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SAFETY DATA SHEET REPRE's product 2010

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

PRODUCT NAME REACH REGISTRATION NOTES CAS-No. CHEMICAL NAME SYNONYMS, TRADE NAMES APPLICATION SUPPLIER REPRE's product 2010 Pre-registered 79-10-7 1, 1, 1-tri----- (>98%) another name Industrial wood coating. To fill out 'Name of IMPORTER' To fill out 'Address of IMPORTER' To fill out 'Telephone of IMPORTER' MANUFACTURER REPRE Co., Ltd. 3-5-3, Nihonbashi Kayaba-cho, Chuo-ku TOKYO, JAPAN tel +81-3-5643-2755 fax +81-3-5643-2756 Mr. Kazumi Ito [email protected]

CONTACT PERSON EMERGENCY TELEPHONE

To fill out 'e mail for a SDS competent person' To fill out 'Emergency telephone number' and select either (office hours) or (24 hours)

2 HAZARDS IDENTIFICATION

CLASSIFICATION (67/548) CLASSIFICATION (EC 1272/2008) Physical Health Environmental LABEL IN ACCORDANCE WITH (EC) NO. 1272/2008 Flam. Sol. 1 - H228 Not classified. Not classified. F;R11.

SIGNAL WORD HAZARD STATEMENTS

Danger H228 Flammable solid. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Wear protective gloves/protective clothing/eye protection/face protection. Use alcohol-resistant foam, carbon dioxide or dry powder for extinction.

PRECAUTIONARY STATEMENTS P210 P240 P280 P378a ENVIRONMENT The product is not expected to be hazardous to the environment. PHYSICAL AND CHEMICAL HAZARDS The product is flammable, and heating may generate vapours which may form explosive vapour/air mixtures. HUMAN HEALTH In high concentrations, vapours and spray mists are narcotic and may cause headache, fatigue, dizziness and nausea.

3 COMPOSITION/INFORMATION ON INGREDIENTS

GROSS FORMULA CAS-No. CH4 79-10-7

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COMPOSITION COMMENTS The Data Shown is in accordance with the latest EC Directives. This product is a 'SUBSTANCE'.

4 FIRST-AID MEASURES

GENERAL INFORMATION General first aid, rest, warmth and fresh air. Do not give victim anything to drink if he is unconscious. Get medical attention if any discomfort continues. INHALATION Place unconscious person on the side in the recovery position and ensure breathing If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort continues. INGESTION Immediately rinse mouth and drink plenty of water or milk. Keep person under observation. Do not induce vomiting. If vomiting occurs, keep head low. Transport immediately to hospital and bring along these instructions. SKIN CONTACT Immediately remove contaminated clothing. Wash off promptly and flush contaminated skin with water. Promptly remove clothing if soaked through and flush skin with water. EYE CONTACT Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Get medical attention promptly if symptoms occur after washing.

5 FIRE-FIGHTING MEASURES

EXTINGUISHING MEDIA Use: Alcohol resistant foam. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. DO NOT use water if avoidable. UNUSUAL FIRE & EXPLOSION HAZARDS Fire causes formation of toxic gases. SPECIFIC HAZARDS The product is flammable, and heating may generate vapours which may form explosive vapour/air mixtures. PROTECTIVE MEASURES IN FIRE Self contained breathing apparatus and full protective clothing must be worn in case of fire.

6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS Wear protective clothing as described in Section 8 of this safety data sheet. ENVIRONMENTAL PRECAUTIONS Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body. Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container. SPILL CLEAN UP METHODS Keep combustibles away from spilled material. Absorb in vermiculite, dry sand or earth and place into containers. Wash contaminated area with water. Wash thoroughly after dealing with a spillage.

7 HANDLING AND STORAGE

USAGE PRECAUTIONS Keep away from heat, sparks and open flame. Do not use contact lenses. Avoid spilling, skin and eye contact. Eye wash facilities and emergency shower must be available when handling this product. During application and drying, solvent vapours will be emitted. STORAGE PRECAUTIONS Store in tightly closed original container in a dry and cool place. Store under well-ventilated conditions at a temperature below 25°C. STORAGE CLASS Flammable liquid storage.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

INGREDIENT COMMENTS No exposure limits noted for ingredient(s). PROTECTIVE EQUIPMENT

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PROCESS CONDITIONS Provide eyewash station. ENGINEERING MEASURES Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded. HAND PROTECTION Protective gloves and goggles must be used if there is a risk of direct contact or splash. EYE PROTECTION Contact lenses should not be worn when working with this chemical! Wear approved safety goggles. OTHER PROTECTION Use engineering controls to reduce air contamination to permissible exposure level. Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact. Provide eyewash station and safety shower. HYGIENE MEASURES Wash promptly if skin becomes contaminated. Promptly remove non-impervious clothing that becomes contaminated. When using do not eat, drink or smoke.

9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE COLOUR ODOUR SOLUBILITY BOILING POINT (°C) RELATIVE DENSITY PARTICLE SIZE (Micron) VAPOUR PRESSURE pH-VALUE, CONC. SOLUTION Clear liquid Colourless Organic solvents. Soluble in: Alcohol Esters Benzene. MELTING POINT (°C) BULK DENSITY VAPOUR DENSITY (air=1) EVAPORATION RATE VISCOSITY FLASH POINT (°C) FLAMMABILITY LIMIT - LOWER(%) PARTITION COEFFICIENT (N-Octanol/Water) No data No data No data No data No data 15degreeC TCC (Tag closed cup). 1.5% No Data

100 1.00 20 No data 10hPa 20 No data DECOMPOSITION TEMPERATURE No data (°C) No data AUTO IGNITION TEMPERATURE (°C) FLAMMABILITY LIMIT - UPPER(%) 20.0% VOLATILE ORGANIC COMPOUND (VOC) No data

10 STABILITY AND REACTIVITY

STABILITY Stable under normal temperature conditions and recommended use. The product is degraded by hydrolysis. CONDITIONS TO AVOID Avoid heat, flames and other sources of ignition. MATERIALS TO AVOID Strong oxidising substances. Acids. HAZARDOUS DECOMPOSITION PRODUCTS No information available.

11 TOXICOLOGICAL INFORMATION

TOXIC DOSE 1 - LD 50 TOXIC DOSE 2 - LD 50 TOXICOLOGICAL INFORMATION No information available. >2000 mg/kg (oral-mouse) >2000 mg/kg (ipr-mouse)

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INHALATION No data INGESTION No specific health warnings noted. SKIN CONTACT Irritating to skin. EYE CONTACT Irritating to eyes. OTHER HEALTH EFFECTS No data

12 ECOLOGICAL INFORMATION

ECOTOXICITY There are no data on the ecotoxicity of this product. LC 50, 96 Hrs, FISH mg/l No Data EC 50, 48 Hrs, DAPHNIA, mg/l IC 50, 72 Hrs, ALGAE, mg/l BIOACCUMULATION No data available on bioaccumulation. DEGRADABILITY The product is easily biodegradable. ACUTE FISH TOXICITY No data available. WATER HAZARD CLASSIFICATION N/A. No Data No Data

13 DISPOSAL CONSIDERATIONS

GENERAL INFORMATION Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority. DISPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements.

14 TRANSPORT INFORMATION

UK ROAD CLASS PROPER SHIPPING NAME UN NO. ROAD ADR CLASS NO. ADR PACK GROUP HAZARD No. (ADR) HAZCHEM CODE RID CLASS NO. UN NO. SEA IMDG PAGE NO. EMS UN NO. AIR AIR PACK GR.

3 ESTERS, N.O.S. 3272 3 II 33 ·3YE 3 3272 3 F-E, S-D 3272 II UK ROAD PACK GR. ADR CLASS TUNNEL RESTRICTION CODE ADR LABEL NO. CEFIC TEC(R) NO. RID PACK GROUP IMDG CLASS IMDG PACK GR. MARINE POLLUTANT AIR CLASS II Class 3: Flammable liquids. (D/E) 3 30GF1-I+II II 3 II No. 3

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15 REGULATORY INFORMATION

UK REGULATORY REFERENCES Chemicals (Hazard Information & Packaging) Regulations. ENVIRONMENTAL LISTING No listing noted. EU DIRECTIVES Dangerous Substance Directive 67/548/EEC. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (CLP) STATUTORY INSTRUMENTS The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). APPROVED CODE OF PRACTICE Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. GUIDANCE NOTES CHIP for everyone HSG(108). NATIONAL REGULATIONS The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689. Workplace Exposure Limits 2005 (EH40)

16 OTHER INFORMATION

GENERAL INFORMATION Only trained personnel should use this material. INFORMATION SOURCES Internal data. REVISION COMMENTS This is first issue. ISSUED BY HS&E Manager. DATE 20 March 2010

DISCLAIMER This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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