quantity
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IMDG (Marine Transport) UN 1950, Aerosols, Class 2.1, Limited Quantity
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Issue date
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IATA/ICAO (Air) UN 1950, Aerosols, Flammable, Class 2.1, Limited Quantity or Consumer Commodity, ID 8000 if acceptable to airline
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15. Regulatory Information
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US Federal regulations
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Product Registration: Not registered
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Occupational Safety and Health Administration (OSHA) Yes 29 CFR 1910.1200 hazardous chemical
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Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Hazard categories Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No No Section 302 extremely hazardous substance Section 311 hazardous chemical Yes
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Clean Air Act (CAA)
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Not available Not available This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm.
Present Present Present
Clean Water Act (CWA)
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State regulations
U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances Butane 106-97-8 U.S. - Massachusetts - Right To Know List Butane 106-97-8 Propane 74-98-6 U.S. - Minnesota - Hazardous Substance List
Butane 106-97-8 Present Propane 74-98-6 Simple asphyxiant U.S. - New Jersey - Right to Know Hazardous Substance List Butane 106-97-8 Propane 74-98-6 U.S. - Pennsylvania - RTK (Right to Know) List Butane 106-97-8 Propane 74-98-6 U.S. - Rhode Island - Hazardous Substance List Butane Propane
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sn 0273 sn 1594 Present Present Toxic; Flammable Toxic; Flammable
106-97-8 74-98-6
Inventory status Country(s) or region United States & Puerto Rico Inventory name Toxic Substances Control Act (TSCA) Inventory On inventory (yes/no)* Yes
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
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16. Other Information
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Disclaimer
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Further information
This product should only be used as directed on the label and for the purpose intended. To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 62338-77895 - AIR WICK® Aerosols 2 in 1 - Papaya and Mango - 0025583 (987-157B) 62338-77897 - AIR WICK® Aerosols 2 in 1 - Plumeria and Wildrose - 0025584 (987-157A) 62338-05762 - AIR WICK® Aerosols 2-in-1 - Lavender and Chamomile - 0025582 (987-043B) 62338-74734 - AIR WICK® Aerosols 2 in 1 - Crisp Breeze® - 370707 (987-171) 62338-74373 - AIR WICK® Aerosols 2 in 1 - Sparkling Citrus® - 376017 (987-157E) 62338-76143 - AIR WICK® Aerosols 2 in 1 - Rain Garden® - 375422 (987-81) 62338-77002 - AIR WICK® Aerosols 2 in 1 - Fresh Waters® - 380762 (987-157C) 62338-05768 - AIR WICK® Aerosols 2 in 1 - Vanilla Indulgence® - 379605 (987-038C) 62338-74164 - AIR WICK® Aerosols 2 in 1 - Neutra Air® - 351945 (1332-145) 62338-79319 - AIR WICK® Aerosols Aqua Essences - Mountain Breeze - 0157184 (1332-099A) 62338-79321 - AIR WICK® Aerosols Aqua Essences - Tropical EscapeTM - 0157187 (1332-099B) 62338-81260 - AIR WICK® Aerosols Aqua Essences - Morning RainTM - 0157188 (1332-099C) 62338-81261 - AIR WICK® Aerosols Aqua Essences - Wildflower Mist - 0157190 (1332-099D) 02-Mar-2010 01-Mar-2010 Reckitt Benckiser Regulatory Department 800-333-3899 For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document.
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Issue date
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Effective date
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Prepared by
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Other information
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Issue date
02-Mar-2010